Dental mill blanks

• US 8,317,516 B2
• Filed: 10/28/2010
• Issued: 11/27/2012
• Est. Priority Date: 01/08/1999
• Status: Expired due to Fees

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Rusin, Richard P., Cummings, Kevin M., Carufel, Roger J.
• Primary Examiner(s): LEWIS, RALPH A
• Application Number:
  US12/914,433
• Publication Number:
  US 20110045436A1
• Time in Patent Office: 761 Days
• Field of Search: 433/212.1, 433/213, 433/223, 264/19
• US Class Current: 433/223
• CPC Class Codes: A61C 13/0022 Blanks or green, unfinished dental restoration parts
• CPC Class Codes: A61K 6/887 Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: A61K 6/891 Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: A61K 6/893 Polyurethanes
• CPC Class Codes: C08L 33/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C08L 75/16 having terminal carbon-to-carbon unsaturated bonds

Abstract

A dental mill blank including a resin and a filler, wherein the blank is fabricated such that it passes a Thermal Shock Test. The mill blank is substantially free of cracks and discontinuities. Further, the blank may have superior cuttability and hardness.

Claims

1. A dental mill blank suitable for the oral environment prepared by a method comprising:

mixing a paste comprising a resin and a filler,

adding a fluoride releasing material to the paste,

shaping the paste into a desired configuration,

minimizing material discontinuities from the paste,

curing the paste into a blank, and

heating the blank to a temperature at or above the Tg of the resin for a time sufficient to relieve internal stresses in the blank,

wherein the cured mill blank, when immersed in liquid nitrogen for about two minutes, does not explode and no cracks are observed upon visual inspection, and

wherein the dental mill blank is suitable for making a dental prosthetic selected from the group consisting of onlays, full crowns, partial crowns, bridges, implants, and posts.

2. A dental prosthetic suitable for the oral environment prepared by a method comprising:

providing a dental mill blank comprising a cured resin and a filler;

heating the dental mill blank to a temperature at or above the Tg of the resin for a time sufficient to relieve internal stresses in the blank; and

carving the heated blank into a desired shape and morphology for a dental prosthetic,

wherein the dental prosthetic, when immersed in liquid nitrogen for about two minutes, does not explode and no cracks are observed upon visual inspection, and

wherein the dental prosthetic is selected from the group consisting of onlays, full crowns, partial crowns, bridges, implants, and posts.

3. The dental prosthetic of claim 2 wherein the method further comprises milling the blank on a milling machine.

4. The dental prosthetic of claim 2 wherein the method further comprises attaching the carved blank to a tooth or bone structure.

5. The dental prosthetic of claim 2 wherein the method further comprises attaching a handle to the cured mill blank.

6. The dental prosthetic of claim 2 wherein the cured resin is derived from a resin selected from the group consisting of a free radically curable monomer, a free radically curable oligomer, a free radically curable polymer, a cationically curable monomer, a cationically curable oligomer, a cationically curable polymer, and combinations thereof.

7. The dental prosthetic of claim 6 wherein the cured resin is an acrylate or methacrylate resin.

8. The dental prosthetic of claim 6 wherein the cured resin is an epoxy resin.

9. A dental prosthetic suitable for the oral environment prepared by a method comprising:

mixing components comprising a resin and a filler;

shaping the mixture into a desired configuration;

minimizing material discontinuities;

curing the mixture into a blank;

heating the blank to a temperature at or above the Tg of the resin for a time sufficient to relieve internal stresses in the blank; and

carving the heated blank into a desired shape and morphology for the dental prosthetic,

wherein the dental prosthetic, when immersed in liquid nitrogen for about two minutes, does not explode and no cracks are observed upon visual inspection, and

wherein the dental prosthetic is selected from the group consisting of onlays, full crowns, partial crowns, bridges, implants, and posts.

10. The dental prosthetic of claim 9 wherein carving comprises carving by a milling machine.

11. The dental prosthetic of claim 9 wherein a contact area between the blank and milling machine is dry or flushed with a lubricant.

12. The dental prosthetic of claim 9 wherein the method further comprises attaching the carved blank to a tooth or bone structure.

13. The dental prosthetic of claim 9 wherein the method further comprises attaching a handle to the cured mill blank.

14. The dental prosthetic of claim 9 wherein curing comprises initiation of polymerization by one or more of heat, light, radiation, e-beam, microwave, or chemical reaction.

15. The dental prosthetic of claim 9 wherein the resin is selected from the group consisting of a free radically curable monomer, a free radically curable oligomer, a free radically curable polymer, a cationically curable monomer, a cationically curable oligomer, a cationically curable polymer, and combinations thereof.

16. The dental prosthetic of claim 9 wherein the resin is an acrylate or methacrylate resin.

17. The dental prosthetic of claim 9 wherein the resin is an epoxy resin.

18. The dental prosthetic of claim 9 wherein the method further comprises application of pressure or vacuum during one or more of the steps of making the heated blank.

19. The dental prosthetic of claim 18 wherein the applied pressure comprises one or more of isostatic pressure, uniaxial pressure, centrifugal pressure, impact pressure, or pressurized gas.

20. The dental prosthetic of claim 9 wherein the components further comprise an initiator system selected from the group consisting of free radical-generating thermal initiators, thermal redox initiators, photoinitiators, and dual initiation systems.