Separating olefin streams

• US 8,338,656 B2
• Filed: 10/01/2007
• Issued: 12/25/2012
• Est. Priority Date: 10/01/2007
• Status: Active Grant

• Current Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation), Lummus Technology Inc.
• Inventors: Lumgair, David Ritchie, Nicoletti, Michael Peter, Mallik, Ram, Malaty, Wadie, Pettigrew, Malcolm
• Primary Examiner(s): Nguyen, Tam M
• Application Number:
  US12/681,336
• Publication Number:
  US 20100292521A1
• Time in Patent Office: 1,912 Days
• Field of Search: None
• US Class Current: 585/809
• CPC Class Codes: C07C 1/20 starting from organic compounds containing only oxygen atoms as heteroatoms
• CPC Class Codes: C07C 11/02 Alkenes
• CPC Class Codes: C07C 2529/83 Aluminophosphates (APO compounds)
• CPC Class Codes: C07C 2529/85 Silicoaluminophosphates (SAPO compounds)
• CPC Class Codes: C07C 7/005 Processes comprising at least two steps in series
• CPC Class Codes: C07C 7/09 by fractional condensation

Abstract

This invention pertains to separating an olefin stream into at least two olefin streams. The olefin stream that is to be separated is low in diene composition, which allows the olefin stream to be compressed at a relatively high temperature without causing fouling problems in the compressor system. The invention is particularly relevant to separating olefins obtained from an oxygen to olefins unit.

Claims

1. A process for making and separating an olefin stream comprising a mixture of olefins into at least two olefin streams, the process comprising the steps of:

(a) providing an olefin stream to be separated comprising at least about 20 wt % of an olefin selected from the group consisting of ethylene, propylene and combinations thereof and not greater than about 3.0 wt % dienes based on the total weight of the olefin stream;

(b) compressing the olefin stream in a compressor system having a first stage and a second stage to obtain a compressed olefin stream; and

(c) separating the compressed olefin stream into at least two olefin streams,

wherein the olefin stream being compressed in step b) is treated between the first stage and the second stage to remove acid gases prior to separating the compressed olefin stream into at least two olefin streams.

2. The process of claim 1, wherein the olefin stream to be separated comprises from at least about 50 wt % to about 90% ethylene and propylene based on the total weight of the olefin stream.

3. The process of claim 1, wherein the olefin stream exits the first stage of the compressor at a pressure of from about 75 psia (517 kPa) to about 150 psia (1,034 kPa), and exits the second stage of the compressor system at a pressure of at least about 175 psia (1,207 kPa), and the compressed olefin stream exits the compressor system at a temperature of from about 220°

F. (104°

C.) to no greater than about 260°

F. (127°

C.).

4. The process of claim 3, wherein the olefin stream to be separated is produced by the step of contacting an oxygenate with a molecular sieve catalyst comprising a silicoaluminophosphate or an aluminophosphate.

5. The process of claim 1, wherein the at least two olefin streams include (i) a light olefin stream comprising at least one olefin selected from the group consisting of ethylene, propylene and butylenes, and (ii) a heavy olefin stream comprising olefins that have boiling points that are, on average, higher than those in the light olefin stream.

7. The process of claim 1, wherein the treated olefin stream is further washed with water prior to separating into the at least two olefin streams.

6. A process for making and separating an olefin stream comprising a mixture of olefins into at least two olefin streams, the process comprising the steps of:

a) providing an olefin stream to be separated comprising at least about 20 wt % of an olefin selected from the group consisting of ethylene, propylene and combinations thereof and not greater than about 3.0 wt % dienes based on the total weight of the olefin stream;

b) compressing the olefin stream in a compressor system having a first stage and a second stage to obtain a compressed olefin stream, wherein the compressed olefin stream exits the first stage and the second stage a temperature of not greater than about 260°

F. (127°

C.) and exits the second stage a pressure of at least about 175 psia (1,207 kPa); and

c) separating the compressed olefin stream into at least two olefin streams, wherein the olefin stream being compressed in step b) is treated between the first stage and the second stage to remove acid gases prior to separating the compressed olefin stream into at least two olefin streams.

