Support material for digital manufacturing systems

• US 8,246,888 B2
• Filed: 07/24/2009
• Issued: 08/21/2012
• Est. Priority Date: 10/17/2008
• Status: Active Grant

• Current Assignee: Stratasys Incorporated
• Original Assignee: Stratasys Incorporated
• Inventors: Hopkins, Paul E., Priedeman, William R. Jr., Bye, Jeffrey F.
• Primary Examiner(s): Gupta, Yogendra
• Assistant Examiner(s): Hindenlang, Alison
• Application Number:
  US12/508,725
• Publication Number:
  US 20100096072A1
• Time in Patent Office: 1,124 Days
• Field of Search: 156/155, 264/308, 264/317
• US Class Current: 264/308
• CPC Class Codes: B29C 64/40 Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: C08L 25/08 Copolymers of styrene C08L29/08, C08L35/06, C08L55/02 take precedence
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 33/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: C08L 33/068 containing glycidyl groups

Abstract

A support material feedstock comprising a first copolymer and a polymeric impact modifier, where the first copolymer includes a first monomer unit comprising a carboxyl group and a second monomer unit comprising a phenyl group.

Claims

1. A method for building a three-dimensional model with a digital manufacturing system, the method comprising:

at least partially melting a support material in the digital manufacturing system, wherein the support material comprises a first copolymer and a second copolymer, wherein the first copolymer comprises a plurality of carboxyl monomer units derived from acrylic acid monomers, a plurality of phenyl monomer units, and a plurality of first carboxylate ester monomer units derived from first alkyl acrylate monomers, and wherein the second copolymer comprises a plurality of epoxy-terminated carboxylate ester monomer units and a plurality of second carboxylate ester monomer units derived from second alkyl acrylate monomers;

depositing the at least partially melted support material onto a platform of the digital manufacturing system using a layer-based additive technique to form a support structure;

depositing a modeling material onto the platform of the digital manufacturing system using the layer-based additive technique to form the three-dimensional model, wherein the three-dimensional model comprises at least one overhanging region supported by the support structure; and

substantially removing the support structure from the three-dimensional model with an aqueous solution.

2. The method of claim 1, wherein substantially removing the support structure from the three-dimensional model with the aqueous solution comprises immersing the support structure and the three-dimensional model into a bath of the aqueous solution.

3. The method of claim 1, wherein the aqueous solution comprises an alkaline aqueous solution.

4. The method of claim 1, wherein the platform is retained within a build chamber of the digital manufacturing system, and wherein the method further comprises maintaining the build chamber at one or more temperatures ranging from about 85°

C. to about 110°

C.

5. The method of claim 1, wherein the support material consists essentially of the first copolymer and the second copolymer.

6. The method of claim 1, wherein the support material further comprises a third copolymer derived from monomers comprising methyl methacrylic acid.

7. The method of claim 1, and further comprising:

feeding a filament of the support material to an extrusion head of the digital manufacturing system, wherein at least partially melting the support material in the digital manufacturing system comprises at least partially melting the support material of the filament in the extrusion head.

8. The method of claim 1, wherein the first copolymer constitutes about 80% by weight to about 90% by weight of the support material, and the second copolymer constitutes about 10% by weight to about 20% by weight of the support material, based on an entire weight of the support material.

9. A method for building a three-dimensional model with a digital manufacturing system, the method comprising:

feeding a support material to a liquefier of the digital manufacturing system, the support material comprising a first copolymer and a second copolymer, wherein the first copolymer comprises a plurality of pendant carboxyl groups having a formula COOH, a plurality of pendant phenyl groups, and a plurality of first pendant carboxylate ester groups having a formula COOR(₁), wherein R(₁) is a first alkyl group, and wherein the second copolymer comprises a plurality of pendant epoxy-terminated carboxylate ester groups and a plurality of second pendant carboxylate ester groups having a formula COOR(₂), wherein R(₂) is a second alkyl group;

at least partially melting the support material in the liquefier; and

extruding the at least partly molten support material from the liquefier; and

depositing the extruded support material onto a platform using a layer-based additive technique to build a support structure for the three-dimensional model.

10. The method of claim 9, and further comprising removing at least a portion of the support structure from the three-dimensional model with an aqueous solution.

11. The method of claim 10, wherein the aqueous solution comprises an alkaline aqueous solution.

12. The method of claim 9, wherein the first copolymer constitutes about 80% by weight to about 90% by weight of the support material, and the second copolymer constitutes about 10% by weight to about 20% by weight of the support material, based on an entire weight of the support material.

13. The method of claim 9, wherein the plurality of pendant carboxyl groups are derived from monomers comprising methacrylic acid.

14. The method of claim 9, and further comprising building the three-dimensional model from a thermoplastic material using the layer-based additive technique, wherein the three-dimensional model comprises at least one overhanging region supported by the support structure.

15. A method for building a three-dimensional model with a digital manufacturing system, the method comprising:

providing a support material to the digital manufacturing system, the support material comprising;

a first copolymer comprising;

a plurality of carboxyl monomer units each having a carboxyl group with a formula COOH;

a plurality of phenyl monomer units each having a phenyl group; and

a plurality of first ester monomer units each having a first carboxylate ester group with a formula COOR(₁), wherein R₁) is a first alkyl group; and

a second copolymer comprising;

a plurality of epoxy monomer units each having an epoxy-terminated carboxylate ester group; and

a plurality of second ester monomer units each having a second carboxylate ester group with a formula COOR(₂), wherein R(₂) is a second alkyl group;

wherein the support material is soluble in an alkaline aqueous solution;

at least partially melting the support material in the digital manufacturing system;

depositing and cooling the at least partially melted support material to build a support structure from the support material with the digital manufacturing system using a layer-based additive technique, the support structure being built to support the three-dimensional model.

16. The method of claim 15, wherein at least a portion of the plurality of carboxyl monomer units of the first copolymer are derived from one or more acid compounds selected from the group consisting of acrylic acid, methacrylic acid, and combinations thereof, and wherein at least a portion of the first ester monomer units of the first copolymer are derived from one or more alkyl acrylate monomers.

17. The method of claim 15, wherein at least a portion of the phenyl groups of the plurality of phenyl groups are pendant phenyl groups.

18. The method of claim 15, wherein the support material further comprises a third copolymer derived from monomers comprising methyl methacrylic acid.

19. The method of claim 15, wherein the first copolymer constitutes about 80% by weight to about 90% by weight of the support material, and the second copolymer constitutes about 10% by weight to about 20% by weight of the support material, based on an entire weight of the support material.

20. The method of claim 15, and further comprising removing at least a portion of the support structure from the three-dimensional model with an alkaline aqueous solution.