Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring

• US 8,273,834 B2
• Filed: 08/09/2007
• Issued: 09/25/2012
• Est. Priority Date: 09/07/2006
• Status: Active Grant

• Current Assignee: Univation Technologies LLC (Dow, Inc.)
• Original Assignee: Univation Technologies LLC (Dow, Inc.)
• Inventors: Markel, Eric J., Hagerty, Robert O., Pannell, Richard B.
• Primary Examiner(s): CHEUNG, WILLIAM K
• Application Number:
  US12/310,723
• Publication Number:
  US 20100144983A1
• Time in Patent Office: 1,874 Days
• Field of Search: 526/59, 526/61, 526/60, 526/348.5
• US Class Current: 526/59
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C08F 210/08 Butenes
• CPC Class Codes: C08F 210/14 Monomers containing five or more carbon atoms
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 2400/02 Control or adjustment of polymerization parameters
• CPC Class Codes: C08F 2500/20 Activation energy or enthalpy

Abstract

In some embodiments, a method including the steps of monitoring a polymerization reaction which produces a polymer resin in a fluid bed reactor, where a dry melt reference temperature is characteristic of melting behavior of a dry version of the resin, and in response to data indicative of at least one monitored parameter of the reaction, determining in on-line fashion a reduced melt reference temperature that is at least substantially equal to the difference between the dry melt reference temperature and a temperature by which the dry melt reference temperature is depressed by the presence of condensable diluent gas with the resin in the reactor. Optionally, the method also includes the step of controlling the reaction in response to the reduced melt reference temperature or a stickiness parameter determined from the reduced melt reference temperature.

Claims

1. A method, including the steps of:

(a) monitoring a polymerization reaction which produces a polymer resin in a fluid bed reactor, wherein a dry melt reference temperature is characteristic of melting behavior of a dry version of the polymer resin;

(b) in response to data indicative of at least one monitored parameter of the reaction, generating, in on-line fashion, a reduced melt reference temperature characteristic of the melting behavior of the polymer resin as it exists in the reactor, wherein the reduced melt reference temperature is at least substantially equal to the difference between the dry melt reference temperature and a melt reference temperature depression value, “

D,”

where D is a temperature by which the dry melt reference temperature is depressed by the presence of diluent with the resin in the reactor; and

(c) controlling the reaction in response to the reduced melt reference temperature.

2. The method of claim 1, also including the step of determining a stickiness control parameter from the reduced melt reference temperature.

3. The method of claim 1, wherein step (c) includes the step of controlling the reaction in response to the stickiness control parameter.

4. The method of claim 1, wherein step (c) includes the step of maintaining a current temperature of the reactor in a predetermined relation with the reduced melt reference temperature.

5. The method of claim 1, wherein step (a) includes the step of monitoring at least one instantaneous parameter of the reaction, and step (b) includes the step of generating melt reference data in response to data indicative of at least one monitored instantaneous parameter of the reaction.

6. The method of claim 1, wherein step (a) includes the step of monitoring at least one bed-averaged parameter of the reaction, and step (b) includes the step of generating melt reference data in response to data indicative of at least one monitored bed-averaged parameter of the reaction.

7. The method of claim 1, wherein step (b) includes the steps of generating first melt reference data indicative of a first reduced melt reference temperature in response to data indicative of at least one monitored instantaneous parameter of the reaction, generating additional melt reference data indicative of a second reduced melt reference temperature in response to data indicative of at least one bed-averaged parameter of the reaction,

and step (c) includes the step of controlling the reaction in response to both the first reduced melt reference temperature and the second reduced melt reference temperature.

8. The method of claim 7, wherein step (c) includes the steps of controlling the reaction in response to the second reduced melt reference temperature during a transition in the reaction, and controlling the reaction in response to the first reduced melt reference temperature when said reaction is not undergoing a transition.

9. The method of claim 7, wherein step (c) includes the step of controlling the reaction in an effort to maintain the first reduced melt reference temperature below a first predetermined limit and to maintain the second reduced melt reference temperature below a second predetermined limit.

10. The method of claim 7, wherein step (c) includes the step of controlling the reaction in an effort to maintain the first reduced melt reference temperature within a first predetermined range and to maintain the second reduced melt reference temperature within a second predetermined range.

11. The method of claim 1, wherein step (c) includes the step of maintaining bed temperature in the reactor in a predetermined relation with the reduced melt reference temperature.

12. The method of claim 1, wherein step (c) includes the step of maintaining bed temperature in the reactor in a predetermined relation with a temperature range related to the reduced melt reference temperature.

13. The method of claim 1, wherein step (a) includes the step of monitoring reactor temperature, at least one of density and melt index of the polymer resin, and concentration of at least one diluent present with the resin in the reactor, and step (b) includes the steps of:

determining said dry melt initiation temperature in response to data indicative of at least one of density and melt index of the polymer resin; and

determining said temperature depression D by processing data, including data indicative of reactor temperature, concentration of each said diluent present with the resin in the reactor, and said dry melt initiation temperature, in accordance with a predetermined model.

14. The method of claim 13, wherein the concentration of each said diluent monitored in step (a) includes at least one of a concentration of at least one induced condensing agent, a concentration of at least one comonomer, and a concentration of at least one isomer of the comonomer.

15. The method of claim 13, wherein the concentration of each said diluent monitored in step (a) includes a concentration of at least one induced condensing agent, at least one comonomer, and at least one isomer of the comonomer.

16. The method of claim 13, wherein the reaction polymerizes ethylene and said at least one comonomer in the presence of a catalyst selected from a group consisting of Ziegler-Natta, chromium, chromium oxide, AlCl₃, cobalt, iron, palladium, and metallocene catalyst.

17. The method of claim 16, wherein the polymer resin is polyethylene and each said comonomer is a C₃-C₁₀ alpha olefin.

18. The method of claim 17, wherein the polymer resin is a polyolefin.

19. The method of claim 18, wherein the polymer resin is polyethylene.