Carbonic anhydrase bioreactor and process for CO 2 containing gas effluent treatment

• US 8,329,458 B2
• Filed: 06/04/2010
• Issued: 12/11/2012
• Est. Priority Date: 07/13/2001
• Status: Expired due to Term

• Current Assignee: Saipem SPA (Saipem)
• Original Assignee: CO2 Solutions Inc.
• Inventors: Parent, Carmen, Dutil, Frédéric
• Primary Examiner(s): Bowers, Nathan
• Assistant Examiner(s): EDWARDS, LYDIA E
• Application Number:
  US12/802,353
• Publication Number:
  US 20100248323A1
• Time in Patent Office: 921 Days
• Field of Search: 4352831-3094
• US Class Current: 435/299.1
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/84 Biological processes
• CPC Class Codes: B01D 53/85 with gas-solid contact
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A triphasic bioreactor for physico-chemically treating a gas is disclosed. The triphasic bioreactor comprises a reaction chamber with a liquid and biocatalysts in suspension in the liquid, for catalyzing a reaction between the gas and the liquid to obtain a treated gas and a solution containing a reaction product. A gas bubbling means is provided in the reaction chamber for bubbling the gas to be treated into the liquid thereby dissolving the gas into the liquid and increasing a pressure inside the reaction chamber. The bioreactor further comprises a liquid inlet in fluid communication with the reaction chamber for receiving the liquid and filling the reaction chamber, a liquid outlet in fluid communication with the reaction chamber for releasing the solution and a gas outlet in fluid communication with the reaction chamber to release the treated gas. The bioreactor further comprises a retention device to retain the biocatalysts in the reaction chamber. The invention also concerns a process using the triphasic bioreactor. The triphasic bioreactor may advantageously be used for removing carbonic dioxide from a CO₂-containing gas.

Claims

1. A carbonic anhydrase bioreactor for treating a CO₂-containing gas, comprising:

a reaction chamber for receiving a liquid;

carbonic anhydrase provided on or in substrates that are in suspension within the liquid for catalyzing a reaction of CO₂ into bicarbonate and hydrogen ions to obtain a treated gas and an ion-rich solution, wherein the substrates comprise porous substrates and the carbonic anhydrase are entrapped in the porous substrates;

a liquid inlet in fluid communication with the reaction chamber for providing the reaction chamber with the liquid;

a gas inlet connected to the reaction chamber for providing the CO₂-containing gas to be treated into the reaction chamber in order to contact the liquid;

a liquid outlet in fluid communication with the reaction chamber for releasing the ion-rich solution; and

a gas outlet in fluid communication with the reaction chamber to release the treated gas.

2. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates are made of organic or inorganic material.

3. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates comprise particles composed of an insoluble gel.

4. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates comprise particles composed of silica.

5. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates comprise particles composed of alginate.

6. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates comprise particles composed of alginate/chitosan.

7. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates comprise particles composed of alginate/carboxymethylcellulose.

8. The carbonic anhydrase bioreactor according to claim 1, wherein the substrates are of 0.005 μ

m to 0.1 μ

m in size.

9. The carbonic anhydrase bioreactor according to claim 1, wherein the substrates are of 1 mm to 9 mm in diameter.

10. The carbonic anhydrase bioreactor according to claim 9, wherein the substrates are of 3 mm in diameter.

11. The carbonic anhydrase bioreactor according to claim 9, wherein the substrates are composed of alginate.

12. The carbonic anhydrase bioreactor according to claim 1, wherein the gas inlet comprises a gas bubbler for bubbling the CO₂-containing gas into the liquid.

13. The carbonic anhydrase bioreactor according to claim 12, comprising a pressure regulating valve to control a pressure created by the gas bubbled within the reaction chamber.

14. The carbonic anhydrase bioreactor according to claim 13, wherein the pressure regulating valve is located in the gas outlet.

