Cementitious veneer and laminate material incorporating reinforcing fibers

• US 8,182,605 B2
• Filed: 05/12/2010
• Issued: 05/22/2012
• Est. Priority Date: 12/27/2002
• Status: Expired due to Fees

• Current Assignee: Ecomold Limited
• Original Assignee: Ecomold Limited
• Inventors: Wallner, Christine E.
• Primary Examiner(s): Marcantoni, Paul
• Application Number:
  US12/778,999
• Publication Number:
  US 20100222457A1
• Time in Patent Office: 741 Days
• Field of Search: 106/685, 106/686, 106/705, 106/772, 106/778, 106/DIG.1, 428/325
• US Class Current: 106/685
• CPC Class Codes: C04B 14/365 Gypsum synthetic gypsum C04B18/0445, C04B18/064
• CPC Class Codes: C04B 14/386 Carbon carbon nanotubes C04B14/026
• CPC Class Codes: C04B 14/42 Glass
• CPC Class Codes: C04B 16/0641 Polyvinylalcohols; Polyvinylacetates
• CPC Class Codes: C04B 16/0691 Polyamides; Polyaramides
• CPC Class Codes: C04B 18/082 Cenospheres
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 2111/00612 as one or more layers of a layered structure
• CPC Class Codes: C04B 22/16 containing phosphorus in the anion, e.g. phosphates
• CPC Class Codes: C04B 22/165 Acids
• CPC Class Codes: C04B 24/2623 Polyvinylalcohols; Polyvinylacetates
• CPC Class Codes: C04B 24/383 Cellulose or derivatives thereof
• CPC Class Codes: C04B 28/30 containing magnesium cements or similar cementsmagnesium oxide cements C04B28/10
• CPC Class Codes: E04F 13/141 with an outer layer of concrete E04F13/147 takes precedence
• CPC Class Codes: E04F 15/02 Flooring or floor layers composed of a number of similar elements of webs E04F15/16
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete
• CPC Class Codes: Y10S 106/01 Fly ash
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

Abstract

A cementitious veneer and laminate composition is provided. The cementitious laminate composition includes a substrate, a primer layer applied to the substrate, the primer layer comprising a mixture of polyvinyl alcohol catalyst, Portland cement, and sand; and a cementitious veneer layer applied to the primer layer, the cementitious veneer layer comprising a mixture of magnesium sulfate, filler, magnesium oxide, gypsum cement or bassanite, cellulose ethers, and polyvinyl alcohol catalyst. The polyvinyl alcohol catalyst comprises a mixture of polyvinyl alcohol fibers dissolved in water and mixed with butylene carbonate. The veneer layer is applied to the substrate and primer layer by means including spraying and manual spreading, and can be ornamentally manipulated either before or after curing of the veneer layer. The veneer composition can be formed into laminated tiles or panels for use in building applications.

Claims

1. A cementitious veneer comprising:

a magnesium oxysulfate compound including magnesium sulfate, magnesium oxide, and sodium hexametaphosphate, phosphoric acid; and

a cementitious composition mixed with the magnesium oxysulfate compound to form a cementitious veneer mixture, the cementitious composition including hydrated calcium sulfate, filler, cellulose ethers, a polyvinyl alcohol polymer mixture, and one or more compositionally different fibers.

2. The cementitious veneer of claim 1 wherein the polyvinyl polymer mixture comprises polyvinyl alcohol fibers boiled in water with butylene carbonate.

3. The cementitious veneer of claim 2 wherein the cementitious veneer is produced through mixing with water, and wherein the water is one of distilled water and microclustered water.

4. The cementitious veneer of claim 2 wherein the one or more compositionally different fibers are selected from the group consisting of:

thermoplastic fibers, polyvinyl alcohol fibers, cellulose fibers, carbon fibers, kevlar fibers, and glass fibers.

5. The cementitious veneer of claim 2 wherein the magnesium oxysulfate compound comprises approximately sixty percent of the cementitious veneer mixture.

