Cellulose pretreatment process

• US 8,287,651 B2
• Filed: 09/16/2009
• Issued: 10/16/2012
• Est. Priority Date: 09/17/2008
• Status: Expired due to Fees

• Current Assignee: GreenField Specialty Alcohols Inc.
• Original Assignee: GreenField Ethanol Inc.
• Inventors: Benson, Robert, Benech, Regis-Olivier, Bradt, Chris, Lehoux, Richard Romeo
• Primary Examiner(s): Brunsman, David M
• Application Number:
  US12/560,843
• Publication Number:
  US 20100065128A1
• Time in Patent Office: 1,126 Days
• Field of Search: 127/37, 162/14, 162/15, 162/21
• US Class Current: 127/37
• CPC Class Codes: B09B 3/45 Steam treatment, e.g. supercritical water gasification or oxidation
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C10G 1/02 by distillation
• CPC Class Codes: C10G 2300/1014 of vegetal origin
• CPC Class Codes: C10G 2300/4006 Temperature
• CPC Class Codes: C10G 2300/4012 Pressure
• CPC Class Codes: C10G 2300/807 Steam
• CPC Class Codes: C10L 1/02 essentially based on components consisting of carbon, hydrogen, and oxygen only
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 30/20 using bio-feedstock
• CPC Class Codes: Y10T 137/0324 With control of flow by a condition or characteristic of a fluid

Abstract

A process for the production of ethanol from biomass is disclosed. The process relates to the pretreatment of corncob biomass and includes the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time. Volatile compounds are continuously vented during pretreatment. The reaction pressure is released for explosive decomposition of the corncob biomass into fibrous solids and condensate. The exposure is preferably carried out at a temperature of 190-210° C. and a pressure of 190 psig to 275 psig and an exposure time of 3 to 10 minutes.

Claims

1. A process for the pretreatment of corncob biomass for biofuel production by fermentation, comprising the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time, venting volatile compounds continuously over the pretreatment time and releasing the reaction pressure for explosive decomposition of the corncob biomass into a fibrous solids portion and a condensate portion, wherein the exposing step is carried out at a temperature of 190°

C.-210°

C. and a pressure of 190 psig to 275 psig and an exposure time of 3 to 10 minutes for minimizing the acetic content in the fibrous solids portion.

2. A process for the pretreatment of corncob biomass for biofuel production by fermentation, comprising the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time, venting volatile compounds continuously over the pretreatment time and releasing the reaction pressure for explosive decomposition of the corncob biomass into a fibrous solids portion and condensate, wherein the exposing step is carried out at a temperature of 203-207°

C. and a pressure of 220-250 psig and an exposure time of 7-9 minutes for minimizing acetic acid content in the fibrous solids portion.

3. The process of claim 2, further comprising the steps of separately capturing the condensate and the solids generated during the pressure release and removing the captured condensate.

4. The process of claim 2, comprising the further step of collecting condensate and liquid reaction products in the reaction vessel during the exposure time and removing the collected reaction products from the reaction vessel prior to the pressure release.

5. A process for the pretreatment of corncob biomass for biofuel production by fermentation, comprising the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time, venting volatile compounds continuously over the pretreatment time and releasing the reaction pressure for explosive decomposition of the corncob biomass into a fibrous solids portion and condensate, wherein the exposing step is carried out at a temperature of 205°

C., a pressure of 235 psig and for a time interval of 8 minutes for minimizing acetic acid content in the fibrous solids portion.

6. The process of claim 5, wherein the pressure is released within less than 1000 milliseconds.

7. The process of claim 6, wherein the pressure is released within 300 milliseconds.

8. A process for the pretreatment of corncob biomass, comprising the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time, venting volatiles and releasing the reaction pressure for explosive decomposition of the corncob biomass into fibrous solids and condensate, the process conditions being selected for the achievement of a severity index of 3.88 to 4.11.

9. The process of claim 8, comprising the further step of collecting condensate and liquid reaction products in the reaction vessel during the exposure time and removing the collected reaction products from the reaction vessel prior to the pressure release.

10. The process of claim 8, wherein the process conditions are selected for the achievement of a severity index of 4.0.