Reducing mercury emissions from the burning of coal

• US 8,226,913 B2
• Filed: 05/02/2011
• Issued: 07/24/2012
• Est. Priority Date: 03/17/2005
• Status: Active Grant

• Current Assignee: Nox Ii Ltd. (Arthur J Gallagher & Company)
• Original Assignee: Nox Ii Ltd. (Arthur J Gallagher & Company)
• Inventors: Comrie, Douglas C.
• Primary Examiner(s): VANOY, TIMOTHY C
• Application Number:
  US13/098,973
• Publication Number:
  US 20110203499A1
• Time in Patent Office: 449 Days
• Field of Search: 423/210, 423/244.01, 423/244.04, 423/244.07, 423/DIG.5, 431/2, 431/8, 110/186, 110/188, 110/203, 110/218, 110/324, 110/344, 110/345, 502/400, 502/407, 502/414, 106/705, 106/713, 106/718, 106/734, 422/108, 422/110, 422/111
• US Class Current: 423/210
• CPC Class Codes: B01D 53/508 by treating the gases with solids
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: C04B 18/065 Residues from coal gasification
• CPC Class Codes: C04B 18/162 Cement kiln dust; Lime kiln dust
• CPC Class Codes: C04B 20/023 Chemical treatment
• CPC Class Codes: C04B 2103/0088 Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes
• CPC Class Codes: C04B 28/04 Portland cements
• CPC Class Codes: C04B 40/0039 Premixtures of ingredients
• CPC Class Codes: C04B 40/0608 Dry ready-made mixtures, e.g. mortars at which only water or a water solution has to be added before use
• CPC Class Codes: C10L 10/00 Use of additives to fuels or fires for particular purposes additives for liquid carbonaceous fuels characterised by their chemical nature C10L1/10; using binders for briquetting solid fuels C10L5/10; using additives to improve the combustion of solid fuels C10L9/10
• CPC Class Codes: C10L 10/02 for reducing smoke development
• CPC Class Codes: C10L 9/10 by using additives
• CPC Class Codes: F23J 15/003 for supplying chemicals to fumes, e.g. using injection devices
• CPC Class Codes: F23J 2215/60 Heavy metals; Compounds thereof
• CPC Class Codes: F23J 7/00 Arrangement of devices for supplying chemicals to fire
• CPC Class Codes: F23K 1/00 Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
• CPC Class Codes: F23K 2201/505 with additives
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete
• CPC Class Codes: Y10S 423/05 Automatic, including computer, control

Abstract

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Claims

1. A process for burning mercury containing fuel in a furnace of a fuel burning system to reduce the amount of mercury released from the system into the environment, the process comprising:

adding a sorbent composition comprising bromine or iodine onto the coal upstream of the furnace;

delivering the fuel with the applied sorbent composition into the furnace;

adding sorbent components comprising calcium, silica, and alumina into the furnace where the temperature is greater than 2000°

F.; and

combusting the fuel in the furnace to produce combustion gases, ash and heat energy.

2. A process according to claim 1, wherein the fuel is coal.

3. A process according to claim 1, wherein the sorbent composition comprises a bromine compound.

4. A process according to claim 1, wherein the sorbent composition comprises calcium bromide.

5. A process according to claim 1, wherein the sorbent composition comprises a solution of a bromine compound.

6. A process according to claim 1, wherein the sorbent composition comprises an iodine compound.

7. A process according to claim 1, wherein the temperature is greater than 2300°

F.

8. A process according to claim 1, wherein the temperature is 2700°

F.-3600°

F.

9. A process according to claim 2, wherein the ash contains 90% or more by weight of the mercury originally in the coal.

10. A process according to claim 1, wherein the amount of mercury in the ash is increased and the amount of acid leachable mercury in the ash is decreased, compared to the respective levels found in ash produced by burning coal without the added sorbent composition and the sorbent components comprising calcium, silica, and alumina.

11. A process for reducing the amount of mercury escaping from a facility upon combustion of a mercury containing fuel in a furnace of the facility, the process comprising:

adding a first sorbent composition comprising bromine onto the fuel upstream of the furnace;

delivering the fuel with the added sorbent composition into the furnace;

adding a second sorbent composition comprising 50-98% by weight of an alkaline powder containing calcium and 2-50% by weight of an aluminosilicate material into the furnace where the temperature is greater than 2000°

F.; and

combusting the fuel in the furnace to produce ash, combustion gases, and heat energy.

12. A process according to claim 11, wherein the fuel is coal.

13. A process according to claim 11, further comprising measuring the mercury level in the combustion gases and adjusting the amount of bromine added depending on the measured mercury level.

14. A process according to claim 12, wherein the ash contains 90% or more by weight of the mercury originally in the coal.

