Methods for forming fibers

• US 8,197,735 B2
• Filed: 11/13/2007
• Issued: 06/12/2012
• Est. Priority Date: 04/19/2005
• Status: Active Grant

• Current Assignee: Kamterter Products, LLC
• Original Assignee: Kamterter Products, LLC
• Inventors: Eastin, John Alvin, Vu, David
• Primary Examiner(s): Johnson, Christina
• Assistant Examiner(s): HUDA, SAEED M
• Application Number:
  US11/983,975
• Publication Number:
  US 20080066664A1
• Time in Patent Office: 1,673 Days
• Field of Search: 264/640, 264/211.12, 264/211.14, 264/211.17, 111/200, 425/72.2
• US Class Current: 264/211.14
• CPC Class Codes: A01C 7/004 using liquid seeding techniques
• CPC Class Codes: A01C 7/06 Seeders combined with fertilising apparatus
• CPC Class Codes: A01M 7/0089 Regulating or controlling systems the delivery being related to the movement of a vehicle B05B9/06
• CPC Class Codes: A01M 9/00 Special adaptations or arrangements of powder-spraying apparatus for purposes covered by this subclass
• CPC Class Codes: A01M 9/0092 Regulating or controlling systems the delivery being related to the movement of a vehicle B05B9/06
• CPC Class Codes: C08B 37/0024 beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
• CPC Class Codes: C08B 37/003 Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
• CPC Class Codes: C08L 5/08 Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
• CPC Class Codes: D01D 1/02 Preparation of spinning solutions
• CPC Class Codes: D01D 5/0007 Electro-spinning non-woven fabrics produced by electro-spinning D04H1/728
• CPC Class Codes: Y10S 111/90 Methods of planting seeds and miscellaneous compositions
• CPC Class Codes: Y10S 111/905 Seed treating seed planter
• CPC Class Codes: Y10S 111/917 Gel
• CPC Class Codes: Y10S 47/09 Physical and chemical treatment of seeds for planting
• CPC Class Codes: Y10S 47/11 The application of protective coatings to plants

Abstract

The configuration of a feedstock material is controlled by bringing it into contact with at least a first gas moving against it at a location with an area and thickness of the feedstock liquid that forms drops or fibers of a selected size. In one embodiment, drops of agricultural input materials are formed for spraying on agricultural fields. In another embodiment, nanofibers of materials such as chitosan or metals are formed. In another embodiment seeds are planted with gel.

Claims

1. A method of forming fibers comprising the steps of:

forming at least one formable material containing a solvent;

causing movement of individual streams of the at least one formable material and solvent into a working zone;

stretching the streams into fibers with at least one fluid energy field and an electric potential;

drying the fibers by evaporation of the solvent during stretching of the fibers and collecting the fibers after they have been dried wherein the formable material is a compatibly-selected feedstock material;

the step of causing movement of individual streams of the at least one formable material into a working zone comprises the substeps of;

bringing the compatibly-selected feedstock material and at least one moving compatibly-selected kinetic energy fluid in contact with each other;

said substep of bringing the compatibly-selected feedstock material and at least one moving compatibly-selected kinetic energy fluid in contact with each other comprising the further breakdown of adjusting at least one of a pressure of the at least one moving compatibly-selected kinetic energy fluid, a velocity of the at least one moving compatibly-selected kinetic energy fluid, a velocity of the compatibly-selected feedstock material, a thickness of the compatibly-selected feedstock material, a width of the at least one moving compatibly-selected kinetic energy fluid, a width of the compatibly-selected feedstock material, a temperature of the compatibly-selected feedstock material, and a viscosity of the compatibly-selected feedstock material, wherein the feedstock material drys to a hardened condition at a selected length and thinness;

the step of bringing the compatibly-selected feedstock material and at least one moving compatibly-selected kinetic energy fluid in contact with each other comprises the step of bringing at least one viscous liquid and the at least one moving compatibly-selected kinetic energy fluid in contact with each other;

the step of stretching the streams into fibers with at least one fluid energy field and an electric potential comprises the step of extruding viscous material through at least one needle opening while a high potential is applied wherein nano fibers are prepared;

the step of extruding viscous material through at least one needle opening while a high potential is a lied corn rises the step of extruding a chitosan solution through the at least one needle opening;

the step of drying and collecting the fibers comprises the step of collecting the fibers on a rotating collector;

the step of extruding a chitosan solution through the at least one needle opening comprises the step of extruding the chitosan solution through a plurality of needle openings at a rate between 2 and 7 micrometers per minute as controlled by a regulator in the presence of a gradient extending over a distance between 5 and 10 centimeters of 4 to 600 volts per centimeter.

2. A method of forming fibers comprising the steps of:

forming at least one formable material containing a solvent, wherein the step of forming at least one formable material comprises the steps of;

dissolving chitosan in an acidic liquid, whereby the formable material containing chitosan is obtained; and

displacing at least some of the acid from the acidic solution while maintaining a pH of the formable material containing chitosan low enough to avoid chitosan precipitation;

causing movement of at least one individual stream of the at least one formable material and solvent into a working zone;

stretching the streams into nano fibers with at least two fluid energy fields having different velocities; and

drying the fibers by evaporation of the solvent during stretching of the streams into nano fibers and collecting the nano fibers after they have been dried.

3. A method in accordance with claim 2 further including the step of adding sufficient organic solvent to lower conductivity to a level that permits electrospinning.

4. A method in accordance with claim 2 further including the step of adding sufficient organic solvent to reduce viscosity to a level that permits formation of long fibers comprising the substeps of:

dissolving chitosan powder that is in a water suspension in glacial acetic acid;

bubbling carbon dioxide through chitosan solution; and

adding an organic solvent to reduce conductivity, surface tension and viscosity until the chitosan solution is suitable for forming fibers.

5. A method of forming fibers comprising the steps of:

forming at least one formable material containing a solvent;

causing movement of at least one individual stream of the at least one formable material and solvent into a working zone;

stretching the streams into nano fibers with at least two fluid energy fields having different velocities;

drying the fibers by evaporation of the solvent during stretching of the streams into nano fibers and collecting the nano fibers after they have been dried;

the step of stretching the streams into nano fibers with at least two fluid energy fields comprises the step of extruding viscous material through at least one needle opening wherein the nano fibers are prepared;

the step of extruding viscous material through at least one needle opening includes the step of extruding a chitosan solution through the at least one needle opening;

the step of extruding a chitosan solution through the at least one needle opening comprises the step of extruding the chitosan solution through a plurality of needle openings at a rate between 2 and 7 micrometers per minute as controlled by a regulator in the presence of gradient extending over a distance between 5 and 10 centimeters of 4 to 600 volts per centimeter.

6. A method in accordance with claim 5 wherein the step of drying and collecting the fibers comprises the step of forming the fibers into a mat.

7. A method in accordance with claim 6 wherein the step of extruding the chitosan solution through a plurality of needle openings includes the step of extruding the chitosan solution in the absence of an electric field whereby a mat of oriented fibers is formed.

8. A method in accordance with claim 5 further including the step of adding a surfactant while bubbling the carbon dioxide through the chitosan solution.

9. A method in accordance with claim 5 further including the step of adding ethanol to the chitosan solution.

10. A method in accordance with claim 5 further including the step of adding poly(ethylene oxide) to the chitosan solution.