Particles for use in electrophoretic displays

• US 8,199,395 B2
• Filed: 08/05/2011
• Issued: 06/12/2012
• Est. Priority Date: 07/13/2006
• Status: Active Grant

• Current Assignee: E Ink Holdings Incorporated
• Original Assignee: E Ink Holdings Incorporated
• Inventors: Whitesides, Thomas H., Oleson, Andrew Y.
• Primary Examiner(s): Pinkney, Dawayne
• Application Number:
  US13/198,855
• Publication Number:
  US 20110284808A1
• Time in Patent Office: 312 Days
• Field of Search: 359/296, 349/33, 345/49, 345/105, 345/107, 430/31, 430/32, 204/450, 204/600, 250/70, 250/208.1, 438/929
• US Class Current: 359/296
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

A particle for use in an electrophoretic display comprises a light-scattering inorganic core and a light-transmissive colored shell of an organic pigment. The core may be titania and the shell may be formed of particles having an average particle size less than 700 nm. The particles are produced by treating a light-scattering inorganic pigment with a polymer which adsorbs on both the inorganic pigment and an organic pigment; and adding the organic pigment and allowing the organic pigment to mix with the polymer-coated inorganic pigment. The particles may have a polymer coating.

Claims

1. A process for producing a particle comprising a light-scattering inorganic core and a light-transmissive colored shell of an organic pigment, the process comprising:

treating a light-scattering inorganic pigment with a polymer which adsorbs on both the inorganic pigment and an organic pigment; and

adding the organic pigment and allowing the organic pigment to mix with the polymer-coated inorganic pigment, thus forming the particle, wherein the inorganic pigment comprises titania.

2. A process according to claim 1 wherein the particle formed is thereafter

(a) reacted with a reagent having a functional group capable of reacting with, and bonding to, the particle, and also having a polymerizable or polymerization-initiating group, whereby the functional group on the reagent reacts with the particle surface and attaches the polymerizable group thereto;

and

(b) the product of step (a) is reacted with at least one monomer or oligomer under conditions effective to cause reaction between the polymerizable or polymerization-initiating group on the particle and the at least one monomer or oligomer, thereby causing the formation of polymer bonded to the particle.

3. A process according to claim 2 wherein the polymerizable group on the reagent is a vinyl group, and this vinyl group is polymerized with the monomer or oligomer by free radical polymerization.

4. A process according to claim 2 wherein the reagent used in step (a) is a silane coupling agent.

5. A process according to claim 1 wherein, after the light-scattering inorganic pigment has been treated with the polymer, excess polymer is washed from the inorganic pigment before the polymer-coated inorganic pigment is contacted with the organic pigment.