8. The process of claim 6, wherein the process further comprises drying the compressed olefin stream formed in step b), prior to the separating in step c).

9. The process of claim 8, wherein the compressed olefin stream is contacted with an adsorbent to dry the compressed olefin stream.

10. The process of claim 6, wherein the at least two olefin streams include (i) a light olefin stream comprising at least one olefin selected from the group consisting of ethylene, propylene and butylenes, and (ii) a heavy olefin stream comprising olefins that have boiling points that are, on average, higher than those in the light olefin stream.

11. A process for making and separating an olefin stream comprising a mixture of olefins into at least two olefin streams, the process comprising the steps of:

a) contacting an oxygenate with a molecular sieve catalyst to produce an olefin stream to be separated comprising at least about 20 wt % of an olefin selected from the group consisting of ethylene, propylene and combinations thereof and not greater than about 3.0 wt % diener based on the total weight of the olefin stream;

b) compressing the olefin stream in a compressor system having a first stage and a second stage to obtain a compressed olefin stream, wherein the compressed olefin stream exits the compressor system at a temperature of not greater than about 260°

F. (127°

C.) and exits the second stage a pressure of at least about 175 psia (1,207 kPa); and

c) separating the compressed olefin stream into at least two olefin streams,

wherein the olefin stream being compressed in step b) is treated between the first stage and the second stage to remove acid gases prior to separating the compressed olefin stream into at least two olefin streams.

12. The process of claim 11, wherein the compressed olefin stream exits the first stage of the compressor at a pressure of from about 75 psia (517 kPa) to about 150 psia (1,034 kPa).

13. The process of claim 11, wherein the olefin stream to be separated comprises from at least about 50 wt % to about 90% ethylene and propylene based on the total weight of the olefin.

14. The process of claim 11, wherein the treated olefin stream is further washed with water prior to separating into the at least two olefin streams.

15. The process of claim 11, wherein the process further comprises drying the compressed olefin stream formed in step b), prior to the separating in step c).

16. The process of claim 11, wherein the at least two olefin streams include (i) a light olefin stream comprising at least one olefin selected from the group consisting of ethylene, propylene and butylenes, and (ii) a heavy olefin stream comprising olefins that have boiling points that are, on average, higher than those in the light olefin stream.

17. The process of claim 11, wherein the molecular sieve catalyst is a silicoaluminophosphate or an alum inophosphate.

18. A process for making and separating an olefin stream comprising a mixture of olefins into at least two olefin streams, the process comprising the steps of:

a) providing an olefin stream to be separated comprising not greater than about 3.0 wt % dienes based on the total weight of the olefin stream;

b) compressing the olefin stream in a compressor system having a first stage and a second stage to obtain a compressed olefin stream; and

c) separating the compressed olefin stream into at least two olefin streams,

wherein the olefin stream being compressed in step b) is treated between the first stage and the second stage to remove acid gases prior to separating the compressed olefin stream into at least two olefin streams.

19. The process of claim 18, wherein the olefin stream exits the first stage of the compressor at a pressure of from about 75 psia (517 kPa) to about 150 psia (1,034 kPa), and exits the second stage of the compressor system at a pressure of at least about 175 psia (1,207 kPa), and the compressed olefin stream exits the compressor system at a temperature of from about 220°

F. (104°

C.) to no greater than about 260°

F. (127°

C.).

20. The process of claim 18, wherein the treated olefin stream is further washed with water prior to separating into the at least two olefin streams.

21. The process of claim 18, wherein the process further comprises drying the compressed olefin stream formed in step b), prior to the separating in step c).

22. The process of claim 18, wherein the at least two olefin streams include (i) a light olefin stream comprising at least one olefin selected from the group consisting of ethylene, propylene and butylenes, and (ii) a heavy olefin stream comprising olefins that have boiling points that are, on average, higher than those in the light olefin stream.