Active metal/aqueous electrochemical cells and systems
First Claim
1. A battery cell, comprising:
- an active metal anode comprising an alkali metal or alkali metal alloy selected from the group consisting of binary and ternary alkali metal alloys with Ca, Mg, Sn, Ag, Zn, Bi, Al, Cd, Ga, and In, the anode having a first surface and a second surface;
a cathode structure comprising a porous electronically conductive support component, an ionically conductive component, and an electrochemically active component, wherein at least one cathode structure component comprises an aqueous constituent;
an ionically conductive protective membrane on the first surface of the anode, the membrane comprising,a first component in contact with the anode that is ionically conductive and chemically compatible with the active metal of the anode, the first component comprising a material selected from the group consisting of a composite reaction product of the active metal with a metal nitride, a composite reaction product of the active metal with a metal halide, a composite reaction product of the active metal with a metal phosphide, a reaction product of the active metal with red phosphorus, and a reaction product of the active metal with LiPON coated with a wetting layer, anda second component in contact with the first component, the second component being substantially impervious, ionically conductive and chemically compatible with the first component and the cathode structure;
wherein the first component is an in situ reaction product of active metal of the active metal anode with a first component precursor formed by application of the active metal anode to the precursor disposed on the second component.
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Abstract
Alkali (or other active) metal battery and other electrochemical cells incorporating active metal anodes together with aqueous cathode/electrolyte systems. The battery cells have a highly ionically conductive protective membrane adjacent to the alkali metal anode that effectively isolates (de-couples) the alkali metal electrode from solvent, electrolyte processing and/or cathode environments, and at the same time allows ion transport in and out of these environments. Isolation of the anode from other components of a battery cell or other electrochemical cell in this way allows the use of virtually any solvent, electrolyte and/or cathode material in conjunction with the anode. Also, optimization of electrolytes or cathode-side solvent systems may be done without impacting anode stability or performance. In particular, Li/water, Li/air and Li/metal hydride cells, components, configurations and fabrication techniques are provided.
266 Citations
45 Claims
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1. A battery cell, comprising:
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an active metal anode comprising an alkali metal or alkali metal alloy selected from the group consisting of binary and ternary alkali metal alloys with Ca, Mg, Sn, Ag, Zn, Bi, Al, Cd, Ga, and In, the anode having a first surface and a second surface; a cathode structure comprising a porous electronically conductive support component, an ionically conductive component, and an electrochemically active component, wherein at least one cathode structure component comprises an aqueous constituent; an ionically conductive protective membrane on the first surface of the anode, the membrane comprising, a first component in contact with the anode that is ionically conductive and chemically compatible with the active metal of the anode, the first component comprising a material selected from the group consisting of a composite reaction product of the active metal with a metal nitride, a composite reaction product of the active metal with a metal halide, a composite reaction product of the active metal with a metal phosphide, a reaction product of the active metal with red phosphorus, and a reaction product of the active metal with LiPON coated with a wetting layer, and a second component in contact with the first component, the second component being substantially impervious, ionically conductive and chemically compatible with the first component and the cathode structure; wherein the first component is an in situ reaction product of active metal of the active metal anode with a first component precursor formed by application of the active metal anode to the precursor disposed on the second component. - View Dependent Claims (4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24)
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2. An electrochemical cell structure, comprising:
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an active metal anode comprising an alkali metal or alkali metal alloy selected from the group consisting of binary and ternary alkali metal alloys with Ca, Mg, Sn, Ag, Zn, Bi, Al, Cd, Ga, and In, the anode having a first surface and a second surface; a porous electronically conductive support catalytic for the reduction of air or water; an ionically conductive protective membrane on the first surface of the anode, the membrane comprising, a first component in contact with the anode that is ionically conductive and chemically compatible with the active metal of the anode, the first component comprising a material selected from the group consisting of a composite reaction product of the active metal with a metal nitride, a composite reaction product of the active metal with a metal halide, a composite reaction product of the active metal with a metal phosphide, a reaction product of the active metal with red phosphorus, and a reaction product of the active metal with LiPON coated with a wetting layer, and a second component in contact with the first component, the second component being substantially impervious, ionically conductive and chemically compatible with the first component, the catalytic electronically conductive support, and aqueous environments; wherein the first component is an in situ reaction product of active metal of the active metal anode with a first component precursor formed by application of the active metal anode to the precursor disposed on the second component. - View Dependent Claims (25, 26, 27)
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3. A method of making a battery cell, comprising:
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assembling an active metal anode comprising an alkali metal or alkali metal alloy selected from the group consisting of binary and ternary alkali metal alloys with Ca, Mg, Sn, Ag, Zn, Bi, Al, Cd, Ga, and In, the anode, and a cathode structure comprising an electronically conductive component and an aqueous constituent; wherein a protective membrane is disposed between the active metal anode and the cathode structure, the membrane being ionically conductive and chemically compatible with an active metal on a first side, and substantially impervious, ionically conductive and chemically compatible the cathode structure on the other side; and wherein an active metal material is applied to the first side of the protective membrane to form the active metal anode. - View Dependent Claims (28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45)
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Specification