Barrier coatings

• US 8,227,984 B2
• Filed: 05/21/2008
• Issued: 07/24/2012
• Est. Priority Date: 09/11/2002
• Status: Active Grant

• Current Assignee: BOE Technology Group Co., Ltd.
• Original Assignee: General Electric Company
• Inventors: Kim, Tae Won, Heller, Christian Maria Anton, Schaepkens, Marc, Erlat, Ahmet Gun, Yan, Min
• Primary Examiner(s): Santiago, Mariceli
• Assistant Examiner(s): Raleigh, Donald
• Application Number:
  US12/124,548
• Publication Number:
  US 20090021150A1
• Time in Patent Office: 1,525 Days
• Field of Search: 257/40, 257/72, 257 98-100, 257642-643, 257/759, 257/75, 313582-587, 313/414, 313441-460, 313495-497, 313498-512, 313293-304, 313/306, 313309-310, 313/346, 313/351, 313/355, 315/169.1, 315/169.3, 427/58, 427/64, 427/66, 427532-535, 427/539, 428690-691, 428/917, 438 26- 29, 438/34, 438/82, 438/20, 445 24- 25, 345/37, 345/41, 345/60, 345/71
• US Class Current: 313/512
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

A barrier coating of organic-inorganic composition, the barrier coating having optical properties that are substantially uniform along an axis of light transmission, said axis oriented substantially perpendicular to the surface of the coating.

Claims

1. A composite article comprising:

a flexible substrate;

a device disposed on said substrate; and

a barrier coating of organic-inorganic composition, the barrier coating having optical properties that are substantially uniform along an axis of light transmission, said axis oriented substantially perpendicular to the surface of the coating,

wherein the barrier coating comprises at least one zone substantially organic in composition and at least one zone substantially inorganic in composition,

wherein the barrier coating composition remains substantially constant over interfaces between the at least one zone substantial organic in composition and the at least one zone substantially inorganic in composition; and

,

wherein the composite article comprises zones of substantially homogenous composition and further comprises transitional zones of mixed organic and inorganic composition.

2. The composite article of claim 1, wherein the refractive index is the barrier coating is substantially uniform along the axis of light transmission.

3. The composite article of claim 1, wherein light transmittance through the barrier coating, along the axis of light transmission, is greater than 85% for all wavelengths in a selected wavelength range.

4. The composite article of claim 3, wherein light transmittance through the barrier coating is greater than 85% in the selected wavelength range between 400 nanometers to about 700 nanometers.

5. The composite article of claim 1, wherein said optical properties of said barrier coating comprise substantially uniform light transmittance for all wavelengths within a selected wavelength range.

6. The composite article of claim 5, wherein light transmittance through the barrier coating is substantially uniform for the selected wavelength range between about 400 nanometers to about 700 nanometers.

7. The composite article of claim 1, wherein a transmission rate of oxygen through the barrier coating is less than 0.1 cm.sup.3/(m.sup.2 day) as measured at 25 degrees C. and with a gas containing 21 volume-percent oxygen.

8. The composite article of claim 1, wherein a transmission rate of water vapor through the barrier coating is less than 1 g/(m.sup.2 day), as measured at 25 degrees C. and with a gas having 100-percent relative humidity.

9. The composite article of claim 1, wherein the barrier coating material is selected from the group consisting of organic, inorganic materials, and combinations thereof.

10. The composite article of claim 9, wherein the inorganic materials are selected from the group consisting of oxide, nitride, carbide, boride, and combinations thereof elements of Groups IIA, IIIA, IA, VA, VIA, VIIA, IB, and IB, metals of Groups IIIB, IVB, and VB and rare-earth metals.

11. The composite article of claim 9, wherein the organic barrier coating material comprising carbon, hydrogen, and oxygen.

12. The composite article of claim 11, wherein said organic material further comprised sulfur, nitrogen, and silicon.

13. The composite article of claim 1, wherein said barrier coating is disposed over at least one surface of said substrate.

14. The composite article of claim 1, wherein at least one barrier coating is disposed over at least one surface of said device.

15. The composite article of claim 1, wherein at least on barrier coating encapsulates the composite article.

16. The composite article of claim 1, wherein at least one barrier coating encapsulates said device.

17. The composite article of claim 1, wherein said device is an optoelectronic element.

18. The composite article of claim 17, wherein the optoelectronic element is an organic element.

19. The composite article of claim 17, wherein the optoelectronic element is electroluminescent.

20. The composite article of claim 17, wherein the optoelectronic element is photoresponsive.

21. The composite article of claim 1, wherein said substrate is substantially transparent.