pH tuneable amido-gellant for use in consumer product compositions

• US 8,236,748 B2
• Filed: 03/11/2011
• Issued: 08/07/2012
• Est. Priority Date: 03/12/2010
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Fernandez Prieto, Susana, Smets, Johan, Escuder Gil, Beatriu, Miravet Celades, Juan Felipe, Nebot Carda, Vincent Josep
• Primary Examiner(s): DELCOTTO, GREGORY R
• Application Number:
  US13/045,768
• Publication Number:
  US 20110224124A1
• Time in Patent Office: 515 Days
• Field of Search: 510/501, 564/152, 564/153
• US Class Current: 510/501
• CPC Class Codes: C07C 237/22 having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated peptides C07K
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
• CPC Class Codes: C11D 3/32 Amides; Substituted amides

Abstract

The invention is to pH tunable amido-gellant that are suitable for use in consumer product compositions.

Claims

1. A pH tunable amido-gellant having a formula:

2. The pH tunable amido-gellant of claim 1, wherein the pH tunable amido-gellant has a pKa of from 1.5 to 14.

3. The pH tunable amido-gellant of claim 1, wherein the pH tunable amido-gellant has a molecular weight from 150 to 1500 g/mol.

4. The pH tunable amido-gellant of claim 1, wherein the pH tunable amido-gellant has a minimum gelling concentration (MGC) of from 0.1 to 100 mg/mL, at the pH of the composition.

5. The pH tunable amido-gellant of claim 1, wherein the pH tunable amido gellant is selected from the group consisting of:

N,N′

-(2S,2′

S)-1,1′

-(ethane-1,2-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N-(2S,2′

S)-1,1′

-(propane-1,3-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N-(2S,2′

S)-1,1′

-(butane-1,4-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N-(2S,2′

S)-1,1′

-(pentane-1,5-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N-(2S,2′

S)-1,1′

-(hexane-1,6-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N-(2S,2′

S)-1,1′

-(heptane-1,7-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N-(2S,2′

S)-1,1′

-(octane-1,8-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

(6S,13S′

)-6,13-diisopropyl-4,7,12,15-tetraoxo-5,8,11,14-tetraazaoctadecane-1,18-dioic acid;

(6S,14S′

)-6,14-diisopropyl-4,7,13,16-tetraoxo-5,8,12,15-tetraazanonadecane-1,19-dioic acid;

(6S,15S′

)-6,15-diisopropyl-4,7,14,17-tetraoxo-5,8,13,16-tetraazaeicosane-1,20-dioic acid;

(6S,16S′

)-6,16-diisopropyl-4,7,15,18-tetraoxo-5,8,14,17-tetraazaheneicosane-1,2′

-dioic acid;

(6S,17S′

)-6,17-diisopropyl-4,7,16,19-tetraoxo-5,8,15,18-tetraazadocosane-1,22-dioic acid;

18S′

)-6,18-diisopropyl-4,7,17,20-tetraoxo-5,8,16,19-tetraazatricosane-1,23-dioic acid;

(6S,19S′

)-6,19-diisopropyl-4,7,18,21-tetraoxo-5,8,17,20-tetraazatetracosane-1,24-dioic acid;

(6S,20S′

)-6,20-diisopropyl-4,7,19,22-tetraoxo-5,8,18,21-tetraazapentacosane-1,25-dioic acid;

(6S,21S′

)-6,21-diisopropyl-4,7,20,23-tetraoxo-5,8,19,22-tetraazahexacosane-1,26-dioic acid;

(6S,22S′

)-6,22-diisopropyl-4,7,21,24-tetraoxo-5,8,20,23-tetraazaheptacosane-1,27-dioic acid;

(6S,23S′

)-6,23-diisopropyl-4,7,22,25-tetraoxo-5,8,21,24-tetraazaoctacosane-1,28-dioic acid;

N,N′

-(2S,2′

S)-1,1′

-(ethane-1,2-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(propane-1,3-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide N,N′

-(2S,2′

S)-1,1′

-(butane-1,4-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(pentane-1,5-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(hexane-1,6-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(heptane-1,7-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(octane-1,8-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(nonane-1,9-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(decane-1,10-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(undecane-1,1′

