Thermal selectivity multivariate optical computing

• US 8,240,189 B2
• Filed: 10/04/2005
• Issued: 08/14/2012
• Est. Priority Date: 10/04/2004
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Myrick, Michael L., Perkins, David L., Priore, Ryan J.
• Primary Examiner(s): FITZGERALD, JOHN P
• Application Number:
  US11/576,359
• Publication Number:
  US 20080276687A1
• Time in Patent Office: 2,506 Days
• Field of Search: 73/240.1, 73/240.2
• US Class Current: 73/24.02
• CPC Class Codes: G01N 2021/1704 in gases
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis

Abstract

A method of using photoacoustic spectroscopy to determine chemical information about an analyte includes the steps of emitting a light ray for interaction with a sample of an analyte; transmitting the light ray through a fill fluid disposed in a detection cell, the fill fluid having molecules substantially similar to molecules of the analyte to absorb the light ray; producing a thermal wave and oscillation in the fill fluid proportional to an intensity of the light ray; including a pressure oscillation in the fill fluid by the thermal wave; and detecting the pressure oscillation by a microphone to determine information about the analyte sample.

Claims

1. A method of using photoacoustic spectroscopy to determine chemical information about a sample of an analyte, the method comprising the steps of:

emitting a light ray for interaction with a sample of an analyte;

passing the light ray through a multivariate optical element;

transmitting the interacted light ray from the sample into a detection cell having a fill fluid disposed in the detection cell, the fill fluid selected to have molecules of the analyte disposed to absorb the transmitted light ray;

producing a thermal wave and oscillation in the fill fluid proportional to an intensity of the light ray;

inducing a pressure oscillation in the fill fluid by the thermal wave; and

detecting the pressure oscillation by a microphone to determine information about the analyte.

2. The method as in claim 1, wherein the fill fluid comprises one of a gaseous analyte, a liquid analyte, a solid analyte, a dissolved analyte, a powdered analyte, or an emulsified analyte.

3. The method as in claim 1, wherein the fill fluid further comprises a substantially non-absorbing carrier fluid.

4. The method as in claim 1, wherein the light ray interacts with the sample of analyte by being emitted through, emitted by, scattered from, or reflecting from the sample.

5. The method as in claim 1, wherein the light ray is emitted from a broadband light source.

6. The method as in claim 1, wherein the microphone records only the pressure oscillation induced by an absorbed wavelength of the light ray.

7. The method as in claim 1, wherein the detection cell is utilized to design the multivariate optical element prior to the step of passing the light ray through the multivariate optical element.

8. The method as in claim 1, further comprising the step of modulating an intensity of the light ray at a fixed frequency and utilizing the cell to measure infrared spectra.

9. The method as in claim 8, wherein a wavelength of the light ray includes a non-zero spectral weighting.

10. A method of using photoacoustic spectroscopy to determine chemical information about a sample of an analyte, the method comprising the steps of:

emitting a light ray for interaction with a sample of an analyte;

transmitting the interacted light ray from the sample into a single, dual function detection cell, the single detection cell having a fill fluid disposed in therein and a microphone disposed therein, the fill fluid selected to have analyte molecules disposed to absorb the transmitted light ray;

producing a thermal wave and oscillation in the fill fluid of the single detection cell, the thermal wave and oscillation proportional to an intensity of the light ray;

inducing a pressure oscillation in the fill fluid of the single detection cell by the thermal wave;

detecting the pressure oscillation by the microphone to determine information about the analyte; and

utilizing the single detection cell to measure transmission spectra of the light ray and to generate a regression vector for use with a multivariate optical element.

11. The method as in claim 10, wherein the fill fluid further comprises a substantially inert carrier fluid.

12. A method of using photoacoustic spectroscopy to determine chemical information about a sample of an analyte, the method comprising the steps of:

providing a detection cell, the detection cell having a fill fluid disposed therein and a microphone disposed therein;

providing a light source external of the detection cell;

providing a sample of an analyte external of the detection cell and between the light source and the detection cell;

emitting a light ray from the light source;

directing the emitted light ray through a multivariate optical element;

directing the light ray to pass through the sample of an analyte;

directing light rays that have passed through the sample into the detection cell, the fill fluid selected to have analyte molecules disposed to absorb the transmitted light ray;

producing a thermal wave and oscillation in the fill fluid of the detection cell, the thermal wave and oscillation proportional to an intensity of the light ray;

inducing a pressure oscillation in the fill fluid of the single detection cell by the thermal wave; and

detecting the pressure oscillation by the microphone to determine information about the analyte.

13. The method as in claim 12, wherein the detection cell is utilized to design the multivariate optical element prior to the step of passing the light ray through the multivariate optical element.