Nanotube assisted self-cleaning material

• US 8,273,425 B2
• Filed: 05/14/2009
• Issued: 09/25/2012
• Est. Priority Date: 05/14/2009
• Status: Expired due to Fees

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Eldering, Charles A., Ehrlacher, Edward A.
• Primary Examiner(s): Dye, Rena
• Assistant Examiner(s): YAGER, JAMES C
• Application Number:
  US12/465,717
• Publication Number:
  US 20100291375A1
• Time in Patent Office: 1,230 Days
• Field of Search: 428/34.4, 428/702, 428/408, 502/350, 423/447.1, 423/447.2, 423/448, 423/460, 977/742, 977/782, 977/811, 977/813, 977/823, 977/832
• US Class Current: 428/34.4
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: Y10T 428/131 Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A self-cleaning material is generally described that may include a substrate having a first surface. A self-cleaning layer of aligned nanotube structures may be formed on the first surface of the substrate, where absorption of light by the nanotube structures may cause a change in state of the self-cleaning material based on an angle of incidence of the light and an orientation vector corresponding to the layer of aligned nanotube structures.

Claims

1. A self-cleaning material that is responsive to exposure to light comprising:

a substrate having a first surface; and

a self-cleaning layer of longitudinally aligned nanotube structures formed on the first surface of the substrate, wherein longitudinal axes of the nanotube structures are parallel to each other and form a non-zero acute orientation angle with respect to an axis normal to the first surface such that the self-cleaning material changes states responsive to the exposure to light based at least in part on an angle of incidence of the light and the orientation angle.

2. The self-cleaning material of claim 1, wherein the self-cleaning layer is further arranged such that absorption of light by the self-cleaning layer of aligned nanotube structures increases as the angle of incidence of the light approaches the orientation angle.

3. The self-cleaning material of claim 1, wherein the self-cleaning layer of aligned nanotube structures is either photocatalytic, hydrophobic, and/or hydrophilic in response to exposure to the light.

4. The self-cleaning material of claim 3, wherein the light is ultraviolet light.

5. The self-cleaning material of claim 1, wherein the nanotube structures at least partially comprise titanium dioxide nanotube structures.

6. The self-cleaning material of claim 1, wherein the nanotube structures are a different material than the substrate.

7. A self-cleaning material that is responsive to exposure to light comprising:

a substrate having a first surface and a second surface;

a first self-cleaning layer of longitudinally aligned nanotube structures formed on the first surface of the substrate, wherein first longitudinal axes of the nanotube structures of the first self-cleaning layer are parallel to each other and form a first non-zero acute orientation angle with respect to an axis normal to the first surface and arranged such that the first self-cleaning layer changes states responsive to the exposure to light based at least in part on the first orientation angle; and

a second self-cleaning layer of longitudinally aligned nanotube structures formed on the second surface of the substrate, wherein second longitudinal axes of the nanotube structures of the second self-cleaning layer are parallel to each other and form a second non-zero acute orientation angle with respect to an axis normal to the second surface and arranged such that the second self-cleaning layer changes states responsive to the exposure to light based at least in part on the second orientation angle.

8. The self-cleaning material of claim 7, wherein the nanotube structures of the first self-cleaning layer and the nanotube structures of the second self-cleaning layer are different materials.

9. The self-cleaning material of claim 7, wherein the first and second self-cleaning layers are further arranged such that absorption of light by the first and second self-cleaning layers causes the first and second self-cleaning layers, respectively, to become either photocatalytic, hydrophobic, and/or hydrophilic.

10. The self-cleaning material of claim 9, wherein the second self-cleaning layer exhibits a different self-cleaning property than the first self-cleaning layer.

11. The self-cleaning material of claim 7, wherein the first and second orientation angles correspond to most probable angles of incidence of the light on the first and second self-cleaning layers, respectively.

12. The self-cleaning material of claim 7, wherein the first orientation angle is selected based on the first self-cleaning layer being utilized in an uncontrolled environment and the second orientation angle is selected based on the second self-cleaning layer being utilized in a controlled environment.

13. A self-cleaning material that is responsive to exposure to light comprising:

a first self-cleaning layer of longitudinally aligned titanium dioxide nanotube structures formed on a first surface of a glass substrate, wherein first longitudinal axes of the titanium dioxide nanotube structures of the first self cleaning layer are parallel to each other and form a first non-zero acute orientation angle with respect to an axis normal to the first surface such that absorption of light by the titanium dioxide nanotube structures of the first self cleaning layer induces a photo-induced hydrophilic state of the first self-cleaning layer of aligned titanium dioxide nanotube structures based at least in part on a first angle of incidence of the light and the first orientation angle.

14. The self-cleaning material of claim 13, wherein the first self-cleaning layer is further arranged such that absorption of light by the first self-cleaning layer of aligned titanium dioxide nanotube structures is increased as the first angle of incidence of the light approaches the orientation angle.

15. The self-cleaning material of claim 13, wherein the self-cleaning layer is further arranged such that absorption of light by the titanium dioxide nanotube structures of the first self-cleaning layer further induces a photocatalytic state of the self-cleaning layer based on the orientation angle and the angle of incidence of the light with the first surface of the glass substrate.

16. The self-cleaning material of claim 15, wherein the light is ultraviolet light.

17. The self-cleaning material of claim 13, further comprising:

a second self-cleaning layer of longitudinally aligned titanium dioxide nanotube structures formed on a second surface of the glass substrate, wherein second longitudinal axes of the titanium dioxide nanotube structures of the second self cleaning layer are parallel to each other and form a second non-zero acute orientation angle with respect to an axis normal to the second surface such that absorption of light by the titanium dioxide nanotube structures of the second self cleaning layer induces a photo-induced hydrophilic state of the second self-cleaning layer based at least in part on a second angle of incidence of the light and the second orientation angle.