Process for producing liquid fuel from carbon dioxide and water

• US 8,198,338 B2
• Filed: 03/20/2007
• Issued: 06/12/2012
• Est. Priority Date: 03/20/2006
• Status: Active Grant

• Current Assignee: Cri Ehf
• Original Assignee: Cri Ehf
• Inventors: Ingolfsson, Oddur, Tran, Kim-Chinh, Shulenberger, Arthur M., Jonsson, Fridik Ragnar
• Primary Examiner(s): Parsa, Jafar
• Application Number:
  US11/725,716
• Publication Number:
  US 20070244208A1
• Time in Patent Office: 1,911 Days
• Field of Search: 568/884, 568/885, 518/700, 518/702, 518/703, 518/704
• US Class Current: 518/700
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0244 the reforming step being an autothermal reforming step, e.g. secondary reforming processes
• CPC Class Codes: C01B 2203/0255 containing a non-catalytic partial oxidation step
• CPC Class Codes: C01B 2203/0261 containing a catalytic partial oxidation step [CPO]
• CPC Class Codes: C01B 2203/062 Hydrocarbon production, e.g. Fischer-Tropsch process
• CPC Class Codes: C01B 2203/1247 Higher hydrocarbons
• CPC Class Codes: C01B 2203/84 Energy production
• CPC Class Codes: C01B 3/34 by reaction of hydrocarbons with gasifying agents
• CPC Class Codes: C07C 29/1516 Multisteps
• CPC Class Codes: C07C 31/04 Methanol
• CPC Class Codes: C10G 2/32 with the use of catalysts
• CPC Class Codes: C10G 2300/4043 Limiting CO2 emissions
• CPC Class Codes: C10G 2300/4081 Recycling aspects
• CPC Class Codes: C10G 2300/42 Hydrogen of special source or of special composition
• CPC Class Codes: C10G 2400/02 Gasoline
• CPC Class Codes: C10G 2400/04 Diesel oil
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10K 3/026 Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y02P 30/00 Technologies relating to oil refining and petrochemical industry
• CPC Class Codes: Y02P 30/40 : Ethylene production

Abstract

A process for producing high octane fuel from carbon dioxide and water is disclosed. The feedstock for the production line is industrial carbon dioxide and water, which may be of lower quality. The end product can be high octane gasoline, high cetane diesel or other liquid hydrocarbon mixtures suitable for driving conventional combustion engines or hydrocarbons suitable for further industrial processing or commercial use. Products, such as dimethyl ether or methanol may also be withdrawn from the production line. The process is emission free and reprocesses all hydrocarbons not suitable for liquid fuel to form high octane products. The heat generated by exothermic reactions in the process is fully utilizes as is the heat produced in the reprocessing of hydrocarbons not suitable for liquid fuel.

Claims

1. A process for production of a liquid fuel from carbon dioxide and water using electricity, comprising:

(a) capturing carbon dioxide from a concentrated carbon dioxide stream within a mixed industrial gas stream;

(b) purifying said concentrated carbon dioxide by separating other constituents from said mixed industrial gas stream;

(c) providing water and electricity and electrolyzing the water into hydrogen and oxygen;

(d) reacting a mixture of purified carbon dioxide from step (b) and hydrogen in the presence of a catalyst to produce methanol, carbon monoxide, water, and at least one hydrocarbon byproduct wherein heat is generated and controlled by increasing the relative amount of said carbon monoxide to increase said heat and/or by adding said carbon dioxide to decrease said heat;

(e) reacting methanol and a mixture of said carbon monoxide and unreacted hydrogen from step (d) in at least one step to obtain said liquid fuel; and

(f) reacting oxygen from step (c) and said at least one hydrocarbon byproduct to produce additional carbon monoxide and hydrogen for increased production of said liquid fuel.

2. The process of claim 1, further comprising the steps of:

(g) separating hydrocarbon byproducts from said liquid fuel;

(h) reacting said separated hydrocarbon byproducts from step (g) to produce said carbon monoxide and/or said carbon dioxide, said hydrogen, and water; and

(i) introducing said carbon monoxide and/or carbon dioxide and said hydrogen produced in step (h) to the reactions of step(s) (d) and/or (e) to produce said liquid fuel.

