Low carbon emissions combined cycle power plant and process

• US 8,327,647 B2
• Filed: 08/02/2010
• Issued: 12/11/2012
• Est. Priority Date: 02/04/2008
• Status: Expired due to Fees

• Current Assignee: General Electric Technology GmbH (GE Aerospace)
• Original Assignee: Alstom Technology Ltd. (Alstom SA)
• Inventors: Guidati, Gianfranco, Pedretti, Camille
• Primary Examiner(s): Kim, Ted
• Application Number:
  US12/848,311
• Publication Number:
  US 20100319354A1
• Time in Patent Office: 862 Days
• Field of Search: 607/72, 607/73, 60/391.82, 60/395, 60/395.2
• US Class Current: 60/772
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: F01K 23/10 with exhaust fluid of one cycle heating the fluid in another cycle F01K17/025 takes precedence
• CPC Class Codes: F02C 3/34 with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
• CPC Class Codes: F05D 2230/50 Building or constructing in particular ways
• CPC Class Codes: F05D 2230/80 Repairing, retrofitting or upgrading methods
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/16 Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation

Abstract

A low carbon emissions, combined cycle power plant utilizes vortex nozzles (38) operative at cryogenic temperatures to separate out carbon dioxide (39) from the flue gases. Complexity of the plant is minimized by operating a gas turbine engine component (10) of the plant at a turbine exhaust pressure of at least 2 bar, so that downstream components of the plant, including a heat recovery steam generator (19A), a gas cooling system (30, 33, 36), and the inlets of the vortex nozzles, all operate at the same pressure of at least two bar. To increase carbon dioxide concentration in the flue gases (37) that pass through the vortex nozzles (38), and thereby increase efficiency of carbon dioxide removal from the flue gases, up to 50% of the flue gases that exit the heat recovery steam generator (19A) may be recirculated to a location (L, FIG. 4)) in the compressor of the gas turbine engine where the pressure of the compressor air matches the flue gas pressure.

Claims

1. A low carbon emissions combined cycle power plant comprising:

a gas turbine engine having a turbine exhaust duct, fuelled by carbon-containing fuel, and operable to exhaust carbon dioxide-containing flue gases from the turbine exhaust duct;

a heat recovery steam generator (HRSG) operable to raise steam by cooling flue gases received from the turbine exhaust duct;

a steam turbine operable to produce shaft power from steam received from the HRSG;

a heat exchanger arrangement operable to cool flue gases received from the HRSG down to a temperature approximating normal ambient temperature;

active cooling apparatus operable to further cool the flue gases down to a temperature range of about −

40°

C. to −

50°

C.; and

a plurality of vortex nozzles, each vortex nozzle having an inlet to receive flue gases from the active cooling apparatus and being operable to cryogenically separate out carbon dioxide from the received flue gases and to emit carbon-dioxide-depleted flue gases;

wherein the gas turbine engine exhaust duct, the HRSG, the heat exchanger arrangement, and the active cooling apparatus are configured and arranged to operate at a pressure sufficient to assure entry of flue gases to the vortex nozzles at a pressure of at least 2 bar.

2. A plant according to claim 1, further comprising:

a gas compressor operable to compress separated carbon dioxide received from the vortex nozzles and pump it into a pipeline for conveyance to storage; and

a discharge flue positioned to receive carbon-dioxide-depleted flue gases from the vortex nozzles and discharge the gases to atmosphere.

3. A plant according to claim 1, wherein the gas turbine engine exhaust duct, the HRSG, the heat exchanger arrangement, and the active cooling apparatus are configured and arranged to operate at a pressure which is sufficient to assure entry of flue gases to the vortex nozzles at a pressure of 2 to 4 bar.

4. A plant according to claim 1, wherein the gas turbine engine comprises a compressor (GT compressor), and further comprising:

a flow diverter positioned to recirculate a proportion of the flue gases that pass through the HRSG to a location in the GT compressor the pressure at which is substantially the same as the pressure of the recirculated gases.

5. A plant according to claim 4, wherein the flow diverter is configured and arranged to recirculate up to 50% of the gases that pass through the HRSG to the GT compressor.

6. A plant according to claim 4, further comprising:

means for cooling the flue gases to a temperature that is substantially the same as the GT compressor air temperature at the location in the compressor to which the gases are recirculated.

7. A plant according to claim 6, wherein the means for cooling comprises a gas cooler between the flow diverter and the GT compressor, configured and arranged to cool the diverted flue gases to the temperature for injection into the GT compressor.

8. A plant according to claim 6, wherein the HRSG is configured and arranged to cool the flue gases to the temperature for injection into the GT compressor.

9. A plant according to claim 8, wherein the flow diverter is configured and arranged to divert a proportion of the flue gases directly to the GT compressor before said gases have passed completely through the HRSG.

10. A plant according to claim 6, wherein:

the flow diverter is configured and arranged to divert a proportion of the flue gases to the GT compressor before said gases have passed completely through the HRSG; and

the means for cooling comprises a gas cooler between the flow diverter and the GT compressor, configured and arranged to cool the diverted flue gases to the temperature for injection into the GT compressor.

11. A plant according to claim 4, further comprising:

means for cooling the flue gases to a temperature that is substantially lower than the GT compressor air temperature at the location in the GT compressor to which the gases are recirculated.

