System and method for protection of SCR catalyst and control of multiple emissions

• US 8,303,919 B2
• Filed: 10/21/2010
• Issued: 11/06/2012
• Est. Priority Date: 10/21/2010
• Status: Active Grant

• Current Assignee: Babcock & Wilcox Company (Babcock International Group PLC)
• Original Assignee: Babcock & Wilcox Power Generation Group Incorporated (Babcock International Group PLC)
• Inventors: Gadgil, Mandar R., Ghorishi, S. Behrooz, Jankura, Bryan J.
• Primary Examiner(s): VANOY, TIMOTHY C
• Application Number:
  US12/909,753
• Publication Number:
  US 20120100052A1
• Time in Patent Office: 747 Days
• Field of Search: 423/210, 502/439, 502/520, 502/521
• US Class Current: 423/210
• CPC Class Codes: B01D 2251/2062 Ammonia
• CPC Class Codes: B01D 2253/11 Clays
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/55 Compounds of silicon, phosphorus, germanium or arsenic
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 53/8625 Nitrogen oxides
• CPC Class Codes: B01D 53/90 Injecting reactants
• CPC Class Codes: B01J 20/0229 Compounds of Fe
• CPC Class Codes: B01J 20/12 Naturally occurring clays or bleaching earth
• CPC Class Codes: F23J 15/003 for supplying chemicals to fumes, e.g. using injection devices
• CPC Class Codes: F23J 2215/10 Nitrogen; Compounds thereof
• CPC Class Codes: F23J 2219/10 Catalytic reduction devices
• CPC Class Codes: F23J 7/00 Arrangement of devices for supplying chemicals to fire
• CPC Class Codes: F23K 1/00 Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
• CPC Class Codes: F23K 2201/505 with additives

Abstract

The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus for preventing the poisoning and/or contamination of an SCR catalyst. In another embodiment, the method and apparatus of the present invention is designed to protect an SCR catalyst, while simultaneously providing emission control.

Claims

1. A method for increasing the active life of an SCR catalyst, the method comprising the steps of:

(a) providing at least one kaolin-bearing compound to a combustion zone or flue gas stream of a furnace, or boiler, prior to entry of the flue gas into an SCR; and

(b) permitting the at least one kaolin-bearing compound to react with any gaseous potassium and/or sodium compounds, or potassium- and/or sodium-containing compounds present in the combustion zone or flue gas prior to the entry of the flue gas into the SCR.

2. The method of claim 1, wherein the kaolin-bearing compound is selected from one or more kaolin-containing clays, kaolinite-containing clays, kaolinite, or mixtures of two or more thereof.

3. The method of claim 1, wherein the kaolin-bearing compound is selected from kaolinite.

4. The method of claim 1, wherein the at least one kaolin-bearing compound is provided to the combustion zone via addition to pulverized coal, biomass, or a mixture thereof.

5. The method of claim 1, wherein the at least one kaolin-bearing compound is provided to the combustion zone via a dedicated supply line.

6. The method of claim 1, wherein the method further comprises the steps of:

(c) providing at least one iron-bearing compound to a combustion zone or flue gas stream of a furnace, or boiler, prior to entry of the flue gas into an SCR; and

(d) permitting the at least one iron-bearing compound to react with any gaseous phosphorus compounds, or phosphorus-containing compounds, present in the combustion zone or flue gas prior to the entry of the flue gas into the SCR.

7. A method for increasing the active life of an SCR catalyst, the method comprising the steps of:

(i) providing at least one kaolin-bearing compound to a combustion zone of a furnace or boiler; and

(ii) permitting the at least one kaolin-bearing compound to react with any gaseous potassium and/or sodium compounds, or potassium- and/or sodium-containing compounds present in the combustion zone prior to the entry of the flue gas into an SCR,

wherein the kaolin-bearing compound is selected from one or more kaolin-containing clays, kaolinite-containing clays, kaolinite, or mixtures of two or more thereof.

8. The method of claim 7, wherein the at least one kaolin-bearing compound is provided to the combustion zone via addition to pulverized coal, biomass, or a mixture thereof.

9. The method of claim 7, wherein the at least one kaolin-bearing compound is provided to the combustion zone via a dedicated supply line either in aqueous suspension or in a powdered form.

10. The method of claim 7, wherein the method further comprises the steps of:

(iii) providing at least one iron-bearing compound to a combustion zone of a furnace or boiler; and

(iv) permitting the at least one iron-bearing compound to react with any gaseous phosphorus compounds, or phosphorus-containing compounds, present in the combustion zone prior to the entry of the flue gas into an SCR.