3. The process of claim 1, further comprising the steps of:

(g) separating hydrocarbon byproducts from said liquid fuel;

(h) reacting said separated hydrocarbon byproducts with oxygen in a total oxidation process to produce said carbon dioxide, and water;

(i) introducing said carbon dioxide produced in said oxidation process in step (h) to the reaction of step (d) to produce said carbon monoxide; and

(j) introducing the water produced in said oxidation process in step (h) to the reaction of step (c) to produce said hydrogen.

4. The process of claim 1, wherein heat from said liquid fuel synthesis in step (e) is utilized to drive the production of said carbon monoxide and said water in step (d).

5. The process of claim 1, wherein said mixed industrial gas stream is selected from the group consisting of a geothermal power plant, an aluminum plant, a coal fired power plant, and a cement production plant.

6. The process of claim 1, wherein said liquid fuel synthesis in step (e) comprises a one-step Fisher-Tropsch type process for producing said liquid fuel including gasoline and/or diesel.

7. The process of claim 1, wherein said hydrocarbon byproducts comprise one or more of the components selected from the group of unsaturated and saturated, linear and branched C1-C4 hydrocarbons including methane, ethane, ethene, ethyne, butane, butene, tert-butane, propane and isobutane.

8. The process of claim 1, wherein the reactant mixture of step (d) and (e) is optimized to maximize desired products yield.

9. The process of claim 1, wherein total electrical energy consumption of the electrolysis step (c) is lowered by using excess energy from recycling of hydrocarbons not suitable for use as said liquid fuel and/or by using excess energy from exothermic steps in the production process.

10. The process of claim 1, wherein the total electrical energy consumption of the electrolysis step (c) is lowered by using heat energy generated in other step(s) of the process for compression of the electrolysis products.

11. The process of claim 1, wherein the total electrical energy consumption of the electrolysis step (c) is lowered by using heat energy generated in other step(s) of the process converted to electric energy to supply electric power to the electrolysis.

12. The process of claim 1, wherein the product ratio of said carbon monoxide to said methanol is optimized to an extent where the exothermic synthesis of said methanol supplies most or all of the required heat to run the mildly endothermic production of carbon monoxide.

13. The process of claim 1, wherein product ratio, including said methanol formation, is controlled by adjusting composition of said carbon monoxide and said hydrogen in step (e).

14. The process of claim 1, wherein generated heat in the process is used for compression, preheating of reactant streams, or to drive endothermic reactions in the process.

15. The process of claim 1, wherein work required for compression is reduced by utilizing said carbon dioxide provided in pressurized, liquefied, or frozen condition.

16. The process of claim 1, wherein work required for compression is reduced by utilizing multistage, intercooled, compression of input streams at the lowest available temperature.

17. The process of claim 1, wherein work required for compression is reduced by operating an electrolysis system at elevated pressure.

18. The process of claim 1, wherein a part of the unreacted hydrogen from step (d) is removed by semi-permeable membrane means and recycled in the process.

19. The process of claim 1, wherein said hydrocarbon byproducts are reacted with oxygen in step (f) in a process selected from the group consisting of a partial oxidation process, an auto thermal process, a steam reforming process, and a total oxidation process to produce said carbon monoxide and said hydrogen.

20. The process of claim 1, wherein the synthesis of said liquid fuel in step (e) comprises the production of any one or combination of dimethyl ether, methanol, gasoline, and diesel.

21. The process of claim 20, wherein the liquid fuel synthesis in step (e) comprises a two-step process of (i) producing dimethyl ether, and (ii) producing gasoline.

22. The process of claim 20, wherein said liquid fuel synthesis in step (e) comprises a two-step process of (i) producing dimethyl ether, and (ii) producing diesel.

23. The process of claim 20, wherein said liquid fuel synthesis in step (e) comprises at least three sub-steps comprising (i) producing methanol, (ii) producing dimethyl ether, and (iii) producing gasoline.

24. The process of claim 20, wherein said liquid fuel synthesis in step (e) comprises at least three sub-steps comprising (i) producing methanol, (ii) producing dimethyl ether, and (iii) producing diesel.

25. The process of claim 1, wherein removal of at least a part of said carbon dioxide in the product stream from step (d) is done by at least one of condensation and adsorption.