15. The carbonic anhydrase bioreactor according to claim 1, further comprising a filter having pores with a smaller diameter than a diameter of the suspended substrates for separating the substrates from the ion-rich solution.

16. The carbonic anhydrase bioreactor according to claim 15, wherein the filter is constructed to enable ultrafiltration or microfiltration.

17. The carbonic anhydrase bioreactor according to claim 1, further comprising a retention device for retaining the substrates within the reaction chamber.

18. The carbonic anhydrase bioreactor according to claim 1, further comprising an additional reaction chamber in series with the reaction chamber, hereinafter referred to as the primary reaction chamber, and the additional reaction chamber is downstream from the primary reaction chamber for further treating the treated gas.

19. The carbonic anhydrase bioreactor according to claim 18, wherein the primary reaction chamber and the additional reaction chamber both receive suspended substrates with the carbonic anhydrase provided therein.

20. The carbonic anhydrase bioreactor according to claim 18, wherein the additional reaction chamber contains a biocatalyst different from the carbonic anhydrase of the primary reaction chamber.

21. The carbonic anhydrase bioreactor according to claim 1, wherein the substrates are of sub-micron size.

22. The carbonic anhydrase bioreactor according to claim 1, wherein a mixer is provided within the reaction chamber.

23. The carbonic anhydrase bioreactor according to claim 22, wherein the mixer is an axial propeller.

24. The carbonic anhydrase bioreactor according to claim 1, wherein the porous substrates comprise organic material, inorganic material, an insoluble gel, silica, alginate, alginate/chitosan or alginate/carboxymethylcellulose.

25. A process using carbonic anhydrase for treating a CO₂-containing gas, comprising:

suspending substrates within a liquid provided to a reaction chamber, carbonic anhydrase being provided on or in the substrates, wherein the substrates comprise porous substrates and the carbonic anhydrase are entrapped in the porous substrates;

contacting the CO₂-containing gas to be treated with the liquid within the reaction chamber in the presence of the carbonic anhydrase, to promote the chemical conversion of the dissolved CO₂ into an ion-rich solution containing hydrogen ions and bicarbonate ions and obtaining a treated gas;

releasing the ion-rich solution from the reaction chamber; and

releasing the treated gas from the reaction chamber.

26. The process according to claim 25, wherein the porous substrates are made of organic or inorganic material.

27. The process according to claim 25, wherein the porous substrates comprise particles composed of an insoluble gel.

28. The process according to claim 25, wherein the porous substrates comprise particles composed of silica.

29. The process according to claim 25, wherein the porous substrates comprise particles composed of alginate.

30. The process according to claim 25, wherein the porous substrates comprise particles composed of alginate/chitosan.

31. The process according to claim 25, wherein the porous substrates comprise particles composed of or alginate/carboxymethylcellulose.

32. The process according to claim 25, wherein the substrates are of 0.005 μ

m to 0.1 μ

m in size.

33. The process according to claim 25, wherein the substrates are of 1 mm to 9 mm in diameter.

34. The process according to claim 33, wherein the substrates are of 3 mm in diameter.

35. The process according to claim 33, wherein the substrates are composed of alginate.

36. The process according to claim 25, wherein the CO₂-containing gas is bubbled into the liquid.

37. The process according to claim 36, wherein the substrates are retained within the reaction chamber.

38. The process according to claim 37, comprising controlling the pressure within the reaction chamber.

39. The process according to claim 38, wherein the ion-rich solution is released by pressure.

40. The process according to claim 25, wherein the substrates are separated from the ion-rich solution.

41. The process according to claim 40, wherein the substrates are separated from the ion-rich solution by filtration.

42. The process according to claim 41, wherein the filtration is ultrafiltration or microfiltration.

43. The process according to claim 25, wherein the porous substrates comprise organic material, inorganic material, an insoluble gel, silica, alginate, alginate/chitosan or alginate/carboxymethylcellulose.