Methods for providing light extraction films on organic light emitting diode devices

• US 8,298,032 B2
• Filed: 06/01/2011
• Issued: 10/30/2012
• Est. Priority Date: 07/13/2007
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Potts, John E., McCormick, Fred B., Wolk, Martin B., Zhang, Jun-Ying, Smith, Terry L., Battiato, James M., Wang, Ding, Tolbert, William A., Roehrig, Mark A., Bright, Clark I.
• Primary Examiner(s): Mai, Anh T.
• Assistant Examiner(s): COUGHLIN, ANDREW J
• Application Number:
  US13/150,590
• Publication Number:
  US 20110229992A1
• Time in Patent Office: 517 Days
• Field of Search: 445 23- 25, 313/512
• US Class Current: 445/24
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: G02F 1/133603 with LEDs
• CPC Class Codes: G02F 2202/02 organic material
• CPC Class Codes: H05B 33/22 characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
• CPC Class Codes: H10K 2102/331 Nanoparticles used in non-emissive layers, e.g. in packaging layer
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 59/877 comprising scattering means

Abstract

A multifunctional optical film for enhancing light extraction includes a flexible substrate, a structured layer, and a backfill layer. The structured layer effectively uses microreplicated diffractive or scattering nanostructures located near enough to the light generation region to enable extraction of an evanescent wave from an organic light emitting diode (OLED) device. The backfill layer has a material having an index of refraction different from the index of refraction of the structured layer. The backfill layer also provides a planarizing layer over the structured layer in order to conform the light extraction film to a layer of an OLED lighting device such as solid state lighting devices or backlight units. The film may have additional layers added to or incorporated within it to an emissive surface in order to effect additional functionalities beyond improvement of light extraction efficiency.

Claims

1. A method for providing a light extraction film on an organic light emitting diode (OLED) device having a surface that outputs light, comprising:

providing a light extraction film, comprising;

a flexible substrate substantially transmissive to light emitted by the OLED device;

a structured layer of extraction elements disposed on the substrate and having a first index of refraction,

wherein the extraction elements comprise a nanostructured surface of the structured layer on a side of the structured layer opposite the substrate,

wherein the nanostructured surface comprises non-particle based features in the structured layer; and

a backfill layer comprising a material having a second index of refraction different from the first index of refraction, wherein the backfill layer forms a planarizing layer over the nanostructured surface, forming a planar surface on a side of the backfill layer opposite the nanostructured surface,

wherein a substantial portion of the extraction elements are within an evanescent zone of the light output surface of the OLED device when the planar surface of the backfill layer is located against the light output surface of the OLED device,

wherein the structured layer and backfill layer are in sufficient proximity to the light output surface of the OLED device when the planar surface of the backfill layer is located against the light output surface of the OLED device in order to at least partially enhance the extraction of light from the light output surface, and

wherein the backfill layer comprises a non-scattering nanoparticle filled polymer material;

applying an optical coupling layer to the planar surface of the backfill layer; and

laminating the light extraction film to the OLED device such that the planar surface of the backfill layer is located against the light output surface of the OLED device,

wherein the optical coupling layer provides for optical coupling between the light output surface of the OLED device and the backfill layer.

2. The method of claim 1, wherein the applying step includes applying an adhesive as the optical coupling layer.

3. A method for providing a light extraction film on an organic light emitting diode (OLED) device having a surface that outputs light, comprising:

providing a light extraction film, comprising;

a flexible substrate substantially transmissive to light emitted by the OLED device;

a structured layer of extraction elements disposed on the substrate and having a first index of refraction,

wherein the extraction elements comprise a nanostructured surface of the structured layer on a side of the structured layer opposite the substrate,

wherein the nanostructured surface comprises non-particle based features in the structured layer; and

a backfill layer comprising a material having a second index of refraction different from the first index of refraction, wherein the backfill layer forms a planarizing layer over the nanostructured surface, forming a planar surface on a side of the backfill layer opposite the nanostructured surface,

wherein a substantial portion of the extraction elements are within an evanescent zone of the light output surface of the OLED device when the planar surface of the backfill layer is located against the light output surface of the OLED device,

wherein the structured layer and backfill layer are in sufficient proximity to the light output surface of the OLED device when the planar surface of the backfill layer is located against the light output surface of the OLED device in order to at least partially enhance the extraction of light from the light output surface, and

wherein the backfill layer comprises a non-scattering nanoparticle filled polymer material;

applying an optical coupling layer to the light output surface of the OLED device; and

laminating the light extraction film to the OLED device such that the planar surface of the backfill layer is located against the light output surface of the OLED device,

wherein the optical coupling layer provides for optical coupling between the light output surface of the OLED device and the backfill layer.

4. The method of claim 3, wherein the applying step includes applying an adhesive as the optical coupling layer.