11. A method for increasing the active life of an SCR catalyst while concurrently controlling mercury in a gas, the method comprising the steps of:

(I) providing at least one kaolin-bearing compound to a combustion zone or flue gas stream of a furnace, or boiler, prior to entry of the flue gas into an SCR;

(II) providing at least one iron-bearing halide compound to a combustion zone or flue gas stream of a furnace, or boiler, prior to entry of the flue gas into an SCR;

(III) permitting the kaolin portion of the at least one kaolin-bearing compound to react with any gaseous potassium and/or sodium compounds, or potassium- and/or sodium-containing compounds present in the combustion zone or flue gas prior to the entry of the flue gas into the SCR;

(IV) permitting the iron portion of the at least one iron-bearing halide compound to react with any gaseous phosphorus compounds, or phosphorus-containing compounds present in the combustion zone or flue gas prior to the entry of the flue gas into the SCR; and

(V) permitting the halide portion of the at least one iron-bearing halide compound to react with any gaseous mercury compounds, or mercury-containing compounds, present in the combustion zone or flue gas.

12. The method of claim 11, wherein the kaolin-bearing compound is selected from one or more kaolin-containing clays, kaolinite-containing clays, kaolinite, or mixtures of two or more thereof.

13. The method of claim 11, wherein the kaolin-bearing compound is selected from kaolinite.

14. The method of claim 11, wherein the iron-bearing halide compound is selected from iron (II) bromide, iron (III) bromide, iron (II) chloride, iron (III) chloride, iron (II) iodide, iron (III) iodate, or mixtures of two or more thereof.

15. The method of claim 11, wherein the iron-bearing halide compound is iron (II) bromide.

16. The method of claim 11, further comprising supplying one or more non-halogen-containing iron-bearing compounds in combination with the at least one iron-bearing halide, where the one or more non-halogen-containing iron-bearing compounds are selected from iron (III) oxide, iron (II) carbonate, iron (II) oxide, or mixtures of two or more thereof.

17. The method of claim 11, further comprising supplying iron (II) carbonate in combination with the at least one iron-bearing halide.

18. The method of claim 11, further comprising supplying iron (II) carbonate in combination with one or more of iron (II) bromide or iron (III) bromide.

19. A method for sequestering one or more potassium and/or sodium compounds, or potassium- and/or sodium-containing compounds, in the form of one or more less reactive sodium aluminosilicate-containing, or potassium aluminosilicate-containing, compounds, as well as sequestering one or more phosphorus compounds, or phosphorus-containing compounds, in the form of one or more less reactive iron-phosphorus-containing compounds while concurrently sequestering mercury, the method comprising the steps of:

(1) providing at least one kaolin-bearing compound to a combustion zone or flue gas stream of a furnace, or boiler;

(2) providing at least one iron-bearing halide compound to a combustion zone or flue gas stream of a furnace, or boiler;

(3) permitting the kaolin portion of the at least one kaolin-bearing compound to react with any gaseous potassium and/or sodium compounds, or potassium- and/or sodium-containing compounds present in the combustion zone or flue gas to form one or more less reactive sodium aluminosilicate-containing, or potassium aluminosilicate-containing, compounds;

(4) permitting the iron portion of the at least one iron-bearing halide compound to react with any gaseous phosphorus compounds, or phosphorus-containing compounds, present in the combustion zone or flue gas to form one or more less reactive iron-phosphorus-containing compounds; and

(5) permitting the halide portion of the at least one iron-bearing halide compound to react with any gaseous mercury compounds, or mercury-containing compounds, present in the combustion zone or flue gas.

20. The method of claim 19, wherein the kaolin-bearing compound is selected from one or more kaolin-containing clays, kaolinite-containing clays, kaolinite, or mixtures of two or more thereof.

21. The method of claim 19, wherein the kaolin-bearing compound is selected from kaolinite.

22. The method of claim 19, wherein the iron-bearing halide compound is selected from iron (II) bromide, iron (III) bromide, iron (II) chloride, iron (III) chloride, iron (II) iodide, iron (III) iodate, or mixtures of two or more thereof.

23. The method of claim 19, wherein the iron-bearing halide compound is one or more of iron (II) bromide or iron (III) bromide.

24. The method of claim 19, further comprising supplying one or more non-halogen-containing iron-bearing compounds in combination with the at least one iron-bearing halide, where the one or more non-halogen-containing iron-bearing compounds are selected from iron (III) oxide, iron (II) carbonate, iron (II) oxide, or mixtures of two or more thereof.

25. The method of claim 19, further comprising supplying iron (II) carbonate in combination with the at least one iron-bearing halide.

26. The method of claim 19, further comprising supplying iron (II) carbonate in combination with one or more of iron (II) bromide or iron (III) bromide.