Titanium alloys including increased oxygen content and exhibiting improved mechanical properties

• US 8,337,750 B2
• Filed: 11/08/2005
• Issued: 12/25/2012
• Est. Priority Date: 09/13/2005
• Status: Active Grant

• Current Assignee: ATI Properties LLC (CNH Industrial N.V.)
• Original Assignee: ATI Properties Incorporated (Allegheny Technologies Incorporated)
• Inventors: Jablokov, Victor R., Freese, Howard L.
• Primary Examiner(s): Kastler, Scott
• Assistant Examiner(s): LUK, VANESSA TIBAY
• Application Number:
  US11/268,922
• Publication Number:
  US 20070193662A1
• Time in Patent Office: 2,604 Days
• Field of Search: 148/421, 420417-421
• US Class Current: 420/421
• CPC Class Codes: C22C 14/00 Alloys based on titanium

Abstract

One aspect of the present disclosure is directed to a metastable β titanium alloy comprising, in weight percentages: up to 0.05 nitrogen; up to 0.10 carbon; up to 0.015 hydrogen; up to 0.10 iron; greater than 0.20 oxygen; 14.00 to 16.00 molybdenum; titanium; and incidental impurities. Articles of manufacture including the alloy also are disclosed.

Claims

1. A metastable β

titanium alloy comprising, in weight percentages based on total alloy;

up to 0.05 nitrogen;

up to 0.10 carbon;

up to 0.015 hydrogen;

up to 0.10 iron;

0.25 oxygen up to 0.50 oxygen;

14.00 to 16.00 molybdenum;

at least 83.54 titanium; and

incidental impurities;

wherein the metastable β

titanium alloy further comprises a yield strength in a range of 128 ksi to 181 ksi and a modulus of elasticity in a range of 10.1 Mpsi to 10.5 Mpsi.

2. The metastable β

titanium alloy of claim 1, wherein, with the sole exception of oxygen content, the alloy has the composition of UNS R58150.

3. The metastable β

titanium alloy of claim 1, wherein, with the exception of oxygen content and the provisions of Section 9.1 under “

Special Requirements”

requiring a fully recrystallized beta phase structure, the alloy satisfies all of the requirements of ASTM F 2066-01 for wrought Ti-15Mo alloy suitable for use in the manufacture of surgical implants.

4. The metastable β

titanium alloy of claim 1, wherein the alloy exhibits at least one of yield strength and ultimate tensile strength that is greater than a second alloy processed in an identical manner and, with one exception, having an identical chemistry, wherein the one exception is that the second alloy includes no greater than 0.20 weight percent oxygen.

5. The metastable β

titanium alloy of claim 1, wherein the alloy has improved cyclic fatigue properties relative to a second alloy processed in an identical manner and, with one exception, having an identical chemistry, wherein the one exception is that the second alloy includes no greater than 0.20 weight percent oxygen.

6. The metastable β

titanium alloy of claim 1, having an ultimate tensile strength in a range of 148 ksi to 186 ksi.

19. An article of manufacture comprising a metastable β

titanium alloy having the composition recited in claim 1.

20. The article of manufacture of claim 19, wherein the article is one of an article of equipment, a part, and a component useful in at least one application selected from:

partial and total joint replacement procedures;

fracture fixation in trauma cases;

cardiovascular procedures;

restorative and reconstructive dental procedures; and

spinal fusion and spinal disc replacement procedures.

21. The article of manufacture of claim 20, wherein the metastable β

titanium alloy consists essentially of, in weight percentages;

up to 0.05 nitrogen;

up to 0.10 carbon;

up to 0.015 hydrogen;

up to 0.10 iron;

0.25 up to 0.50 oxygen;

14.00 to 16.00 molybdenum;

remainder titanium and incidental impurities;

wherein the metastable β

titanium alloy further comprises a yield strength in a range of 128 ksi to 181 ksi and a modulus of elasticity in a range of 10.1 Mpsi to 10.5 Mpsi.

22. The article of manufacture of claim 20, wherein the metastable β

titanium alloy consists of, in weight percentages;

up to 0.05 nitrogen;

up to 0.10 carbon;

up to 0.015 hydrogen;

up to 0.10 iron;

0.25 up to 0.5 oxygen;

14.00 to 16.00 molybdenum;

remainder titanium and incidental impurities;

wherein the metastable β

titanium alloy further comprises a yield strength in a range of 128 ksi to 181 ksi and a modulus of elasticity in a range of 10.1 Mpsi to 10.5 Mpsi.

