Hydrogen generator

• US 8,187,348 B2
• Filed: 03/09/2009
• Issued: 05/29/2012
• Est. Priority Date: 04/07/2008
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Eickhoff, Steven J., Zhang, Chunbo
• Primary Examiner(s): MERKLING, MATTHEW J
• Application Number:
  US12/400,599
• Publication Number:
  US 20090252670A1
• Time in Patent Office: 1,177 Days
• Field of Search: 48/61, 481/97.R, 422625-629, 423644-6582
• US Class Current: 48/61
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen generator includes a container with multiple concentric hollow cylinders of chemical hydride fuel disposed within the container. A water vapor source is disposed within the container and operable to deliver water vapor to the cylinders of chemical hydride fuel. Generated hydrogen is provided via a hydrogen output port formed in the container.

Claims

1. A hydrogen generator comprising:

a container;

a multiple concentric hollow cylinders of chemical hydride fuel disposed within the container;

a water vapor source disposed within the container and operable to deliver water vapor to the cylinders of chemical hydride fuel; and

a hydrogen output port formed in the container;

a hydrogen vapor source comprising a water reservoir and wicking material extending into the water reservoir and disposed adjacent the hollow cylinders of chemical hydride to provide water vapor; and

water impermeable, water vapor and hydrogen permeable membranes disposed between the wicking material and the hollow cylinders of the chemical hydride fuel.

2. The hydrogen generator of claim 1 wherein the hollow cylinders of chemical hydride fuel are substantially round.

3. The hydrogen generator of claim 1 wherein the generator comprises three concentric hollow cylinders of chemical hydride.

4. The hydrogen generator of claim 1 wherein the wicking material comprises a first wicking material extending into the water reservoir and a second wicking material in fluid contact with the first wicking material and extending adjacent the hollow cylinders of chemical hydride.

5. The hydrogen generator of claim 1 and further comprising air gaps between the membranes and the hollow cylinders of chemical hydride, wherein the air gaps are formed to provide diffusion of the water vapor and transport of generated hydrogen.

6. The hydrogen generator of claim 5 and further comprising a pressure release valve coupled to the air gaps and operable to maintain hydrogen pressure in the container at or below a predetermined pressure.

7. The hydrogen generator of claim 1 and further comprising perforated metal supports coupled to membranes and positioned to support the membrane, confine the hollow cylinders of chemical hydride, and transfer heat generated during reaction of the chemical hydride with water vapor.

8. The hydrogen generator of claim 1 wherein the hollow cylinders of chemical hydride are formed a with grain size of from approximately 1 to 100 μ

m.

9. A pressurized hydrogen generator comprising:

a pressure container;

a multiple concentric hollow cylinders of chemical hydride fuel disposed within the container;

a water reservoir within a smallest hollow cylinder of chemical hydride fuel;

a wicking structure coupled to the water reservoir and extending along sides of the multiple concentric hollow cylinders of chemical hydride fuel to provide water vapor to the fuel; and

water impermeable and hydrogen and water vapor permeable membranes separating the wicking structure from each of the multiple concentric hollow cylinders of chemical hydride fuel; and

a hydrogen output port.

10. The pressurized hydrogen generator of claim 9 wherein the hollow cylinders of chemical hydride fuel are substantially round.

11. The pressurized hydrogen generator of claim 9 wherein the generator comprises three concentric hollow cylinders of chemical hydride.

12. The pressurized hydrogen generator of claim 9 and further comprising air gaps between the membranes and the hollow cylinders of chemical hydride, wherein the air gaps are formed to provide diffusion of the water vapor and transport of generated hydrogen.

13. The pressurized hydrogen generator of claim 12 and further comprising a pressure release valve coupled to the air gaps and operable to maintain hydrogen pressure in the container at or below a predetermined pressure.

14. The pressurized hydrogen generator of claim 9 and further comprising perforated metal supports coupled to the membranes and positioned to support the membranes, confine the hollow cylinders of chemical hydride, and transfer heat generated during reaction of the chemical hydride with water vapor.

15. The pressurized hydrogen generator of claim 9 wherein the hollow cylinders of chemical hydride are formed a with grain size of from approximately 1 to 100 μ

m.