Portable water treatment method

• US 8,226,832 B2
• Filed: 04/09/2010
• Issued: 07/24/2012
• Est. Priority Date: 04/09/2010
• Status: Expired due to Fees

• Current Assignee: FQ Fraxtar, LLC
• Original Assignee: NCH Ecoservices, LLC (NCH Corporation)
• Inventors: Angelilli, Jerome F., Guccione, Patrick D., Pierce, Billy E., Williams, John H., Wong, Daniel Wai-tak
• Primary Examiner(s): Drodge, Joseph
• Application Number:
  US12/757,334
• Publication Number:
  US 20110137465A1
• Time in Patent Office: 837 Days
• Field of Search: 210/85, 210/87, 210/96.1, 210/143, 210/170.01, 210/170.09, 210/194, 210/195.1, 210/198, 210/199, 210/739, 210/747, 210/748.2, 210/754, 210/758, 210/764, 210/765, 210/805, 210/747.1, 210/747.7, 210/202, 210/205, 210/806, 175/65, 175/66, 175/207, 166/259, 166264-267, 166/271, 166/305.1, 166/308.1, 166/308.2, 166/308.3, 366/136, 366/137, 422/129, 731/520.1, 731/521.8, 731/521.9, 731/522.1, 731/522.9, 507/90, 507/200, 507/922, 436/124, 436/127
• US Class Current: 210/739
• CPC Class Codes: C02F 1/763 Devices for the addition of such compounds in gaseous form
• CPC Class Codes: C02F 2103/02 Non-contaminated water, e.g. for industrial water supply
• CPC Class Codes: C02F 2103/10 from quarries or from mining activities
• CPC Class Codes: C02F 2209/005 Processes using a programmable logic controller [PLC]
• CPC Class Codes: C02F 2209/29 Chlorine compounds
• CPC Class Codes: C02F 2209/40 Liquid flow rate
• CPC Class Codes: C02F 2301/046 Recirculation with an external loop
• CPC Class Codes: Y10T 436/19 Halogen containing

Abstract

A method that can be used in a portable system and apparatus to effectively and efficiently treat aqueous fluids by quickly and reliably adjusting and controlling the free residual level of disinfectants, contaminants or additives through the addition of one or more treating agents such as oxidizing chemicals and/or other special-purpose additives, and that can continuously store, log, retrieve and report the related fluid composition data and other operating parameters on a real-time basis at either the use site or a remote location. A preferred use for the subject method is managing the chemistry of disinfectant, contaminant and/or additive levels in aqueous fluids used in hydraulic fracturing operations, and controlling the free residual levels of the disinfectant or contaminants within the fluids, including fluids maintained in frac tanks during temporary cessation of a hydraulic fracturing operation.

Claims

1. A method for producing and continuously monitoring and controlling a concentration of chlorine dioxide in an aqueous fluid that is present at a well site, which aqueous fluid is adapted hydraulic fracturing, the method comprising:

providing at the well site a continuous, pressurized flow of the aqueous fluid through at least one fluid flow line from at least one source of aqueous fluid to at least one frac tank;

continuously determining the flow rate of the pressurized flow of the aqueous fluid;

continuously determining an initial concentration of the chlorine dioxide within the pressurized flow of the aqueous fluid;

continuously determining a treating rate capable of adjusting the initial concentration of the chlorine dioxide to a defined free residual level based upon stoichiometric demand;

automatically generating at the well site sufficient chlorine dioxide solution to achieve the defined free residual level;

treating the aqueous fluid at the well site by automatically introducing the chlorine dioxide into the aqueous fluid at the determined treating rate at an initial in-line treatment point under conditions conducive to thorough mixing of the chlorine dioxide within the pressurized flow of at least a portion of the aqueous fluid to produce treated aqueous fluid;

continuously monitoring a post-treating concentration of the chlorine dioxide within the pressurized flow of the treated aqueous fluid;

continuously comparing the post-treating concentration of the chlorine dioxide to the defined free residual level; and

selectively adjusting the post-treating concentration at the well site by recirculating at least a portion of the treated aqueous fluid from the at least one frac tank to a point upstream of where the aqueous fluid is treated.

2. The method of claim 1, comprising recirculating the treated aqueous fluid until the post-treating concentration of chlorine dioxide is acceptably close to the defined free residual level.

3. The method of claim 1 as monitored and managed by at least one programmable controller from either a remote location or at the well site.

4. The method of claim 1 wherein the post-treating concentration of chlorine dioxide is selectively adjusted by injecting additional chlorine dioxide into the treated aqueous fluid at one or more treatment points disposed downstream from the initial treatment point.

5. The method of claim 1 wherein at least a portion of the recirculated treated aqueous fluid is introduced into the pressurized flow of aqueous fluid upstream of the initial treatment point.

6. The method of claim 1 wherein a scale inhibitor is also injected into the pressurized flow of aqueous fluid.

7. The method of claim 1 wherein the pressurized flow of aqueous fluid is divided into at least one primary stream and at least one side stream, and wherein the chlorine dioxide solution is introduced into the at least one side stream.

8. The method of claim 1 wherein the aqueous fluid is selected from the group consisting of source water, produced water, fluid recirculated from the at least one frac tank, and mixtures thereof.

9. The method of claim 8 wherein at least one frac tank contains source water that is produced water.

10. The method of claim 1 wherein the aqueous fluid comprises source water received from at least two different sources.

11. The method of claim 1, further comprising providing at least one motor vehicle or towable carrier unit within which the chlorine dioxide is made and introduced into the pressurized flow of aqueous fluid and wherein the post-treating concentration is continuously monitored and selectively adjusted.

12. The method of claim 11 wherein at least one fluid flow line is looped or coiled within the at least one motor vehicle or towable carrier unit.

13. The method of claim 1 wherein the at least one frac tanks is a plurality of frac tanks and at least part of the recirculated treated aqueous fluid is recirculated selectively from at least one of the plurality of frac tanks.

14. The method of claim 13 wherein the aqueous fluid is recirculated intermittently.

15. The method of claim 1 wherein the aqueous fluid is selectively consolidated from at least two of a plurality of frac tanks into a single return header.

16. The method of claim 1 wherein the chlorine dioxide free residual level is between about 0.25 ppm and about 5.0 ppm.

17. The method of claim 1 further comprising logging and storing physical and compositional parameters of the aqueous fluid on a continuous, real-time basis.

18. The method of claim 17 further comprising selectively reporting the stored physical and compositional parameters.

19. The method of claim 1 wherein sequential treatment points are provided to facilitate continuous, real-time trimming of the chlorine dioxide free residual level.