23. The article of manufacture of claim 20, wherein the metastable β

titanium alloy has an ultimate tensile strength in a range of 148 ksi to 186 ksi.

24. The article of manufacture of claim 19, wherein the article is selected from the following biomedical components and parts:

a component for partial and total hip and knee replacement;

an intermedullary rod;

a fracture plate;

a spinal fixation replacement component; and

spinal disc replacement component;

a trauma screw;

a trauma plate;

a wire;

a cable;

a fastener;

a screw;

a nail;

an anchor;

a dental casting;

a dental implant;

an orthodontic arch wire;

an orthodontic anchor;

a heart valve ring;

a heart valve component;

profile and plate stocks;

a tool;

an instrument;

a fastener; and

an item of hardware.

25. The article of manufacture of claim 19, wherein the article is an article of equipment, a part, or a component useful in at least one application selected from:

aerospace applications;

automotive applications;

nuclear applications;

power generation applications;

jewelry; and

chemical processing applications.

26. The article of manufacture of claim 19, wherein the article is selected from the following components and parts:

automotive torsions bars;

aerospace fasteners;

corrosion-resistant thin sheet for military and commercial aircraft;

high performance racing and motorcycle springs; and

corrosion-resistant chemical processing tubing and fasteners.

7. A metastable β

titanium alloy consisting essentially of, in weight percentages;

up to 0.05 nitrogen;

up to 0.10 carbon;

up to 0.015 hydrogen;

up to 0.10 iron;

0.25 up to 0.50 oxygen;

14.00 to 16.00 molybdenum;

remainder titanium; and

incidental impurities;

wherein the metastable β

titanium alloy further comprises a yield strength in a range of 128 ksi to 181 ksi and a modulus of elasticity in a range of 10.1 Mpsi to 10.5 Mpsi.

8. The metastable β

titanium alloy of claim 7, wherein the titanium content of the alloy is at least 83.5.

9. The metastable β

titanium alloy of claim 7, wherein, with the sole exception of oxygen content, the alloy has the composition of UNS R58150.

10. The metastable β

titanium alloy of claim 7, wherein, with the exception of oxygen content and the provisions of Section 9.1 under “

Special Requirements”

requiring a fully recrystallized beta phase structure, the alloy satisfies all of the requirements of ASTM F 2066-01 for wrought Ti-15Mo alloy suitable for use in the manufacture of surgical implants.

11. The metastable β

titanium alloy of claim 7, wherein the alloy has at least one of yield strength and ultimate tensile strength that is greater than a second alloy processed in an identical manner and, with one exception, having an identical chemistry, wherein the one exception is that second alloy includes no greater than 0.20 weight percent oxygen based on the total weight of the second alloy.

12. The metastable β

titanium alloy of claim 7, wherein the alloy has improved cyclic fatigue properties relative to a second alloy processed in an identical manner and, with one exception, having an identical chemistry, wherein the one exception is that second alloy includes no greater than 0.20 weight percent oxygen based on the total weight of the second alloy.

13. The metastable β

titanium alloy of claim 7, having an ultimate tensile strength in a range of 148 ksi to 186 ksi.

14. A metastable β

titanium alloy consisting of, in weight percentages;

up to 0.05 nitrogen;

up to 0.10 carbon;

up to 0.015 hydrogen;

up to 0.10 iron;

0.25 up to 0.50 oxygen;

14.00 to 16.00 molybdenum;

remainder titanium and incidental impurities;

wherein the metastable β

titanium alloy further comprises a yield strength in a range of 128 ksi to 181 ksi and a modulus of elasticity in a range of 10.1 Mpsi to 10.5 Mpsi.

15. The metastable β

titanium alloy of claim 14, wherein, with the sole exception of oxygen content, the alloy has the composition of UNS R58150.

16. The metastable β

titanium alloy of claim 14, wherein the alloy has at least one of yield strength and ultimate tensile strength that is greater than a second alloy processed in an identical manner and, with one exception, having an identical chemistry, wherein the one exception is that the second alloy includes no greater than 0.20 weight percent oxygen.

17. The metastable β

titanium alloy of claim 14, wherein the alloy has improved cyclic fatigue properties relative to a second alloy processed in an identical manner and, with one exception, having an identical chemistry, wherein the one exception is that the second alloy includes no greater than 0.20 weight percent oxygen.

18. The metastable β

titanium alloy of claim 14, having an ultimate tensile strength in a range of 148 ksi to 186 ksi.