Devices and methods for water removal in distillation columns

• US 8,192,588 B2
• Filed: 08/28/2008
• Issued: 06/05/2012
• Est. Priority Date: 08/29/2007
• Status: Expired due to Fees

• Current Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Original Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Inventors: Mak, John
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US12/672,390
• Publication Number:
  US 20110192805A1
• Time in Patent Office: 1,377 Days
• Field of Search: 196/46, 196/121, 196/132, 196/141, 159/37, 159/44, 159/47.1, 159/DIG.1, 159/DIG.25, 202/160, 202/204, 203/1, 203/2, 203/10, 203/14, 203/98, 208/187, 210/137, 210/149, 210/175, 210/513, 210/742, 210/774
• US Class Current: 203/1
• CPC Class Codes: B01D 17/02 Separation of non-miscible liquids
• CPC Class Codes: B01D 17/045 with coalescers
• CPC Class Codes: B01D 3/14 Fractional distillation or use of a fractionation or rectification column
• CPC Class Codes: C02F 1/02 by heating methods of steam generation F22B; preheating boiler feed-water or accumulating preheated boiler feed-water F22D
• CPC Class Codes: C02F 1/40 Devices for separating or removing fatty or oily substances or similar floating material cleaning or keeping clear the surface of open water from oil or like materials E02B15/04; devices in sewers for separating liquid or solid substances from sewage E03F5/14, e.g. for use in drains leading to the sewer E03F5/16
• CPC Class Codes: C02F 2101/32 Hydrocarbons, e.g. oil
• CPC Class Codes: C02F 2103/365 from petrochemical industry (e.g. refineries)
• CPC Class Codes: C02F 2209/02 Temperature
• CPC Class Codes: C02F 2209/40 Liquid flow rate
• CPC Class Codes: C02F 2209/42 Liquid level
• CPC Class Codes: Y10S 159/01 Electric heat

Abstract

Water is removed from oily water produced during operation of a separation column by withdrawing the oily water from the column during separation into an external separator where the oily water is separated into a water phase and an oily phase. The oily phase is then heated to a temperature effective to produce a density differential that drives the oily phase back into the operating column.

Claims

1. A water removal apparatus for removal of water in a separation column, comprising:

a separator fluidly and externally coupled to the separation column and configured to receive an oily water from the separation column and to allow separation of water from the oily water into a water phase and an oil phase, wherein the separation column is configured to receive a water-containing hydrocarbon feed and to separate hydrocarbons;

a feed line that is fluidly coupled to the separator and the column such that the feed line provides the oily water from a side draw of the separation column to the separator;

a return line that is fluidly coupled to the separator and the column such that the return line provides oil from the oil phase to the column; and

a thermal control unit thermally coupled to the return line and configured to allow raising a temperature of the oil in the return line in an amount effective to promote density-driven flow of the oil from the separator to the column through the return line, and

wherein the thermal control unit comprises an electric heater or a steam heater that are configured to allow raising of a temperature of the oil in the return line in an amount of at least 5°

F. relative to the temperature of the oil in the oily water.

2. The apparatus of claim 1 wherein the separator has a volume relative to product flow in the column to thereby allow for a residence time of the oily water in the separator effective to separate the water phase from the oil phase via gravity settling.

3. The apparatus of claim 1 wherein the column and the separator are configured to allow operation at substantially the same pressure.

4. The apparatus of claim 1 wherein the separator is configured to allow operation at a pressure of between 100 psi and 500 psi.

5. The apparatus of claim 1 wherein the thermal control unit further comprises a control circuit that is configured to receive temperature information and flow data of the oil in the return line.

6. The apparatus of claim 1 further comprising an oil-water interface level sensor that is coupled to the separator.

7. The apparatus of claim 1 further comprising a coalescing element disposed within the separator to thereby enhance separation of the oily water into the water phase and the oil phase.

8. A method of removing water from oily water produced in a separation column while operating the separation column, comprising the steps of:

feeding a water-containing hydrocarbon feed into the separation column and operating the separation column to separate hydrocarbons;

withdrawing from a side draw of the separation column oily water and separating the oily water in a separator that is external to the column to thereby form a water phase and an oil phase;

heating at least part of the oil phase to a temperature effective to generate a density difference that is sufficient to move the heated oil phase back to the column while the column is operating;

wherein the at least part of the oil phase is heated in a return line using an electric heater or a steam heater; and

wherein the electric heater or the steam heater raise a temperature of the oil phase in the return line in an amount of at least 5°

F. relative to the temperature of the oil phase in the oily water.

9. The method of claim 8 wherein the separator has a volume relative to product flow in the column to thereby allow for a residence time of the oily water in the separator effective to separate the water phase from the oil phase via gravity settling.

10. The method of claim 8 wherein the column and the separator are operated at substantially the same pressure.

11. The method of claim 8 wherein the separator is operated at a pressure of between 100 psi and 500 psi.

12. The method of claim 8 further comprising a step of measuring an oil-water interface using a level sensor that is coupled to the separator.

13. The method of claim 8 wherein the step of separating the oily water includes use of a coalescing element.