Fuel cell system and starting method therefor

• US 8,206,858 B2
• Filed: 01/20/2006
• Issued: 06/26/2012
• Est. Priority Date: 01/24/2005
• Status: Expired due to Fees

• Current Assignee: Yamaha Hatsudoki Kabushiki Kaisha (Yamaha Corporation)
• Original Assignee: Yamaha Hatsudoki Kabushiki Kaisha (Yamaha Corporation)
• Inventors: Oishi, Masatsugu, Muramatsu, Yasuyuki
• Primary Examiner(s): Ha, Nathan
• Assistant Examiner(s): Jung, Michael
• Application Number:
  US11/814,630
• Publication Number:
  US 20090130497A1
• Time in Patent Office: 2,349 Days
• Field of Search: None
• US Class Current: 429/429
• CPC Class Codes: B60L 58/31 for starting of fuel cells
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 16/006 of fuel cells with rechargeable batteries
• CPC Class Codes: H01M 2250/20 Fuel cells in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/04164 by condensers, gas-liquid separators or filters
• CPC Class Codes: H01M 8/04186 of liquid-charged or electrolyte-charged reactants
• CPC Class Codes: H01M 8/04194 Concentration measuring cells
• CPC Class Codes: H01M 8/04216 characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
• CPC Class Codes: H01M 8/04225 during start-up
• CPC Class Codes: H01M 8/04302 applied during start-up
• CPC Class Codes: H01M 8/04313 characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
• CPC Class Codes: H01M 8/0432 Temperature; Ambient temperature
• CPC Class Codes: H01M 8/04328 of anode reactants at the inlet or inside the fuel cell
• CPC Class Codes: H01M 8/04365 of other components of a fuel cell or fuel cell stacks
• CPC Class Codes: H01M 8/04447 of anode reactants at the inlet or inside the fuel cell
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04589 of fuel cell stacks
• CPC Class Codes: H01M 8/04708 of fuel cell reactants
• CPC Class Codes: H01M 8/04716 of fuel cell exhausts
• CPC Class Codes: H01M 8/04753 : of fuel cell reactants
• CPC Class Codes: H01M 8/0488 : of fuel cell stacks
• CPC Class Codes: H01M 8/0494 : of fuel cell stacks
• CPC Class Codes: H01M 8/04947 : of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/0662 : Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: H01M 8/1011 : Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
• CPC Class Codes: Y02E 60/10 : Energy storage using batteries
• CPC Class Codes: Y02E 60/50 : Fuel cells
• CPC Class Codes: Y02T 90/40 : Application of hydrogen technology to transportation, e.g. using fuel cells

Abstract

A fuel cell system and a starting method therefor are capable of setting a start-up mode which is appropriate to energy stored in a secondary battery so as to eliminate problems in starting the fuel cell system. The fuel cell system includes a fuel cell, a secondary battery which is electrically connected with the fuel cell, a secondary-battery charge-amount detection unit which detects an amount of charge in the secondary battery, and a memory which stores at least one threshold value for determining the start-up mode of the fuel cell system. Stored electric energy which corresponds to the amount of charge in the secondary battery is calculated, and a start-up mode of the fuel cell system is determined based on the electric energy stored in the secondary battery and the threshold value stored in the memory.

Claims

1. A fuel cell system connected with a load, the fuel cell system comprising:

a fuel cell;

a secondary battery electrically connected with the fuel cell;

a data gathering unit to obtain data concerning electric energy stored in the secondary battery;

a determination unit to determine one of a plurality of start-up modes, differing from each other in energy consumption, for the fuel cell system based on the obtained data concerning electric energy stored in the secondary battery; and

a memory programmed to store at least one threshold value used to determine the one of the plurality of start-up modes of the fuel cell system, wherein the determination unit determines the one of the plurality of start-up modes of the fuel cell system based on the data concerning electric energy stored in the secondary battery and the at least one threshold value stored in the memory;

wherein

the at least one threshold value includes a first energy start threshold value representing energy necessary to start the fuel cell system, and the determination unit includes a start determination unit to determine whether or not to start the fuel cell system based on the data concerning electric energy stored in the secondary battery and the first energy start threshold value; and

the at least one threshold value includes a second energy start threshold value representing normal-consumption energy necessary to start the fuel cell system in a normal mode, and the start determination unit determines whether to start the fuel cell system in the normal mode or in a low consumption mode based on the data concerning electric energy stored in the secondary battery and the second energy start threshold value.

2. The fuel cell system according to claim 1, wherein the memory is programmed to store a third energy start threshold value representing a sum of the normal-consumption energy necessary to start the fuel cell system in the normal mode and a load energy demand necessary to drive the load normally, and the fuel cell system further comprises another determination unit to determine whether or not to drive the load normally based on the data concerning electric energy stored in the secondary battery and the third energy start threshold value.

3. The fuel cell system according to claim 1, wherein the fuel cell is configured to receive aqueous fuel solution and use the aqueous fuel solution to generate power.

