Method for manufacturing high-temperature superconducting conductors

• US 8,268,386 B2
• Filed: 01/03/2006
• Issued: 09/18/2012
• Est. Priority Date: 04/08/2004
• Status: Active Grant

• Current Assignee: Superpower, Inc. (Furukawa Electric Company Limited)
• Original Assignee: Superpower, Inc. (Furukawa Electric Company Limited)
• Inventors: Selvamanickam, Venkat, Lee, Hee-Gyoun
• Primary Examiner(s): Talbot, Brian K
• Application Number:
  US11/324,511
• Publication Number:
  US 20060115580A1
• Time in Patent Office: 2,450 Days
• Field of Search: 427/62, 295/99, 505/434, 505/470, 505/473, 505/500, 505/741
• US Class Current: 427/62
• CPC Class Codes: C23C 16/408 of copper or solid solutions thereof
• CPC Class Codes: C23C 16/455 characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
• CPC Class Codes: C23C 16/45517 Confinement of gases to vicinity of substrate
• CPC Class Codes: C23C 16/45565 Shower nozzles
• CPC Class Codes: C23C 16/45591 Fixed means, e.g. wings, baffles
• CPC Class Codes: C23C 16/545 for coating elongated substrates
• CPC Class Codes: H10N 60/0464 by metalloorganic chemical vapour deposition [MOCVD]
• CPC Class Codes: Y10T 29/49014 Superconductor

Abstract

A method for manufacturing a high-temperature superconducting conductor includes providing an elongate substrate to a reactor, the reactor having a longitudinal flow distributor. The longitudinal flow distributor has an entrance, a plurality of exits, and an interior distribution member provided between the entrance and the plurality of exits. The method further includes heating at least a portion of the substrate to a temperature sufficient to facilitate the formation of one of a superconducting material and a predecessor to a superconducting material. Further, the method includes flowing at least one precursor into the longitudinal flow distributor, through the entrance thereof, past an internal distribution member, and out through a plurality of exits, thereby longitudinally distributing the at least one precursor to form the superconducting material or predecessor thereof on the substrate.

Claims

1. A method for manufacturing a high temperature superconducting conductor, said method comprising the steps of:

a) providing an elongate substrate to a reactor, the elongate substrate having a major axis, the reactor having a longitudinal flow distributor, the longitudinal flow distributor having a top portion including an entrance, a bottom portion including a plurality of exits, and an internal distribution member provided between the top portion and the bottom portion, wherein the internal distribution member (i) includes a thickness, a width greater than the thickness, and a length greater than the width, and a plurality of through passages arranged non-uniformly along the length of the internal distribution member, and (ii) has no through passages aligned with the entrance;

b) shielding a first and second low temperature regions of the substrate with a first and second shield;

c) heating at least a portion of the substrate, located between the first and second low temperature regions, to a temperature sufficient to facilitate the formation of one of (i) a predecessor to a superconducting material and (ii) a superconducting material; and

d) flowing at least one precursor into the longitudinal flow distributor through the entrance, past the internal distribution member and out through the plurality of exits thereby longitudinally distributing a flow of the at least one precursor so as to communicate the at least one precursor with the heated at least a portion of the substrate so as to permit the formation of said one of (i) a predecessor to a superconducting material and (ii) a superconducting material, wherein the major axis of the elongate substrate is perpendicular to the flow as the flow exits the longitudinal flow distributor;

wherein the first and second shields substantially prevent flowing at least one precursor onto the first and second low temperature regions.

3. The method of claim 1, wherein the plurality of through passages have decreasing spacing between adjacent through passages along a direction extending from the entrance of the longitudinal flow distributor along the length of the internal distribution member.

4. The method of claim 1, wherein the plurality of through passages have increasing size along a direction extending from the entrance of the longitudinal flow distributor along the length of the internal distribution member.

5. The method of claim 1, wherein the internal distribution member is positioned in the longitudinal flow distributor to define a receiving volume between the internal distribution member and the entrance, and a distribution volume between the internal distribution member and the plurality of exits.

6. The method of claim 5, wherein the distribution volume is smaller than the receiving volume.

7. The method of claim 5, wherein the receiving volume is greater than a total volume of the through passages of the internal distribution member.

8. The method of claim 5, wherein a total volume of the through passages of the internal distribution member is greater than the distribution volume.

9. The method of claim 3, wherein a spacing along the length between the adjacent through passages nearest the entrance is greater than a spacing between any remaining pair of adjacent through passages.

2. A method for manufacturing a high temperature superconducting conductor, said method comprising the steps of:

a) providing an elongate substrate to a reactor, the elongate substrate having a major axis, the reactor having a longitudinal flow distributor, the longitudinal flow distributor having a top portion including an entrance, a bottom portion including a plurality of exits, and an internal distribution member provided between the top portion and the bottom portion, wherein the internal distribution member (i) includes a thickness along a direction extending from the top portion to the bottom portion, a width greater than the thickness, and a length greater than the width, and a plurality of through passages arranged non-uniformly along the length of the internal distribution member, and (ii) has no through passages aligned with the entrance;

b) heating at least a portion of the substrate, located between the first and second low temperature regions, to a temperature sufficient to facilitate the formation of one of (i) a predecessor to a superconducting material and (ii) a superconducting material;

c) flowing at least one precursor into the longitudinal flow distributor through the entrance, past the internal distribution member and out through the plurality of exits thereby longitudinally distributing a flow of the at least one precursor so as to communicate the at least one precursor with the heated at least a portion of the substrate so as to permit the formation of said one of (i) a predecessor to a superconducting material and (ii) a superconducting material, wherein the major axis of the elongate substrate is perpendicular to the flow as the flow exits the longitudinal flow distributor; and

d) transversely restricting the flow of the at least one precursor;

wherein transversely restricting the flow of the at least one precursor includes provision of first and second lateral flow restrictors disposed along opposite sides of the substrate.