Method of using a thermal plasma to produce a functionally graded composite surface layer on metals

• US 8,203,095 B2
• Filed: 04/16/2007
• Issued: 06/19/2012
• Est. Priority Date: 04/20/2006
• Status: Expired due to Fees

• Current Assignee: Ats Mer, LLC
• Original Assignee: Materials and Electrochemical Research Corporation
• Inventors: Storm, Roger S., Shapovalov, Vladimir, Withers, James C., Loutfy, Raouf
• Primary Examiner(s): PASCHALL, MARK H
• Application Number:
  US11/735,939
• Publication Number:
  US 20080000881A1
• Time in Patent Office: 1,891 Days
• Field of Search: 219/121.47, 219/121.58, 219/121.59, 219/121.48, 219/121.4, 219/121.43, 219/121.41, 219/75, 428/610, 204/298.33, 148/222
• US Class Current: 219/121.47
• CPC Class Codes: C23C 26/00 Coating not provided for in groups C23C2/00 - C23C24/00
• CPC Class Codes: C23C 8/24 Nitriding
• CPC Class Codes: C23C 8/36 using ionised gases, e.g. ionitriding

Abstract

A method of material treatment in which the surface of a metal substrate is converted to a composite structure of the metal and its nitride or carbide utilizing a high temperature chemically active thermal plasma stream, and the product obtained from that method. The complex thermal plasma contains controllable additions of active gas, liquid or solid substances. The surface layer obtained is functionally graded to the substrate resulting in an excellent bond that resists delamination and spalling, and provides a significant increase in hardness, wear and erosion resistance, and corrosion resistance, and a decrease in coefficient of friction.

Claims

1. A method of providing a surface layer on an electrically conductive work piece substrate, the method comprising:

using a scanning plasma torch to impinge a high temperature arc plasma stream on the surface of the work piece, said plasma stream comprising an initial plasma stream and a stream of nitrogen gas or a carbon containing gas that is blended into the initial plasma stream, said work piece forming an electrode and completing an electrical circuit with said plasma arc and the torch power supply, said plasma having sufficient energy to ionize the nitrogen gas or the carbon containing gas, so as to heat the surface of the substrate to a temperature below the melting point of the metal;

causing the metal substrate to react with the nitrogen ions or carbon ions forming a composite surface layer of the metal and the corresponding metal nitride or the corresponding metal carbide; and

directing a cooling jet stream of an inert gas onto the plasma heated area of the substrate.

2. The method of claim 1, wherein the initial plasma gas comprises at least one of Ar, He, and a mixture of Ar and H₂, and N₂ is blended into the hot plasma gas in a controlled manner so as to achieve homogeneous mixing.

3. The method of claim 1, wherein the plasma torch comprises a plasma transferred arc, TIG, or MIG torch.

4. The method of claim 1, wherein the metal substrate comprises a metal selected from the group consisting of Ti, Ta, Cr, Fe, Ni, Co, Al and, an alloy of one or more of said metals.

5. The method of claim 1, wherein a carbon containing gas is used in addition to the N₂ gas.

6. The method of claim 1, wherein the surface layer has a thickness of from about 5 microns to about 2500 microns.

7. The method of claim 1, wherein the increase in hardness is at least about 10% as measured by the Rockwell C method.

8. The method of claim 1, wherein the substrate is Ti-6-4 and the hardness of the coated substrate is from about 45 to about 85 as measured by the Rockwell C method compared to a hardness of about 34-39 for the unreacted Ti-6-4.

9. The method of claim 1, wherein the substrate surface is heated to a temperature of about 10°

C. to about 200°

C. below that of the melting point of the substrate.

10. A method according to claim 1, wherein the plasma stream has a temperature in a range from about 3,000°

C. to about 10,000°

C., a pressure from about 0.01 to about 0.5 Mpa, and power density from about 10 to about 1000 W/mm².

11. A method of thermo-chemical treatment including nitriding, carbonizing, carbonitriding, and boronating of a metal work piece substrate using a direct arc plasma stream, comprising the steps of:

providing said metal work piece;

using the work piece as an electrode to create an initial high temperature arc plasma stream;

blending nitrogen and/or carbon containing gases and/or BCl₃ inside of said plasma stream causing decomposition of said gases to atoms and ionization of the atoms to obtain an active plasma mix;

scanning said active plasma mix in a stream along a surface of said substrate in a duration sufficient to locally heat said substrate to a temperature about 5-200°

C. lower than the melt temperature of the substrate to permit nitrogen and/or carbon ions and/or boron ions to be absorbed by the heated area; and

directing a cooling jet stream of an inert gas onto the plasma heated area of the substrate to obtain a desired structure or property in at least part of said substrate.

12. The method of claim 11, wherein the plasma stream has an initial temperature between about 3,000-10,000°

C., a pressure between about 0.01-0.5 Mpa, a gas composition of pure argon or argon containing up to 5% of hydrogen, and a power density between 10-1000 W/mm².

13. The method of claim 11, including the step of controlling direction and linear speed of said active gas or gas mix.

14. The method of claim 11, including the step of controlling direction and linear speed of materials flowing inside said plasma stream.

15. The method of claim 13, wherein the direction and linear speed of said active gas or gas mix, or the direction and linear speed of materials flowing inside said plasma stream are controlled based on initial plasma stream parameters.

16. A method of claim 11, including the step of controlling distance between the plasma torch and substrate surface, and contact time.

17. A method of claim 11, including the step of controlling trajectory and linear speed of said trajectory.

18. A method of claim 11, including the step of controlling cooling based on a temperature difference between an initial substrate temperature and the temperature in a spot of contact of said plasma stream with said substrate surface, and an initial temperature of said substrate, and the parameters of artificial cooling or preheating of the substrate.