Fabricating amorphous zinc oxide semiconductor layer
First Claim
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1. A process for fabricating a semiconductor layer of an electronic device comprising:
- (a) liquid depositing a first mixture comprising a zinc oxide precursor composition;
(b) heating the deposited first mixture to a maximum temperature of from about 20 degrees C. to below about 300 degrees C. to form predominately amorphous zinc oxide from the first mixture;
(c) cooling the deposited first mixture;
(d) liquid depositing a second mixture comprising a zinc oxide precursor composition upon the predominately amorphous zinc oxide formed from the first mixture;
(e) heating the deposited second mixture to a maximum temperature of from about 20 degrees C. to below about 300 degrees C. to form predominately amorphous zinc oxide from the second mixture; and
(f) cooling the deposited second mixture,wherein the first mixture and the second mixture are different, to form at least one semiconductor layer of the electronic device.
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Abstract
A process for fabricating a semiconductor layer of an electronic device including: liquid depositing one or more zinc oxide precursor compositions and forming at least one semiconductor layer of the electronic device comprising predominately amorphous zinc oxide from the liquid deposited one or more zinc oxide precursor compositions.
6 Citations
15 Claims
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1. A process for fabricating a semiconductor layer of an electronic device comprising:
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(a) liquid depositing a first mixture comprising a zinc oxide precursor composition; (b) heating the deposited first mixture to a maximum temperature of from about 20 degrees C. to below about 300 degrees C. to form predominately amorphous zinc oxide from the first mixture; (c) cooling the deposited first mixture; (d) liquid depositing a second mixture comprising a zinc oxide precursor composition upon the predominately amorphous zinc oxide formed from the first mixture; (e) heating the deposited second mixture to a maximum temperature of from about 20 degrees C. to below about 300 degrees C. to form predominately amorphous zinc oxide from the second mixture; and (f) cooling the deposited second mixture, wherein the first mixture and the second mixture are different, to form at least one semiconductor layer of the electronic device. - View Dependent Claims (2, 3, 4, 5, 6)
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7. A process for fabricating a semiconductor layer of an electronic device comprising:
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(a) liquid depositing a zinc oxide precursor composition to result in a deposited composition; (b) heating the deposited composition to a maximum temperature of from about 20 degrees C. to about 300 degrees C. to form a predominately amorphous zinc oxide sublayer; and (c) cooling the heated deposited composition; (d) liquid depositing the zinc oxide precursor composition upon the previously deposited predominately amorphous zinc oxide sublayer; (e) heating the deposited composition to a maximum temperature of from about 20 degrees C. to about 300 degrees C. to form another predominately amorphous zinc oxide sublayer; and (f) cooling the deposited composition;
wherein the steps (d), (e), and (f) are each accomplished a number of times in any effective arrangement, resulting in the formation of a semiconductor layer formed from multiple predominately amorphous zinc oxide sublayers;wherein (d) and (e) are consecutively repeated in sequence from 1 to 9 times; and
wherein the zinc oxide precursor composition comprises a zinc compound selected from the group consisting of zinc hexafluoroacetylacetonate, zinc lactate, zinc citrate, zinc oxalate, zinc acrylate, zinc methacrylate, zinc sulfate, zinc sulfite, ethylenediaminetetraacetic acid zinc disodium salt, cobalt/barium/zinc octoate blends, zinc borate, zinc molybdate, zinc niobate, their hydrate forms, or a mixture thereof. - View Dependent Claims (8, 9, 10, 11, 12, 13, 14, 15)
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Specification