Polyolefin adhesive compositions and articles made therefrom

• US 8,193,289 B2
• Filed: 11/24/2009
• Issued: 06/05/2012
• Est. Priority Date: 10/15/2002
• Status: Active Grant

• Current Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Abhari, Ramin, Sims, Charles Lewis, Lewtas, Kenneth, Tse, Mun Fu, Brant, Patrick, Jiang, Peijun, Chow, Wai Yan, Schauder, Jean-Roch, Gong, Caiguo, Johnsrud, David Raymond, Canich, Jo Ann Marie
• Primary Examiner(s): CAIN, EDWARD J
• Application Number:
  US12/624,697
• Publication Number:
  US 20100076128A1
• Time in Patent Office: 924 Days
• Field of Search: 523/348, 526/348, 526/351, 524/570, 524/582
• US Class Current: 526/348
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 91/06 Waxes
• CPC Class Codes: C09J 123/10 Homopolymers or copolymers of propene
• CPC Class Codes: C09J 123/12 Polypropene

Abstract

Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.

Claims

1. An adhesive comprising:

i) at least one functionalized component chosen from functionalized polymers, functionalized oligomers and beta nucleating agents; and

ii) an olefin polymer comprising 50 wt % or more of an alpha-olefin having 3 to 30 carbon atoms, where the olefin polymer has a Dot T-Peel of 1 N or more on Kraft paper, an Mw of 10,000 to 100,000, a g′

measured at the Mz of 0.95 or less, a heat of fusion of 1 to 70 J/g, a heptane insoluble fraction of 70 wt % or less, based upon the weight of the starting olefin polymer.

2. The adhesive of claim 1, wherein the heptane insoluble fraction has a branching index g′

of 0.9 or less as measured at the Mz of the polymer.

3. The adhesive of claim 1, wherein the heptane insoluble fraction has a branching index g′

of 0.7 or less as measured at the Mz of the polymer.

4. The adhesive of claim 1, wherein the olefin polymer has a percent crystallinity of between 5 and 40% or less.

5. The adhesive of claim 1, wherein the olefin polymer has heat of fusion of from 20 to 70 J/g.

6. The adhesive of claim 1, wherein the olefin polymer has heat of fusion of from 30 to 60 J/g.

7. The adhesive of claim 1, wherein the olefin polymer has a percent crystallinity of 10-30%.

8. The adhesive of claim 1, wherein the olefin polymer has tensile strength at break of 0.75 MPa or more.

9. The adhesive of claim 1, wherein the olefin polymer has a Dot T-Peel of between 3 and 10,000 N.

10. The adhesive of claim 1, wherein the olefin polymer has a Tg of between 5 and −

65°

C.

11. The adhesive of claim 1, wherein the olefin polymer comprises at least 50 wt % propylene and up to 50 wt % of a comonomer chosen from butene and hexene.

12. The adhesive of claim 1, wherein tackifier is present at 1 to 60 wt %.

13. The adhesive of claim 1, wherein the olefin polymer has a Tg of 0°

C. or less.

14. The adhesive of claim 1, wherein the olefin polymer has a melt index of 50 dg/min or more.

15. The adhesive of claim 1, wherein the functionalized component is present at 0.1 to 10 wt %.

16. The adhesive of claim 1, wherein the functionalized component comprises functionalized polymer.

17. The adhesive of claim 1, wherein the functionalized component comprises functionalized polymer selected from the group consisting of maleated polyethylene, maleated metallocene polyethylene, maleated metallocene polypropylene, maleated ethylene propylene rubber, and functionalized polyisobutylene.

18. The adhesive of claim 1, wherein the functionalized component comprises functionalized oligomer.

19. The adhesive of claim 1, wherein the functional component comprises a functional group selected from the group consisting of maleic anhydride, citraconic anhydride, 2-methyl maleic anhydride, 2-chloromaleic anhydride, 2,3-dimethylmaleic anhydride, bicyclo [2,2,1]-5-heptene-2,3-dicarboxylic anhydride and 4-methyl-4-cyclohexene-1,2dicarboxylic anhydride, acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, crotonic acid, bicyclo(2.2.2)oct-5-ene-2,3-dicarboxylic acid anhydride, 1,2,3,4,5,&

g, lo-octahydronaphthalene-2,3-dicarboxylic acid anhydride, 2-oxa-1,3-diketospiro (4.4)non-7-ene, bicyclo (2.2.1)hept- 5- ene-2,3- dicarboxylic acid anhydride, maleopimaric acid, tetrahydrophtalic anhydride, norborn-5-ene-2,3-dicarboxylic acid anhydride, nadic anhydride, methyl nadic anhydride, himic anhydride, methyl himic anhydride, and x -methyl-bicyclo(2.2.1)hept-5-ene-2,3- dicarboxylic acid anhydride (XMNA).

20. The adhesive of claim 1, wherein the functional component comprises a functional polymer where the polymer of the functional polymer is polypropylene having a weight average molecular weight of 15,000 or less and a crystallinity of 5% or more.