Thermally stable nanoparticles on supports

• US 8,309,489 B2
• Filed: 06/18/2010
• Issued: 11/13/2012
• Est. Priority Date: 06/18/2009
• Status: Active Grant

• Current Assignee: University of Central Florida Research Foundation Inc. (State University System of Florida)
• Original Assignee: University of Central Florida Research Foundation Inc. (State University System of Florida)
• Inventors: Roldan Cuenya, Beatriz, Naitabdi, Ahmed R., Behafarid, Farzad
• Primary Examiner(s): Nguyen, Cam N.
• Application Number:
  US12/818,928
• Publication Number:
  US 20100323884A1
• Time in Patent Office: 879 Days
• Field of Search: 502182-185, 502/332, 502/333, 502/334, 502/339, 502/350, 502/351, 502/355, 502/415, 502/439, 977/773, 977/775
• US Class Current: 502/339
• CPC Class Codes: B01D 2255/1021 Platinum
• CPC Class Codes: B01D 2255/1023 Palladium
• CPC Class Codes: B01D 2255/20707 Titanium
• CPC Class Codes: B01D 2255/2092 Aluminium
• CPC Class Codes: B01D 2255/9202 Linear dimensions
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 53/88 Handling or mounting catalysts
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 21/066 Zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 23/42 Platinum
• CPC Class Codes: B01J 23/52 Gold
• CPC Class Codes: B01J 23/62 with gallium, indium, thallium, germanium, tin or lead
• CPC Class Codes: B01J 23/745 Iron
• CPC Class Codes: B01J 23/8906 Iron and noble metals
• CPC Class Codes: B01J 35/23 in a colloidal state
• CPC Class Codes: B01J 35/393 Metal or metal oxide crystallite size
• CPC Class Codes: B01J 37/0203 the impregnation liquid containing organic compounds
• CPC Class Codes: B01J 37/0211 using a colloidal suspension
• CPC Class Codes: B01J 37/14 with gases containing free oxygen
• CPC Class Codes: B01J 37/349 : making use of flames, plasmas or lasers

Abstract

An inverse micelle-based method for forming nanoparticles on supports includes dissolving a polymeric material in a solvent to provide a micelle solution. A nanoparticle source is dissolved in the micelle solution. A plurality of micelles having a nanoparticle in their core and an outer polymeric coating layer are formed in the micelle solution. The micelles are applied to a support. The polymeric coating layer is then removed from the micelles to expose the nanoparticles. A supported catalyst includes a nanocrystalline powder, thin film, or single crystal support. Metal nanoparticles having a median size from 0.5 nm to 25 nm, a size distribution having a standard deviation ≦0.1 of their median size are on or embedded in the support. The plurality of metal nanoparticles are dispersed and in a periodic arrangement. The metal nanoparticles maintain their periodic arrangement and size distribution following heat treatments of at least 1,000° C.

Claims

1. A supported catalyst, comprising:

a support comprising a nanocrystalline powder, a thin film, or a single crystal;

a plurality of metal nanoparticles having a median size from 0.5 nm to 25 nm, a size distribution having a standard deviation ≦

0.1 of said median size on or embedded in said support, said plurality of metal nanoparticles being dispersed from one another and positioned in a periodic arrangement.

2. The supported catalyst of claim 1, wherein said support comprises said thin film or said single crystal, and wherein said thin film or said single crystal includes a metal oxide surface.

3. The supported catalyst of claim 2, wherein said metal oxide surface comprises alumina or titania.

4. The supported catalyst of claim 3, further comprising raised metal oxide stripes on said metal oxide surface, wherein said raised metal oxide stripes are raised 0.3 to 0.6 nm above surrounding portions of said metal oxide surface.

5. The supported catalyst of claim 4, wherein said plurality of metal nanoparticles comprise Pt or Pd.

6. The supported catalyst of claim 1, wherein said plurality of metal nanoparticles have a median size from 0.5 to 5 nm.

7. The supported catalyst of claim 1, further comprising a carbon comprising adhesion layer interposed between said support and said plurality of nanoparticles that enhances adhesion between said support and said plurality of nanoparticles so that said plurality of metal nanoparticles maintain said periodic arrangement and said size distribution following heat treatments of at least 1,000°

C.

8. The supported catalyst of claim 7, wherein said carbon comprising adhesion layer is about 1 to 2 nm thick.

9. A supported catalyst, comprising:

a support comprising an oxide thin film, or a single crystal having an oxide surface;

a plurality of metal nanoparticles comprising Pt or Pd having a median size from 0.5 nm to 5 nm, a size distribution having a standard deviation ≦

0.1 of said median size on or embedded in said support, said plurality of metal nanoparticles being dispersed from one another and positioned in a periodic arrangement.

10. The supported catalyst of claim 9, wherein said oxide comprises titania and said oxide surface comprises a titania surface, and wherein said periodic arrangement comprises hexagonal, further comprising raised titania stripes on said titania surface, wherein said raised titania stripes are raised 0.3 to 0.6 nm above surrounding portions of said titania surface.

11. The supported catalyst of claim 9, further comprising a carbon comprising adhesion layer interposed between said support and said plurality of nanoparticles that enhances adhesion between said support and said plurality of nanoparticles sufficiently so that said plurality of metal nanoparticles maintain said periodic arrangement and said size distribution following heat treatments of at least 1,000°

C.

12. The supported catalyst of claim 11, wherein said carbon comprising adhesion layer is about 1 to 2 nm thick.