Method and system for corn fractionation

• US 8,344,107 B2
• Filed: 07/14/2009
• Issued: 01/01/2013
• Est. Priority Date: 01/06/2005
• Status: Expired due to Fees

• Current Assignee: Board of Trustees of The University of Illinois
• Original Assignee: Board of Trustees of The University of Illinois
• Inventors: Cheryan, Munir
• Primary Examiner(s): TSAY, MARSHA M
• Application Number:
  US12/502,862
• Publication Number:
  US 20100010197A1
• Time in Patent Office: 1,267 Days
• Field of Search: None
• US Class Current: 530/376
• CPC Class Codes: A23K 20/147 Polymeric derivatives, e.g. peptides or proteins
• CPC Class Codes: A23L 7/115 Cereal fibre products, e.g. bran, husk
• CPC Class Codes: C08B 30/044 from corn or maize
• CPC Class Codes: C11B 1/10 by extracting
• CPC Class Codes: C11B 1/108 after-treatment, e.g. of miscellae

Abstract

Methods and apparatus for processing corn into one or more corn products. Oil is extracted from corn or corn products or by-products with a solvent. The corn-solvent mixture is separated into streams, one of which preferably includes an extract containing at least oil and solvent, and another containing de-oiled corn solids and adsorbed solvent. Zein is separated from the de-oiled corn solids. Solvent is then separated, and the de-oiled, de-zeined, desolventized corn solids are processed to provide one or more corn products.

Claims

1. A process for fractionation of corn, the process comprising the steps of:

preparing the corn for extraction to obtain prepared corn that has not been steeped and has not been de-germed;

extracting the oil from the prepared corn that has not been steeped and has not been de-germed with a first solvent to provide an extracted corn-solvent mixture, wherein the first solvent comprises at least one of a hydrocarbon, an alcohol and a combination of at least one of an alcohol with water;

separating the extracted corn-solvent mixture into at least a stream including an extract comprising the oil and first solvent, and another stream comprising de-oiled corn solids and adsorbed first solvent;

separating the first solvent from the oil in the extract by membrane processing the extract;

extracting zein from the de-oiled corn solids with a second solvent to provide a de-oiled corn solids-second solvent mixture;

separating the de-oiled corn solids-second solvent mixture into at least a stream comprising a second extract including the zein and second solvent, and another stream comprising de-oiled, de-zeined corn solids and adsorbed second solvent;

separating zein from the second solvent by membrane processing the second extract;

desolventizing the de-oiled, de-zeined corn solids to remove the adsorbed second solvent;

resuspending said desolventized, de-oiled, de-zeined corn solids in water; and

separating one or more of the fiber, starch, and protein from the resuspended desolventized, de-oiled, de-zeined corn solids to produce one or more corn products.

2. The process of claim 1 wherein said preparing the corn for extraction comprises at least one of dry-grinding the corn and flaking the corn.

3. The process of claim 1 wherein said extracting using the first solvent comprises at least one of batch and continuous extracting.

4. The process of claim 1 wherein said separating the extracted corn-solvent mixture uses at least one of centrifugation, filtration, and membrane filtration.

5. The process of claim 1 wherein said separating the first solvent from the oil comprises at least one of nanofiltration and ultrafiltration.

6. The process of claim 1 wherein said desolventizing the de-oiled corn solids uses at least one of vacuum, heat, steam, air and gas.

7. The process of claim 1 wherein the de-oiled corn solids are desolventized before said extracting with a second solvent.

8. The process of claim 1 wherein the first solvent and the second solvent each comprise at least one of a hydrocarbon, an alcohol, an ethanol, and a solution of at least one of a hydrocarbon, an alcohol, an ethanol, and water.

9. The process of claim 1 wherein said separating the extracted corn-solvent mixture and said separating the de-oiled corn solids-second solvent mixture each comprise at least one of centrifugation, filtration, and membrane filtration.

10. The process of claim 1 wherein the extract comprising the oil and solvent is pretreated with an ultrafiltration membrane, and further comprising:

nanofiltering a permeate from the ultrafiltration membrane to recover oil and solvent.

11. The process of claim 1 wherein said separating one or more of the fiber, starch, and protein comprises separating fiber;

and

wherein the process further comprises washing the separated fiber.

12. The process of claim 11 further comprising:

dewatering and drying the separated and washed fiber.

13. The process of claim 12 wherein the wash water from said fiber dewatering is membrane filtered to recover protein and starch.

14. The process of claim 11 wherein the de-oiled, de-zeined, desolventized corn solids after said fiber separating comprise a suspension including substantially starch and protein in water;

and

wherein the process further comprises dewatering and thickening the suspension by at least one of a centrifuge, a membrane microfilter, and a membrane ultrafilter.

15. The process of claim 14 wherein the suspension is separated into crude starch and protein fractions.

16. The process of claim 15 further comprising:

washing and purifying the crude starch using water.

17. The process of claim 16 wherein said washing and purifying uses at least one of a hydrocyclone and a membrane microfilter.

18. The process of claim 17, further comprising:

passing the wash water from said starch purifying through at least one of a membrane, a reverse osmosis membrane, a nanofiltration membrane, an ultrafiltration membrane and a microfiltration membrane, to recover a clean water permeate and concentrated solids.

19. The process of claim 18 wherein the clean water permeate from said passing through the membrane is recycled to upstream operations.

20. The process of claim 19 further comprising:

recycling retained solids from said passing through the membrane to upstream operations to recover the solids.

21. The process of claim 20, further comprising:

thickening the separated protein fraction in a gluten thickener, wherein the gluten thickener includes at least one of a centrifuge, a membrane microfilter, and an ultrafilter designed to retain substantially all proteins and starch.

22. The process of claim 21 wherein said thickening uses a centrifuge, and wherein the overflow from the centrifuge is sent to at least one of a membrane microfilter, an ultrafilter, and a nanofilter to recover substantially all the protein.

23. The process of claim 22 wherein said thickening uses a gluten filter;

and

wherein the process further comprises membrane processing a filtrate from the gluten filter using at least one of reverse osmosis, nanofiltration, ultrafiltration, and microfiltration to recover protein.

24. A process for fractionation of corn, the process comprising the steps of:

preparing the corn for extraction to obtain prepared corn that has not been steeped and has not been de-germed;

extracting the oil from the prepared corn that has not been steeped and has not been de-germed with a first solvent to provide an extracted corn-solvent mixture, wherein the first solvent comprises at least one of a hydrocarbon, an alcohol and a combination of at least one of an alcohol with water;

separating the extracted corn-solvent mixture into at least a stream including an extract comprising the oil and first solvent, and another stream comprising de-oiled corn solids and adsorbed first solvent;

extracting zein from the de-oiled corn solids with a second solvent to provide a de-oiled corn solids-second solvent mixture;

separating the de-oiled corn solids-second solvent mixture into at least a stream comprising a second extract including the zein and second solvent, and another stream comprising de-oiled, de-zeined corn solids and adsorbed second solvent;

separating the second solvent from zein by membrane processing the second extract;

desolventizing the de-oiled, de-zeined corn solids to remove the adsorbed second solvent;

resuspending said desolventized, de-oiled, de-zeined corn solids in water; and

separating one or more of the fiber, starch, and protein from the resuspended desolventized, de-oiled, de-zeined corn solids to produce one or more corn products.