12. A plant according to claim 11, wherein the means for cooling comprises a gas cooler between the flow diverter and the GT compressor, configured and arranged to cool the diverted flue gases to the temperature for injection into the GT compressor.

13. A plant according to claim 11, wherein the HRSG is configured and arranged to cool the flue gases to the temperature for injection into the GT compressor.

14. A plant according to claim 11, wherein:

the flow diverter is configured and arranged to divert a proportion of the flue gases to the GT compressor before said gases have passed completely through the HRSG; and

the means for cooling comprises a gas cooler between the flow diverter and the GT compressor configured and arranged to cool the diverted flue gases to the temperature for injection into the GT compressor.

15. A plant according to claim 1, wherein:

the gas turbine engine comprises at least one turbine stage less than a pre-existing engine having a plurality of turbine stages and operative with a pressure in the turbine exhaust duct of approximately 1 bar; and

the gas turbine engine is operative with a pressure in the turbine exhaust that is the required inlet pressure of the vortex nozzle plus the pressure losses of portions of the plant fluidly between the gas turbine engine and the vortex nozzles.

16. A process for obtaining low carbon emissions from a combined cycle power plant that includes a gas turbine engine fuelled by carbon-containing fuel and operable to exhaust carbon dioxide-containing flue gases of the gas turbine, a heat recovery steam generator (HRSG) operable to raise steam by cooling flue gases received from the turbine exhaust duct, a steam turbine operable to produce shaft power from steam received from the HRSG, a heat exchanger arrangement operable to cool flue gases received from the HRSG down to a temperature approximating normal ambient temperature, and active cooling apparatus operable to further cool the flue gases down to a temperature range of about −

40°

C. to −

50°

C., the process comprising;

first cooling gas turbine flue gases by using them in the HRSG to raise steam to drive the steam turbine to produce shaft power;

second further cooling said flue gases to a temperature about normal ambient temperature in the heat exchanger;

third further cooling said flue gases to a temperature range of about −

40°

C. to −

50°

C. in the active cooling apparatus; and

cryogenically separating carbon dioxide from the flue gases in a plurality of vortex nozzles and emitting carbon-dioxide-depleted flue gases;

wherein exhausting flue gases from the gas turbine engine and said third further cooling of the flue gases step occurs at a pressure which is sufficient to assure entry to the plurality of vortex nozzles at a pressure of at least 2 bar.

17. A process according to claim 16, further comprising:

compressing separated carbon dioxide for storage; and

in parallel with said compressing, discharging carbon-dioxide-depleted flue gases to atmosphere.

18. A process according to claim 16, wherein the inlet pressure to the vortex nozzle is in the range of 2 to 4 bar.

19. A process according to claim 16, wherein the gas turbine engine comprises a compressor (GT compressor), and further comprising:

diverting a proportion of the flue gases from said first cooling step before said proportion of flue gases is acted upon by said second cooling step; and

recirculating and injecting said proportion of flue gases into the GT compressor at a location in the GT compressor the pressure at which is substantially the same as the pressure of the recirculated flue gases.

20. A process according to claim 19, wherein diverting comprises diverting up to 50% of the gases from said first cooling step.

21. A process according to claim 19, further comprising:

subsequently cooling said recirculated flue gases to a temperature that is substantially the same as the GT compressor air temperature at the location in the GT compressor to which the gases are recirculated.

22. A process according to claim 21, wherein said first cooling step comprises cooling the flue gases to the temperature for recirculation to the GT compressor.

23. A process according to claim 21, wherein said first cooling step and said subsequently cooling said recirculated flue gases step cool the flue gases to the temperature for recirculation to the GT compressor.

24. A process according to claim 23, wherein said subsequently cooling step occurs before said diverting.

25. A process according to claim 23, wherein said subsequently cooling step occurs between said diverting and said injecting.

26. A process according to claim 25, wherein said diverting occurs part-way through said first cooling.

27. A process according to claim 19, further comprising:

subsequently cooling said recirculated flue gases to a temperature that is substantially lower than the GT compressor air temperature at the location in the GT compressor to which the gases are recirculated.

28. A process according to claim 27, wherein said first cooling step comprises cooling the flue gases to the temperature for recirculation to the GT compressor.

29. A process according to claim 27, wherein said first cooling step and said subsequently cooling said recirculated flue gases step cool the flue gases to the temperature for recirculation to the GT compressor.

30. A process according to claim 29, wherein said subsequently cooling step occurs before said diverting.

31. A process of operating a low-carbon-emissions combined cycle power plant, the plant having a gas turbine engine part fuelled by carbon-containing fuel and operable to exhaust carbon dioxide-containing flue gases of the gas turbine, a heat recovery steam generator (HRSG) operable to raise steam by cooling flue gases received from the turbine exhaust duct, a steam turbine operable to produce shaft power from steam received from the HRSG, a heat exchanger arrangement operable to cool flue gases received from the HRSG down to a temperature approximating normal ambient temperature, active cooling apparatus operable to further cool the flue gases down to a temperature range of about −

40°

C. to −

50°

C., a plurality of vortex nozzles to separate out carbon dioxide from flue gases at cryogenic temperatures, and parts of the plant fluidly connected between the gas turbine engine and the vortex nozzles, the process comprising;

operating said gas turbine engine part with a turbine exhaust pressure and pressure of said parts at a pressure which is sufficient to assure an inlet pressure to the plurality of vortex nozzles of at least 2 bar.