System for preventing unnecessary shutdown of a high-purity gas production plant

• US 8,280,554 B2
• Filed: 11/03/2008
• Issued: 10/02/2012
• Est. Priority Date: 11/09/2007
• Status: Active Grant

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Praxair Technology Incorporated (Linde Plc)
• Inventors: Bergman, Thomas John Jr., Boyer, Rick, Di Santo, Sandro, Hawke, Michael Henry, Pace, Keith Randall, Schulte, Thomas Robert, Warrick, Brian Donald
• Primary Examiner(s): Warden, Jill
• Assistant Examiner(s): Sasaki, Shogo
• Application Number:
  US12/263,788
• Publication Number:
  US 20090125127A1
• Time in Patent Office: 1,429 Days
• Field of Search: 422/62, 700/266, 700/268, 700269-273, 340/584, 702/31, 702/32
• US Class Current: 700/271
• CPC Class Codes: B01D 2256/10 Nitrogen
• CPC Class Codes: B01D 2257/104 Oxygen
• CPC Class Codes: B01D 2257/108 Hydrogen
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 53/0454 Controlling adsorption controlling temperature swing adsorption B01D53/0462, controlling pressure swing adsorption B01D53/047

Abstract

A novel fail-safe temperature monitoring system that can distinguish excessive chemical adsorbent temperature from temperature sensing component failure is provided. This system prevents the gas purifier from shutting down as a result of temperature sensing component failure, and thereby prevents a false shutdown of a high-purity gas production plant.

Claims

1. A system for preventing an equipment failure from a potentially catastrophic exothermic reaction in a gas purifier bed, comprising:

providing one or more dual temperature sensors at various locations in the purifier bed having one or more inlet and outlet valves and, wherein a first set of temperature measuring devices are disposed in close proximity to a corresponding second set of temperature measuring devices forming part of each individual dual temperature sensor;

selecting a first predetermined temperature differential between a first and second temperature measuring device for each individual dual temperature sensor;

selecting a second predetermined temperature;

preventing failure by shutting down the gas purification bed upon determining that the differential between the first and the second temperature measuring device in each of the dual temperature sensors is below the first predetermined temperature differential but wherein the first and the second temperature measuring device of any of said dual temperature sensors exceeds the second predetermined temperature, thereby closing the inlet and the outlet valves to isolate the bed.

2. The system of claim 1, wherein three dual temperature sensors employed are disposed at an upper part, middle part, and lower part of the gas purifier bed.

3. The system of claim 1, wherein the first set of temperature measuring devices are connected to a first receiving computer card, and the second set of temperature measuring devices are connected to a second computer card.

4. The system of claim 1, wherein the gas purifier bed is taken off line upon exceeding the first predetermined temperature differential and the second predetermined temperature set point.

5. The system of claim 1, wherein the first predetermined temperature differential is determined by a temperature difference between two temperature measuring devices of each individual dual temperature sensor.

6. The system of claim 1, wherein the first predetermined temperature differential ranges from about 5°

F. to about 100°

F.

7. The system of claim 1, wherein the second predetermined set point temperature ranges from 120°

F. to about 400°

F.

8. An apparatus designed for preventing failure in a gas purification bed due to an exothermic reaction, comprising:

a gas purification bed having one or more inlet and outlet valves and one or more dual temperature sensors at various locations in the gas purification bed,

each of the one or more dual temperature sensors having two temperature measuring devices in close proximity to one another;

the two temperature measuring devices in each of the one or more dual temperature sensors being connected to separate temperature receiving computer cards; and

a program logic controller configured to monitor an exothermic reaction in the gas purification bed based on (i) a first predetermined temperature differential between the temperature measuring devices of each dual temperature sensor; and

(ii) temperatures measured by the two measuring devices of one of said dual temperature sensors exceeding a second predetermined temperature;

wherein the program logic controller is configured for preventing failure by shutting down the gas purification bed upon the controller determining that the differential between the two temperature measuring devices in each of the one or more dual temperature sensors is below the first predetermined temperature differential but wherein the two measuring devices of any of the dual temperature sensors exceeds the second predetermined temperature, thereby causing the controller to transmit a signal to close the inlet and the outlet valves to isolate the bed.

9. The apparatus of claim 8, further comprising three dual temperature sensors disposed at an upper part, middle part, and lower part of the gas purification bed, respectively.

10. The apparatus of claim 8, wherein the temperature sensors are disposed in thermal wells within the purifier bed.

11. The apparatus of claim 8, wherein each temperature measuring device of a dual temperature sensor is placed in a single or separate thermowells.

12. The apparatus of claim 8, wherein the temperature measuring devices are located on the wall of the purifier bed at an upper part, middle part, and lower part of the gas purifier bed.

13. The apparatus of claim 8, further comprising a source of conventional purity nitrogen gas upstream of the gas purification bed having oxygen, carbon monoxide, and hydrogen impurities in an amount ranging from about 0.1 to about 10 ppm.

14. The apparatus of claim 8, further comprising an isolation valve between the source of conventional nitrogen gas and the gas purification bed which is controlled by the program logic controller to isolate the gas purification bed upon exceeding the first predetermined temperature differential and the second predetermined set point temperature.

15. The apparatus of claim 8, wherein upon exceeding the first predetermined temperature of an individual dual temperature sensor, an alarm is triggered and the program logic controller alerts the operator to an equipment failure of said dual temperature sensor.

16. The system of claim 8, wherein the gas purifier bed contains a chemical adsorbent selected from the group consisting of nickel, palladium, zirconium, platinum, rhodium, ruthenium, and titanium.

17. The system of claim 8, further comprising a source of conventional nitrogen gas upstream of the gas purification bed having oxygen, carbon monoxide and hydrogen impurities in an amount ranging from 0.1-10 ppm.

18. The system of claim 8, wherein the gas purifier bed further purifies the conventional purity nitrogen gas stream to an ultra-high-purity level having oxygen, carbon monoxide and hydrogen impurities in an amount ranging 0-20 ppb.