6. The cementitious veneer of claim 1, wherein the magnesium oxysulfate compound consists of, on a volume basis, 0.04% to 0.08% sodium hexametaphosphate, 0.06% to 0.17% phosphoric acid at a concentration of 75% to 85%, 40% to 46% magnesium sulfate, 30% to 35% magnesium oxide, 1.3% to 1.4% distilled water, 2.5% to 3.25% fly ash cenospheres, and the cementitious composition consists of, on volume basis, 1.2% to 1.9% fly ash cenospheres, 77% to 85% gypsum cement, 13.5% to 14% distilled water, and 1.25% to 2.5% of the 16:

1 mixture of polyvinyl polymer and butylene carbonate.

7. The cementitious veneer of claim 1 wherein the cellulose ethers comprise hydroxyethyl cellulose.

8. The cementitious veneer of claim 7 further comprising a starch ether in combination with the hydroxyethyl cellulose during processing.

9. A cementitious veneer comprising a cementitious composition mixed with a magnesium oxysulfate compound to form a cementitious veneer mixture, the magnesium oxysulfate compound consisting of, on a volume basis, 0.04% to 0.08% sodium hexametaphosphate, 0.06% to 0.17% phosphoric acid at a concentration of 75% to 85%, 40% to 46% magnesium sulfate, 30% to 35% magnesium oxide, 1.3% to 1.4% distilled water, 2.5% to 3.25% fly ash cenospheres, and the cementitious composition consisting of fly ash cenospheres and one or more additives including cellulose ethers and one or more compositionally different fibers.

10. The cementitious veneer of claim 9 wherein the cellulose ethers comprise hydroxyethyl cellulose.

11. The cementitious veneer of claim 9 wherein the one or more compositionally different fibers are selected from the group consisting of:

thermoplastic fibers, polyvinyl alcohol fibers, cellulose fibers, carbon fibers, kevlar fibers, and glass fibers.

12. A cementitious veneer made by a process comprising:

mixing magnesium sulfate, magnesium oxide, sodium hexametaphosphate, phosphoric acid together with water to form a magnesium oxysulfate compound; and

mixing hydrated calcium sulfate, filler, cellulose ethers, a polyvinyl alcohol polymer mixture, and one or more compositionally different fibers together with water to form a cementitious composition; and

combining the cementitious composition with the magnesium oxysulfate compound to form a cementitious veneer.

13. The cementitious veneer of claim 12 wherein the polyvinyl polymer mixture is produced through a process comprising boiling polyvinyl alcohol fibers in water with butylene carbonate.

14. The cementitious veneer of claim 12 wherein the one or more compositionally different fibers are selected from the group consisting of:

thermoplastic fibers, polyvinyl alcohol fibers, cellulose fibers, carbon fibers, kevlar fibers, and glass fibers.

15. The cementitious veneer of claim 12 wherein the magnesium oxysulfate compound comprises approximately sixty percent of the cementitious veneer mixture.

16. The cementitious veneer of claim 12, wherein the magnesium oxysulfate compound consists of, on a volume basis, 0.04% to 0.08% sodium hexametaphosphate, 0.06% to 0.17% phosphoric acid at a concentration of 75% to 85%, 40% to 46% magnesium sulfate, 30% to 35% magnesium oxide, 1.3% to 1.4% distilled water, 2.5% to 3.25% fly ash cenospheres, and the cementitious composition consists of, on volume basis, 1.2% to 1.9% fly ash cenospheres, 77% to 85% gypsum cement, 13.5% to 14% distilled water, and 1.25% to 2.5% of the 16:

1 mixture of polyvinyl polymer and butylene carbonate.

17. The cementitious veneer of claim 12 wherein the cellulose ethers comprise hydroxyethyl cellulose.

18. The cementitious veneer of claim 17 wherein the process further comprises combining a starch ether with the hydroxyethyl cellulose during processing.

19. The cementitious veneer of claim 12 wherein the process further comprises adding a dye or pigment cementitious composition to the cementitious veneer.

20. The cementitious veneer of claim 12 wherein the process further comprises forming the cementitious veneer in a mold to form tile or shaped objects.