4. The fuel cell system according to claim 1, wherein the load includes at least a motor of transportation equipment.

5. A method of starting a fuel cell system connected with a load, the system including a fuel cell and a secondary battery electrically connected with the fuel cell, the method comprising the steps of:

obtaining data concerning electric energy stored in the secondary battery;

determining one of a plurality of start-up modes differing from each other in energy consumption for the fuel cell system based on the obtained data concerning electric energy stored in the secondary battery; and

operating the fuel cell system in accordance with the determined mode;

wherein

the step of determining one of a plurality of start-up modes includes the steps of;

determining the one of the plurality of start-up modes of the fuel cell system based on the data concerning electric energy stored in the secondary battery and at least one threshold value; and

determining whether or not to start the fuel cell system based on the data concerning electric energy stored in the secondary battery and a first energy start threshold value representing energy necessary to start the fuel cell system, wherein the at least one threshold value includes the first energy start threshold value; and

a predetermined voltage for determining whether or not the fuel cell is disconnected from the secondary battery is set to a lower value when starting the fuel cell system in a low consumption mode than when starting in a normal mode, the determination on whether or not the fuel cell is disconnected from the secondary battery being made based on an output voltage of the fuel cell and the predetermined voltage.

6. The method of starting a fuel cell system according to claim 5, wherein the at least one threshold value includes a second energy start threshold value representing normal-consumption energy necessary to start the fuel cell system in the normal mode, and whether to start the fuel cell system in the normal mode or in the low consumption mode being determined based on the data concerning electric energy stored in the secondary battery and the second energy start threshold value.

7. The method of starting a fuel cell system according to claim 5, further comprising the step of using a second energy start threshold value representing a sum of normal-consumption energy necessary for starting the fuel cell system in the normal mode and a load energy demand necessary for driving the load normally, and

whether or not to drive the load normally being determined based on the data concerning electric energy stored in the secondary battery and the second energy start threshold value, the load being driven normally or in a mode other than normal driving in accordance with a result of the determination.

8. The method of starting a fuel cell system according to claim 7, wherein the load being driven in a mode other than normal driving is switched to normal driving when electric energy stored in the secondary battery is not lower than energy represented by the second energy start threshold value.

9. The method of starting a fuel cell system according to claim 5, further comprising the step of using an aqueous solution tank for storing aqueous fuel solution to be supplied to the fuel cell, wherein an amount of aqueous solution in the aqueous solution tank is not controlled when the fuel cell system is started in the low consumption mode.

10. The method of starting a fuel cell system according to claim 5, wherein the fuel cell is supplied with aqueous fuel solution having a higher concentration when the fuel cell system is started in the low consumption mode than a concentration used when the system is started in the normal mode, to start power generation.

11. The method of starting a fuel cell system according to claim 5, further comprising the step of using an aqueous solution tank for storing aqueous fuel solution to be supplied to the fuel cell, wherein no control is performed for decreasing an amount of aqueous solution in the aqueous solution tank when the fuel cell system is started in the low consumption mode.

12. The method of starting a fuel cell system according to claim 5, further using an air pump for supplying the fuel cell with air containing oxygen, wherein the air pump is operated at a lower output when the fuel cell system is started in the low consumption mode than when started in the normal mode, to start power generation.

13. The method of starting a fuel cell system according to claim 5, further comprising the step of using an air pump for supplying the fuel cell with air containing oxygen, and an aqueous solution pump for supplying the fuel cell with aqueous fuel solution, wherein the air pump and the aqueous solution pump are driven alternately with each other when the fuel cell system is started in the low consumption mode.

14. A method of starting a fuel cell system connected with a load, the system including a fuel cell and a secondary battery electrically connected with the fuel cell, the method comprising the steps of:

obtaining data concerning electric energy stored in the secondary battery;

determining one of a plurality of start-up modes differing from each other in energy consumption for the fuel cell system based on the obtained data concerning electric energy stored in the secondary battery; and

operating the fuel cell system in accordance with the determined mode;

wherein

the step of determining one of a plurality of start-up modes includes the steps of;

determining the one of the plurality of start-up modes of the fuel cell system based on the data concerning electric energy stored in the secondary battery and at least one threshold value; and

determining whether or not to start the fuel cell system based on the data concerning electric energy stored in the secondary battery and a first energy start threshold value representing energy necessary to start the fuel cell system, wherein the at least one threshold value includes the first energy start threshold value; and

the fuel cell system is connected with the load when an output voltage of the fuel cell is not lower than a voltage in the secondary battery when starting the fuel cell system in a low consumption mode.

15. A method of starting a fuel cell system connected with a load, the system including a fuel cell and a secondary battery electrically connected with the fuel cell, the method comprising the steps of:

obtaining data concerning electric energy stored in the secondary battery;

determining one of a plurality of start-up modes differing from each other in energy consumption for the fuel cell system based on the obtained data concerning electric energy stored in the secondary battery; and

operating the fuel cell system in accordance with the determined mode;

wherein

the step of determining one of a plurality of start-up modes includes the steps of;

determining the one of the plurality of start-up modes of the fuel cell system based on the data concerning electric energy stored in the secondary battery and at least one threshold value; and

determining whether or not to start the fuel cell system based on the data concerning electric energy stored in the secondary battery and a first energy start threshold value representing energy necessary to start the fuel cell system, wherein the at least one threshold value includes the first energy start threshold value; and

the fuel cell is operated at a lower output voltage when the fuel cell system is started in a low consumption mode than when started in a normal mode at a same temperature of the fuel cell.