-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(dodecane-1,12-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)bis(4-(1H-imidazol-5-yl)benzamide);

N,N′

-(2S,2′

S)-1,1′

-(nonane-1,9-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(decane-1,10-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(undecane-1,11-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(dodecane-1,12-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(tridecane-1,13-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(tetradecane-1,14-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(hexadecane-1,16-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(octadecane-1,18-diylbis(azanediyl))bis(3-methyl-1-oxobutane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(ethane-1,2-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(propane-1,3-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(butane-1,4-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(pentane-1,5-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(hexane-1,6-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(heptane-1,7-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(octane-1,8-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(nonane-1,9-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(decane-1,10-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(undecane-1,11-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(dodecane-1,12-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(tridecane-1,13-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(tetradecane-1,14-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(hexadecane-1,16-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(octadecane-1,18-diylbis(azanediyl))bis(1-oxopropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(ethane-1,2-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(propane-1,3-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(butane-1,4-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(pentane-1,5-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(hexane-1,6-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide N,N′

-(2S,2′

S)-1,1′

-(heptane-1,7-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(octane-1,8-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(nonane-1,9-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(decane-1,10-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(undecane-1,1′

-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(dodecane-1,12-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(tridecane-1,13-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(tetradecane-1,14-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(hexadecane-1,16-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

N,N′

-(2S,2′

S)-1,1′

-(octadecane-1,18-diylbis(azanediyl))bis(1-oxo-3-phenylpropane-2,1-diyl)diisonicotinamide;

[1-12-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-ethylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-{8-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-octylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-13-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-propylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-{9-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-nonylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-{4-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-butylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-[10-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-decylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-15-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-pentylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-{11-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-undecylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-16-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-hexylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-{12-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-dodecylylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

[1-{7-[2-Benzyloxycarbonylamino-3-(1H-indol-3-yl)-propionylamino]-heptylcarbamoyl}-2-(1H-indol-3-yl)-ethyl]-carbamic acid benzyl ester;

N-[(1S)-2-methyl-1-[2-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]ethylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[8-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]octylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[3-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]propylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[9-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]nonylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[4-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]butylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[10-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]decylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[5-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]pentylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[11-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]undecylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[6-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]hexylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[12-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]dodecylcarbamoyl]butyl]pyridine-4-carboxamide;

N-[(1S)-2-methyl-1-[7-[[(2S)-3-methyl-2-(pyridine-4-carbonylamino)pentanoyl]amino]heptylcarbamoyl]butyl]pyridine-4-carboxamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[2-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]ethylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[8-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]octylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[3-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]propylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[9-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]nonylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[4-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]butylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[10-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]decylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[5-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]pentylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[11-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]undecylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[6-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]hexylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[12-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]dodecylcarbamoyl]-2-methyl-butyl]benzamide;

4-(1H-imidazol-5-yl)-N-[(1S)-1-[7-[[(2S)-2-[[4-(1H-imidazol-5-yl)benzoyl]amino]-3-methyl-pentanoyl]amino]heptylcarbamoyl]-2-methyl-butyl]benzamide;

N-[(1S)-2-[[(1S)-1-[[(2R)-2-[[(2R)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]methylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[8-[[(2S)-2-[[(25)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]octylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[3-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]propylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[9-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]nonylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[4-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]butylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[10-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]decylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[5-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]pentylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[11-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]undecylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[6-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]hexylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-1-[12-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]dodecylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide;

N-[(1R)-2-[[(1R)-147-[[(2S)-2-[[(2S)-2-benzamido-3-(1H-imidazol-5-yl)propanoyl]amino]-3-methyl-pentanoyl]amino]heptylcarbamoyl]-2-methyl-butyl]amino]-1-(1H-imidazol-5-ylmethyl)-2-oxo-ethyl]benzamide; and

mixtures thereof.

6. A method of structuring a consumer product composition comprising adding the pH tunable amido-gellant of claim 1 to the consumer product composition.