Inkjet recording medium

• US 8,293,343 B2
• Filed: 10/28/2009
• Issued: 10/23/2012
• Est. Priority Date: 11/05/2008
• Status: Expired due to Fees

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Inventors: Nakano, Ryoichi
• Primary Examiner(s): Shewareged, Betelhem
• Application Number:
  US12/607,087
• Publication Number:
  US 20100112245A1
• Time in Patent Office: 1,091 Days
• Field of Search: 428/32.21, 428/32.26, 428/32.27, 428/32.28, 428/32.29, 428/32.3, 428/32.34
• US Class Current: 428/32.21
• CPC Class Codes: B41M 5/508 Supports
• CPC Class Codes: B41M 5/52 Macromolecular coatings
• CPC Class Codes: B41M 5/5218 characterised by inorganic additives, e.g. pigments, clays
• CPC Class Codes: B41M 5/5227 characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
• CPC Class Codes: B41M 5/5245 characterised by the use of polymers containing cationic or anionic groups, e.g. mordants

Abstract

An inkjet recording medium having a substrate and, on or above the substrate, an ink-receiving layer is disclosed. The ink-receiving layer contains at least one type of inorganic fine particles, at least one water-soluble resin, and at least one ethylene oxide adduct of an acetylene glycol compound having an HLB value of 6 or less.

Claims

1. An inkjet recording medium comprising a substrate and, provided on or above the substrate, an ink-receiving layer comprising at least one type of inorganic fine particles, at least one water-soluble resin, and at least one ethylene oxide adduct of an acetylene glycol compound having an HLB value of from 2 to 6, wherein a content of the ethylene oxide adduct of the acetylene glycol compound in the ink-receiving layer is from 0.01 to 0.2 g/m² and the ethylene oxide adduct of the acetylene glycol compound is a compound represented by the following Formula (1):

2. The inkjet recording medium as claimed in claim 1, wherein the ethylene oxide adduct of the acetylene glycol compound has a structure that is a product of addition of at least one ethylene oxide to an acetylene glycol compound having a carbon-carbon triple bond and two hydroxyl groups in the molecule thereof.

3. The inkjet recording medium as claimed in claim 1, wherein, in Formula (I), each of R¹ and R² is an isobutyl group;

each of R³ and R⁴ is a methyl group; and

the total of m and n is 1 or 2.

4. The inkjet recording medium as claimed in claim 1, wherein the content of the ethylene oxide adduct of acetylene glycol compound represented by Formula (I) in the ink-receiving layer is from 0.03 to 0.15 g/m² and the ethylene oxide adduct of the acetylene glycol compound has an HLB value of from 3 to 5.

5. The inkjet recording medium as claimed in claim 1, wherein the inorganic particles comprise at least one selected from the group consisting of silica fine particles, alumina fine particles and pseudo-boehmite.

6. The inkjet recording medium as claimed in claim 1, wherein the water-soluble resin comprises at least one water-soluble resin selected from polyvinyl alcohol resins, cellulose resins, resins having ether links, resins having carbamoyl groups, gelatins or other resins having carboxyl groups.

7. The inkjet recording medium as claimed in claim 1, wherein the ratio of the inorganic fine particle content (x) by mass to the water-soluble resin content (y) by mass [PB ratio (x/y)] is from 1.5 to 10.

8. The inkjet recording medium as claimed in claim 7, wherein the PB ratio (x/y) is from 2 to 5.

9. The inkjet recording medium as claimed in claim 7, wherein the x/y ratio in an upper-side half of the ink-receiving layer is equal to or higher than the x/y ratio in a lower-side half of the ink-receiving layer.

10. The inkjet recording medium as claimed in claim 1, wherein the ink-receiving layer further comprises a crosslinking agent and is a porous layer formed by hardening the water-soluble resin due to a crosslinking reaction with the crosslinking agent.

11. The inkjet recording medium as claimed in claim 1, wherein the ink-receiving layer further comprises at least one water-soluble multivalent metal compound as a mordant.

12. The inkjet recording medium as claimed in claim 1, wherein the ink-receiving layer further comprises at least one organic nitrogen-containing cationic polymer.

13. The inkjet recording medium as claimed in claim 1, wherein the ink-receiving layer further comprises at least one sulfur-based compound.