Method for preparing three-dimensional plaster objects

• US 8,323,429 B2
• Filed: 07/31/2009
• Issued: 12/04/2012
• Est. Priority Date: 07/31/2009
• Status: Active Grant

• Current Assignee: United States Gypsum Company (GEBR Knauf Verwaltungsgesellschaft KG)
• Original Assignee: United States Gypsum Company (GEBR Knauf Verwaltungsgesellschaft KG)
• Inventors: Immordino, Salvatore C., Yeung, Lee K.
• Primary Examiner(s): ORLANDO, MICHAEL N
• Application Number:
  US12/533,774
• Publication Number:
  US 20110024028A1
• Time in Patent Office: 1,222 Days
• Field of Search: 156/39, 156/244.11, 427/265
• US Class Current: 156/39
• CPC Class Codes: C04B 2103/44 Thickening, gelling or viscosity increasing agents
• CPC Class Codes: C04B 2103/46 Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
• CPC Class Codes: C04B 2103/67 Biocides
• CPC Class Codes: C04B 2103/69 Fungicides
• CPC Class Codes: C04B 2111/00181 Mixtures specially adapted for three-dimensional printing (3DP), stereo-lithography or prototyping
• CPC Class Codes: C04B 28/145 Calcium sulfate hemi-hydrate with a specific crystal form
• CPC Class Codes: C04B 40/0658 Retarder inhibited mortars activated by the addition of accelerators or retarder-neutralising agents

Abstract

The present invention relates to a method for producing three-dimensional plaster objects via thin layer deposition. The inventive method comprises steps of depositing a layer of a calcium sulfate hemihydrate slurry onto the surface of a support in a predetermined pattern and activating the slurry with an activating agent so as to accelerate the setting reaction of calcium sulfate hemihydrate and water to form set calcium sulfate dihydrate. The depositing and activating steps can be repeated as necessary until the desired three-dimensional plaster object is formed.

Claims

1. A method for producing a three-dimensional plaster object having a desired shape, the method comprising:

(a) depositing a first layer of a calcium sulfate hemihydrate slurry that does not contain activating agents onto a support substrate in a predetermined pattern using a spray head,

(b) activating the first layer of the calcium sulfate hemihydrate slurry by depositing at least one first activating agent on top of said first layer,

(c) depositing a second layer of the calcium sulfate hemihydrate slurry on top of the first layer of the calcium sulfate hemihydrate slurry that was activated in step (b),

(d) depositing at least one second activating agent on top of said second layer, wherein the first and second activating agents can be the same or different,

(e) repeating steps (c) and (d) to form additional layers until the three-dimensional plaster object is formed, and

(f) removing the three-dimensional plaster object from the support substrate,

wherein the activating agents are present in amounts sufficient to accelerate the setting reaction of calcium sulfate hemihydrate and water to form set calcium dihydrate;

wherein the layers of calcium sulfate hemihydrate slurry are deposited in thicknesses of about 0.01 mm to about 1.0 mm;

and wherein no machining is required to form the plaster object into the desired shape.

2. The method of claim 1, wherein the calcium sulfate hemihydrate slurry further comprises a binder, a flow modifier, a water retainer, a rheology modifier, an anti-sedimentation additive, a biocide, a fungicide, or combinations thereof.

3. The method of claim 1, wherein the calcium sulfate hemihydrate slurry further comprises a calcium sulfate hemihydrate set inhibitor, wherein the calcium sulfate hemihydrate set inhibitor is present in an amount sufficient to deactivate the setting reaction of calcium sulfate hemihydrate and water to form set calcium sulfate dihydrate.

4. The method of claim 3, wherein the calcium sulfate hemihydrate slurry further comprises a binder, a flow modifier, a water retainer, a rheology modifier, an anti-sedimentation additive, a biocide, a fungicide, or combinations thereof.

5. The method of claim 3, wherein the calcium sulfate hemihydrate set inhibitor is present in an amount of about 0.01 to about 2.00 weight-percent.

6. The method of claim 3, wherein the calcium sulfate hemihydrate set inhibitor is selected from a group consisting of low molecular weight polymers or copolymers of vinyl acrylates, vinyl acetates, vinyl chlorides, ethylene, styrene, substituted ethylene, and substituted styrene, and polyphosphonic compounds, and combinations thereof.

7. The method of claim 6, wherein the calcium sulfate hemihydrate set inhibitor is a polyphosphonic compound selected from a group consisting of tetrasodiumpyrophosphate, tetrapotassiumpyrophosphate, hexamethylene diamine tetra(methylene phosphonic acid), and combinations thereof.

8. The method of claim 1, wherein the first activating agent and the second activating agent are aqueous solutions or slurries comprising at least one salt, wherein the cation of the at least one salt is selected from a group consisting of aluminum, zinc, iron, an alkali metal, and an alkaline earth metal.

9. The method of claim 8, wherein the anion of the at least one salt is sulfate or chloride.

10. The method of claim 9, wherein the at least one salt is selected from a group consisting of aluminum sulfate, zinc sulfate, sodium sulfate, potassium sulfate, and calcium sulfate.