15. A process according to claim 12, wherein the ash has a higher mercury concentration but a lower acid leachable concentration than ash produced from burning coal without the added first and second compositions.

16. A process according to claim 12, wherein the temperature is 2700-3600°

F.

17. A process according to claim 12, wherein the alkaline powder containing calcium comprises one or more of Portland cement, lime kiln dust, and cement kiln dust.

18. A process according to claim 17, wherein the alkaline powder containing calcium comprises cement kiln dust and lime kiln dust.

19. A process according to claim 12, wherein the aluminosilicate material comprises calcium montmorillonite, sodium montmorillonite, or kaolin.

20. A process according to claim 12, wherein the first composition comprises calcium bromide.

21. A method of burning coal with reduced levels of undesirable elements escaping into the environment, comprising:

applying a solution of calcium bromide onto the coal;

delivering the coal with the calcium bromide applied into a coal burning furnace;

injecting a powder sorbent comprising an aluminosilicate mineral and one or more of portland cement, cement kiln dust, and lime kiln dust into the furnace where the temperature is greater than 1000°

F.; and

combusting the coal in the presence of the added calcium bromide and the injected powder to produce ash, combustion gases, and heat energy.

22. A method according to claim 21, wherein the powder sorbent comprises cement kiln dust and lime kiln dust.

23. A method according to claim 21, wherein the temperature is greater than 1500°

F.

24. A method according to claim 21, wherein the temperature is greater than 2000°

F.

25. A method according to claim 21, wherein the temperature is greater than 2300°

F.

26. A method according to claim 21, wherein the temperature is 2700°

F.-3600°

F.

27. A method according to claim 21, wherein the ash has a higher mercury level but a lower acid leachable level in comparison to ash prepared by burning the coal without the applied calcium bromide and powder sorbent.

28. A method according to claim 21, wherein the ash contains 90% or more of the total weight of mercury originally present in the coal prior to combustion.

29. A method according to claim 21, wherein the powder sorbent comprises 2-50% by weight aluminosilicate and 50-98% by weight of a mixture of cement kiln dust and lime kiln dust.

30. A method according to claim 21, comprising adding the calcium bromide at a rate 0.01-1% by weight of solid calcium bromide and adding the powder sorbent at a rate of 0.01-10% by weight, both based on the amount of coal being consumed by combustion.

31. A method according to claim 21, wherein the solution of calcium bromide is 50% by weight calcium bromide solution in water.

32. A method for reducing mercury levels in the flue gases resulting from combustion of the coal in the furnace of a coal burning system, the method comprising:

applying sorbent components comprising halogen, calcium, silica, and alumina onto coal;

delivering the coal with the applied sorbent components into the furnace; and

combusting the coal with the applied sorbent components in the furnace to produce ash, combustion gases, and heat energy.

33. A method according to claim 32, further comprising measuring a mercury level in the combustion gases and adjusting the amount of halogen applied onto the coal based on the value of the mercury level.

34. A method according to claim 32, further comprising measuring acid leaching of mercury from the ash and adjusting the amount of silica and alumina applied onto the coal based on the value of the measured leaching.

35. A method according to claim 32, comprising adding a liquid composition comprising a bromine compound onto the coal.

36. A method according to claim 35, wherein the liquid composition is a solution of calcium bromide in water.

37. A method according to claim 32, when the sorbent components comprise an aluminosilicate mineral and one or more of Portland cement, cement kiln dust, and lime kiln dust.

38. A method according to claim 32, wherein the ash contains 90% or more by weight of the mercury present in the coal before combustion.

39. A method of burning a mercury containing fuel in a furnace of a fuel burning system to reduce emissions of mercury or other heavy metals to the environment outside the system, the method comprising:

adding sorbent components comprising halogen, calcium, silica, and alumina onto the fuel upstream of the furnace, into the furnace, or into a convective pathway downstream of the furnace where the temperature is greater than 1500°

F.; and

combusting the fuel to produce ash, combustion ashes, and heat energy.

40. A method according to claim 39, wherein one or more sorbent components are added into the furnace where the temperature is greater than 2000°

F.

41. A method according to claim 39, wherein one or more of the sorbent components is added into the furnace where the temperature is greater than 2300°

F.

42. A method according to claim 39, wherein one or more of the components is added into the furnace where the temperature is greater than 2700°

F.

43. A method according to claim 39, wherein the fuel is municipal waste.

44. A method according to claim 39, wherein the fuel is coal.

45. A method according to claim 44, wherein 90% of the mercury in the coal is captured in the ash produced upon combusting the coal.

46. A method according to claim 44, further comprising measuring the mercury level in the combustion gases and adjusting the amount of halogen added based on the value of the measured mercury level.

47. A method according to claim 44, further comprising measuring acid leaching of mercury from the ash and adjusting the amount of silica and alumina added based on the value of the measured leaching.