Enhanced cavity for a photoacoustic gas sensor

• US 8,322,191 B2
• Filed: 06/30/2010
• Issued: 12/04/2012
• Est. Priority Date: 06/30/2010
• Status: Expired due to Fees

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Fritz, Bernard
• Primary Examiner(s): Caputo, Lisa
• Assistant Examiner(s): ROY, PUNAM P
• Application Number:
  US12/827,873
• Publication Number:
  US 20120000271A1
• Time in Patent Office: 888 Days
• Field of Search: 356/432, 356/437, 73/240.2
• US Class Current: 73/24.02
• CPC Class Codes: G01N 2021/0382 Frustoconical, tapered cell
• CPC Class Codes: G01N 2021/1704 in gases
• CPC Class Codes: G01N 21/0303 Optical path conditioning in cuvettes, e.g. windows; adapted optical elements or systems; path modifying or adjustment G01N21/031 - G01N21/15 take precedence
• CPC Class Codes: G01N 21/031 Multipass arrangements
• CPC Class Codes: G01N 21/1702 with opto-acoustic detection, e.g. for gases or analysing solids
• CPC Class Codes: G01N 2291/0215 Mixtures of three or more gases, e.g. air
• CPC Class Codes: G01N 29/2425 optoacoustic fluid cells therefor

Abstract

Photoacoustic cells for gas sensors are described. In some instances, the photoacoustic cell may be configured to provide an increased internal path length of the light beam in the photoacoustic cell relative to, for example, a conventional cylindrical photoacoustic cell. The photoacoustic cell may be shaped to provide increased internal reflection of the light within the photoacoustic cell, thereby increasing the absorption of the light by a gas to be detected in the photoacoustic cell. One example photoacoustic cell that can provide such increased internal reflection may be a generally conical-shaped.

Claims

1. A photoacoustic gas sensor comprising:

an electromagnetic radiation source configured to emit electromagnetic radiation;

a photoacoustic cell configured to receive a gas sample to be detected, wherein the photoacoustic cell includes an optical element adjacent the photoacoustic cell and configured to transmit at least part of the electromagnetic radiation into the photoacoustic cell, wherein the photoacoustic cell includes a front wall, a reflective back wall, and reflective side walls extending between the front wall and the back wall to collectively define an optical cavity, wherein the optical element is positioned adjacent the front wall and opposite the back wall, wherein the cross-sectional area defined by the side walls increases from the front wall toward the back wall, and wherein the electromagnetic radiation transmitted into the photoacoustic cell first reflects off the reflective back wall of the photoacoustic cell; and

an acoustical detector acoustically coupled to the photoacoustic cell, the acoustical detector configured to detect an acoustic signal that is related to absorption of the electromagnetic radiation by the gas sample in the photoacoustic cell.

2. The photoacoustic gas sensor of claim 1, wherein the optical element is configured to only transmit a band of wavelengths corresponding to an absorption line of a gas to be detected.

3. The photoacoustic gas sensor of claim 1, wherein the electromagnetic radiation emitted by the electromagnetic radiation source has a wavelength corresponding to an absorption line of the gas to be detected.

4. The photoacoustic gas sensor of claim 1, wherein the optical cavity of the photoacoustic cell is shaped to increase an optical path length of the electromagnetic radiation internal to the photoacoustic cell.

5. The photoacoustic gas sensor of claim 1, wherein at least one of the side walls is at a non-orthogonal angle relative to the back wall.

6. The photoacoustic gas sensor of claim 1, wherein the back wall is non-parallel with the optical element.

7. The photoacoustic gas sensor of claim 1, wherein at least one of the back wall and side walls is curved.

8. The photoacoustic gas sensor of claim 1, wherein the photoacoustic cell is conical in shape.

9. The photoacoustic gas sensor of claim 1, wherein the photoacoustic gas sensor is generally free from optical elements positioned between the electromagnetic radiation source and the optical element of the photoacoustic cell.

10. A photoacoustic gas sensor comprising:

an electromagnetic radiation source configured to emit electromagnetic radiation;

a photoacoustic cell configured to receive a gas sample to be detected, wherein the photoacoustic cell includes an optical element adjacent the photoacoustic cell and configured to transmit at least part of the electromagnetic radiation into the photoacoustic cell, wherein the photoacoustic cell includes a front wall, a reflective back wall, and reflective side walls extending between the front wall and the back wall to collectively define an optical cavity, wherein the optical element is positioned adjacent the front wall and opposite the back wall, and wherein the cross-sectional area defined by the side walls increases from the front wall toward the back wall;

an acoustical detector acoustically coupled to the photoacoustic cell, the acoustical detector configured to detect an acoustic signal that is related to absorption of the electromagnetic radiation by the gas sample in the photoacoustic cell;

wherein the optical element includes a rear side facing toward the back wall of the photoacoustic cell;

wherein the rear side of the optical element reflects electromagnetic radiation when an incident angle of the electromagnetic radiation is greater than a threshold angle, and transmits electromagnetic radiation when the incident angle is less than the threshold angle; and

wherein the photoacoustic cell is shaped such that at least a majority of the electromagnetic radiation that is transmitted through the optical element and into the cavity of the photoacoustic cell has an incident angle that is greater than the threshold angle for at least a first time that the electromagnetic radiation returns to the rear side of the optical element.

11. A photoacoustic gas sensor comprising:

an electromagnetic radiation source configured to emit electromagnetic radiation;

a photoacoustic cell configured to receive a gas sample to be detected, wherein the photoacoustic cell includes an optical element adjacent the photoacoustic cell that is configured to transmit at least part of the electromagnetic radiation into the photoacoustic cell, wherein the photoacoustic cell includes a front wall, a reflective back wall, and reflective side walls extending between the front wall and the back wall to collectively define an optical cavity, wherein the optical element is positioned adjacent to and/or forms at least part of the front wall, and wherein the cross-sectional area defined by the side walls increases monotonically from the front wall toward the back wall; and

an acoustical detector acoustically coupled to the photoacoustic cell, the acoustical detector configured to detect an acoustic signal that is related to absorption of the electromagnetic radiation by the gas sample in the photoacoustic cell.

12. The photoacoustic gas sensor of claim 11, wherein at least one of the side walls is at a non-orthogonal angle relative to the back wall.

13. The photoacoustic gas sensor of claim 11, wherein at least one of the back wall and side walls is curved.