Soil remediation method and composition

• US 8,206,062 B2
• Filed: 04/30/2010
• Issued: 06/26/2012
• Est. Priority Date: 03/27/2006
• Status: Active Grant

• Current Assignee: Ethical Solutions, LLC
• Original Assignee: VeruTEK Technologies, Inc.
• Inventors: Hoag, George E., Collins, John
• Primary Examiner(s): Lorengo, Jerry
• Assistant Examiner(s): Smith, Jennifer
• Application Number:
  US12/771,210
• Publication Number:
  US 20100209193A1
• Time in Patent Office: 788 Days
• Field of Search: 4051281-131, 588312-400
• US Class Current: 405/128.15
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: C11D 3/0084 Antioxidants; Free-radical scavengers
• CPC Class Codes: C11D 3/188 Terpenes
• CPC Class Codes: C11D 3/382 Vegetable products, e.g. soya meal, wood flour, sawdust
• CPC Class Codes: C11D 3/39 Organic or inorganic per-compounds

Abstract

A method for in-situ reduction of contaminants in soil.

Claims

1. A method for determining a subsurface contaminant remediation protocol, comprising:

collecting a soil sample from the subsurface;

identifying at least one target contaminant for concentration reduction;

choosing a surfactant and optionally choosing a cosolvent for injection into the subsurface to solubilize and/or desorb the at least one target contaminant;

choosing an oxidant and optionally choosing an activator for the oxidant for injection into the subsurface to oxidize the target contaminant; and

choosing the quantity of surfactant for injection into the subsurface to form a Winsor I system or a submicellar surfactant solution or a microemulsion;

injecting the surfactant and the oxidant into the soil sample; and

measuring an initial surfactant concentration in the soil sample and a final surfactant concentration in the soil sample after a period of time,

wherein the surfactant resists oxidation by the oxidant, and the surfactant increases oxidation of the at least one target contaminant in the soil sample,

wherein the contaminant comprises a nonaqueous phase liquid (NAPL), and

wherein at least 40% of the initial mass of the contaminant is destroyed in situ in the sample.

2. The method of claim 1, further comprising collecting a contaminant sample from the subsurface.

3. The method of claim 1, further comprising

choosing an antioxidant for injection into the subsurface;

injecting the antioxidant into the soil sample; and

determining the type and quantity of surfactant and optionally of cosolvent required to solubilize or desorb the target contaminant in a batch experiment.

4. The method of claim 1, further comprising optimizing the hydrophile/lipophile balance (HLB) ratio of the surfactant or surfactants of a solution to be injected, in order to maximize the solubility of the target contaminant.

5. The method of claim 1, further comprising determining the spatial mass distribution of the target contaminant in the subsurface.

6. The method of claim 1, further comprising determining the spatial concentration distribution of the target contaminant in the subsurface.

7. The method of claim 6, further comprising determining a hydrogeological property of the subsurface.

8. The method of claim 7, wherein the hydrogeological property is selected from the group consisting of water saturated zones, water unsaturated zones, hydraulic gradient, saturated thickness, soil composition, hydraulic conductivity, porosity, density, and variation of any of these with time or space.

9. The method of claim 7, wherein the hydrogeological property is a physical property or a chemical property.

10. The method of claim 7, further comprising using the determined spatial concentration distribution of the target contaminant and the hydrogeological property to determine an optimal location of an injection site for introducing the surfactant and oxidant and optionally the solvent and optionally the activator and an optimal amount of surfactant and oxidant and optionally the solvent and optionally the activator to introduce at each injection site.

11. The method of claim 10, wherein determining the optimal location of an injection site comprises modeling the flow of surfactant and oxidant and optionally the solvent and optionally the activator in the subsurface and selecting an injection site from which the surfactant and oxidant and optionally the solvent and optionally the activator will flow to the target contaminant.

12. The method of claim 10, wherein determining the optimal amount of surfactant and oxidant and optionally the solvent and optionally the activator comprises determining the amount of surfactant and oxidant and optionally the amount of solvent and optionally the amount of activator to oxidize at least 90% of the target contaminant.

21. The method of claim 1, wherein the oxidant comprises hydrogen peroxide, a peroxide, and/or a peroxide containing compound.

13. A method for determining a subsurface contaminant remediation protocol, comprising:

collecting a soil sample from the subsurface;

identifying at least one target contaminant for concentration reduction;

choosing a surfactant or surfactants and optionally choosing a solvent for injection into the subsurface to desorb and solubilize the at least one target contaminant;

choosing an oxidant and optionally choosing an activator for injection into the subsurface to oxidize the target contaminant;

choosing the quantity of surfactant for injection into the subsurface to form a Winsor I system or a microemulsion;

determining the spatial concentration distribution of the target contaminant;

determining a hydrogeological property of the subsurface; and

using the determined spatial concentration distribution of the target contaminant and the hydrogeological property to determine the target depth for the surfactant and oxidant and optionally for the solvent and activator,

injecting the surfactant and the oxidant into the soil sample; and

measuring an initial surfactant concentration in the soil sample and a final surfactant concentration in the soil sample after a period of time,

wherein the surfactant resists oxidation by the oxidant, and the surfactant increases oxidation of the at least one target contaminant in the soil sample,

wherein the contaminant comprises a nonaqueous phase liquid (NAPL), and

wherein at least 40% of the initial mass of the contaminant is destroyed in situ in the sample.

14. The method of claim 13, further comprising collecting at least one contaminant sample from the subsurface.

15. The method of claim 13, further comprising selecting the ratio of the mass of surfactant and oxidant and optionally of solvent and activator to the mass of an introduced substance to maximize the fraction of surfactant and oxidant and optionally of solvent and activator that remains at the target depth.

16. The method of claim 15, wherein the introduced substance comprises water.

17. The method of claim 15, wherein if the at least one target contaminant resides above the water table, then the ratio of the mass of surfactant and oxidant and optionally of solvent and activator to the mass of the introduced substance is selected so that the density of the introduced substance is less than 1 gram/cm³.

18. The method of claim 15, wherein if the at least one target contaminant resides below the water table, then the ratio of the mass of surfactant and oxidant and optionally of solvent and activator to the mass of the introduced substance is selected so that the density of the introduced substance is greater than 1 gram/cm³.

19. The method of claim 15, wherein if the at least one target contaminant resides at about the same level as the water table, then the ratio of the mass of surfactant and oxidant and optionally of solvent and activator to the mass of the introduced substance is selected so that the density of the introduced substance is about 1 gram/cm³.

20. The method of claim 15, further comprising choosing a non-oxidant, non-activator salt for injection into the subsurface to maximize the fraction of surfactant and oxidant and optionally of solvent and activator that remains at the target depth and choosing an antioxidant for injection into the subsurface.

22. The method of claim 13, wherein the oxidant comprises hydrogen peroxide, a peroxide, and/or a peroxide containing compound.