Integrated process for production of alcohol from syngas and removal of CO 2
First Claim
1. A process for the production of alcohol from a feed gas comprising CO2 and at least one of hydrogen and CO, the process comprising:
- a) contacting a feed gas comprising CO2 and at least one of hydrogen and CO with a first aqueous alcohol stream to absorb CO2 from the feed gas to produce a contacted stream and separating the contacted stream into a CO2 reduced feed gas and a CO2 enriched liquid stream;
b) passing the CO2 reduced feed gas to a bioreactor for contact therein with microorganisms that convert at least a portion of the hydrogen and CO2, or CO to a bioreactor effluent stream comprising alcohol;
c) separating the CO2 enriched liquid stream into a gaseous effluent stream comprising CO2 and the alcohol and a second aqueous alcohol stream;
d) returning at least a portion of the second aqueous alcohol stream to the first aqueous alcohol stream for contact with the feed gas in step a);
e) recovering alcohol from the bioreactor effluent stream from step b);
f) introducing a portion of the alcohol from the bioreactor effluent stream of step b) into the first aqueous alcohol stream of step a); and
,g) condensing the gaseous effluent stream from step c) to produce a CO2 off gas stream and an alcohol enriched stream.
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Accused Products
Abstract
A process for producing alcohol from syngas integrates the alcohol recovery with the removal of CO2 from syngas. A syngas feed containing CO, H2, and CO2 contacts an aqueous alcohol stream to remove CO2 from the syngas that then passes to bioreactor containing microorganisms for conversion to alcohol and other liquid products. Flashing of the scrubbing liquid releases the CO2 and simultaneously concentrates alcohol in the overhead flash vapor. Condensation of the flash vapor provides an enriched alcohol stream for enhanced recovery of the ethanol product in a product separation zone. The remainder of the scrubbing liquid along with make-up alcohol and water from the process gets returned for continued contact with the syngas feed.
27 Citations
22 Claims
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1. A process for the production of alcohol from a feed gas comprising CO2 and at least one of hydrogen and CO, the process comprising:
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a) contacting a feed gas comprising CO2 and at least one of hydrogen and CO with a first aqueous alcohol stream to absorb CO2 from the feed gas to produce a contacted stream and separating the contacted stream into a CO2 reduced feed gas and a CO2 enriched liquid stream; b) passing the CO2 reduced feed gas to a bioreactor for contact therein with microorganisms that convert at least a portion of the hydrogen and CO2, or CO to a bioreactor effluent stream comprising alcohol; c) separating the CO2 enriched liquid stream into a gaseous effluent stream comprising CO2 and the alcohol and a second aqueous alcohol stream; d) returning at least a portion of the second aqueous alcohol stream to the first aqueous alcohol stream for contact with the feed gas in step a); e) recovering alcohol from the bioreactor effluent stream from step b); f) introducing a portion of the alcohol from the bioreactor effluent stream of step b) into the first aqueous alcohol stream of step a); and
,g) condensing the gaseous effluent stream from step c) to produce a CO2 off gas stream and an alcohol enriched stream. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11)
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12. A process for the production of ethanol from a feed gas comprising CO2 and at least one of hydrogen and CO, the process comprising:
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a) contacting a feed gas comprising CO2 and at least one of hydrogen and CO with a first aqueous ethanol stream to absorb CO2 from the feed gas to produce a contacted stream and separating the contacted stream into a CO2 reduced feed gas and a CO2 enriched liquid stream; b) passing the CO2 reduced feed gas to a bioreactor for contact therein with microorganisms that convert at least a portion of the hydrogen and CO2, or CO to a bioreactor effluent stream comprising ethanol; c) separating the CO2 enriched liquid stream into a CO2 effluent stream and a second aqueous ethanol stream; d) recovering ethanol from the CO2 effluent stream from step c) to produce a CO2 off-gas stream and an ethanol enriched stream; and
,e) adding a portion of the bioreactor effluent stream from step b) to the first aqueous ethanol stream to supply make-up ethanol for contact with the feed gas of step a). - View Dependent Claims (13, 14, 15, 16, 17)
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18. A process for the production of ethanol from a feed gas comprising CO2, H2, CO, COS and H2S, the process comprising:
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a) passing the feed gas to a contactor; b) passing a first aqueous ethanol stream to the contactor; c) absorbing CO2, COS and H2S from the feed gas in the contactor to produce a CO2 reduced feed gas having a reduced concentration of CO2, H2S and COS relative to the feed gas and a CO2 enriched stream containing CO2, COS and H2S; d) passing the CO2 reduced feed gas to a bioreactor for contact therein with microorganisms that convert at least a portion of the hydrogen and CO2, or CO to a bioreactor effluent stream comprising ethanol; e) separating ethanol from the CO2 enriched stream from step c) in a separator to produce a CO2 effluent stream comprising ethanol and CO2 and a second aqueous ethanol stream; f) condensing ethanol from the CO2 effluent stream from step e) to produce an ethanol enriched stream and a CO2 off gas stream containing CO2, COS and H2S; g) passing at least a portion of the bioreactor effluent stream from step d) and the ethanol enriched stream from step f) to an ethanol recovery zone to produce an ethanol effluent stream having an ethanol concentration of at least 90 wt %; h) passing at least a portion of the second aqueous ethanol stream from step e) to the contactor to supply a portion of the first aqueous ethanol stream to step b); i) passing make-up ethanol to the contactor to supply a portion of the first aqueous ethanol stream; and j) recovering an ethanol product stream from the ethanol recovery zone from step g). - View Dependent Claims (19, 20, 21, 22)
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Specification