Spandrel coating and method

• US 8,287,701 B2
• Filed: 07/12/2005
• Issued: 10/16/2012
• Est. Priority Date: 07/12/2005
• Status: Expired due to Fees

• Current Assignee: Guardian Europe S.A.R.L.. (Interguard Holding Corp.)
• Original Assignee: Verre et La Ceramique SA
• Inventors: Kriltz, Uwe, Olbrich, Mario, Homuth, Marion, Heft, Andreas, Pfuch, Andreas, Grüenler, Bernd E.
• Primary Examiner(s): MCDONALD, RODNEY GLENN
• Application Number:
  US11/178,595
• Publication Number:
  US 20070026241A1
• Time in Patent Office: 2,653 Days
• Field of Search: 204/192.26, 204/192.27, 204/192.28
• US Class Current: 204/192.26
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 2218/17 from a solid phase

Abstract

A coated article for use in spandrel applications and/or the like is provided. In certain example embodiments, a coating is provided to have a coating design which permits the coating to realize more predictable and/or consistent optical characteristics such as glass side reflectance, color and/or the like. Certain example embodiments of this invention relate to a method of making a coated article for spandrel applications or the like. In certain embodiments, a powder inclusive lacquer coating is used as an overcoat.

Claims

1. A method of making a spandrel panel, the method comprising:

providing a glass substrate;

sputter-depositing a layer comprising titanium oxide on the glass substrate;

sputter-depositing a layer comprising silicon nitride on the glass substrate over at least the layer comprising titanium oxide;

thermally tempering the glass substrate with the layers comprising titanium oxide and silicon nitride thereon, so that the article has a Δ

E*_g value of no more than 6.0 due to the thermal tempering;

after said thermal tempering, applying an opaque overcoat layer on the substrate over at least the layers comprising titanium oxide and silicon nitride,

wherein the opaque overcoat layer directly contacts the layer comprising silicon nitride or an optional primer layer which may be provided on the layer comprising silicon nitride; and

wherein after said tempering the glass substrate having the layer comprising titanium oxide and the layer comprising silicon nitride thereon, before the opaque overcoat layer is applied, has a visible transmission of from about 65-90%.

2. The method of claim 1, wherein the article has a Δ

E*_g value of no more than 4.0 due to the thermal tempering.

3. The method of claim 1, wherein the article has a Δ

E*_g value of no more than 2.5 due to the thermal tempering.

4. The method of claim 1, wherein said step of applying an opaque overcoat layer comprises applying a primer layer and then applying a powder paint over the primer layer, and heating the article with the powder paint thereon in an oven or furnace at a temperature of from about 100-300 degrees C. in order to cure and/or burn in the powder paint to the coated article.

5. The method of claim 4, wherein said step of applying the opaque overcoat further comprises, before applying the primer layer, cleaning an exposed surface of the article to be coated with a cleanser comprising an acid alcoholic solution, and thereafter applying the primer layer to the cleansed surface.

6. The method of claim 5, further comprising applying a silicon oxide layer after the cleaning but before application of the primer layer.

7. The method of claim 6, wherein said applying of the silicon oxide layer comprises depositing the silicon oxide layer by flame pyrolysis of at least one organosilane compound(s).

8. A method of making a spandrel panel, the method comprising:

providing a glass substrate;

sputter-depositing a first dielectric layer on the glass substrate;

sputter-depositing a second dielectric layer on the glass substrate over at least the first dielectric layer;

thermally tempering the article including the glass substrate with the first and second dielectric layers thereon to produce a tempered article, wherein after said tempering the tempered coated article with the first and second dielectric layers thereon has a visible transmission of from about 65-90%;

applying a primer layer on the tempered article, and then applying a powder paint over at least the primer layer.

9. The method of claim 8, further comprising heating the article with the powder paint thereon in an oven or furnace at a temperature of from about 100-300 degrees C. in order to cure and/or burn in the powder paint to the coated article.

10. The method of claim 8, wherein (a) the first dielectric layer comprising titanium oxide, and/or (b) the second dielectric layer comprises silicon nitride.

11. The method of claim 10, wherein the first and second dielectric layers directly contact each other.

12. The method of claim 8, wherein following application and curing of the powder paint, the coated article has a glass side reflectance of from about 10-14%, and glass side reflective a* color of from about −

2 to +2.

13. The method of claim 8, further comprising depositing a layer comprising silicon oxide using flame pyrolysis prior to applying the primer layer on the tempered article.