System and method of introducing an additive with a unique catalyst to a coking process

• US 8,361,310 B2
• Filed: 02/17/2009
• Issued: 01/29/2013
• Est. Priority Date: 11/17/2006
• Status: Expired due to Fees

• Current Assignee: Augusto Quinones, Roger G. Etter
• Original Assignee: Augusto Quinones, Roger G. Etter
• Inventors: Etter, Roger G., Quinones, Augusto
• Primary Examiner(s): MCCAIG, BRIAN A
• Application Number:
  US12/372,586
• Publication Number:
  US 20090209799A1
• Time in Patent Office: 1,442 Days
• Field of Search: 208/50, 208/52.R, 208 53- 55, 208/131, 208/52.CT, 208 67- 77
• US Class Current: 208/52.R
• CPC Class Codes: B01J 29/06 Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
• CPC Class Codes: B01J 29/084 Y-type faujasite
• CPC Class Codes: C07C 11/02 Alkenes
• CPC Class Codes: C07C 4/06 Catalytic processes C07C4/025 takes precedence
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10B 55/10 according to the "fluidised bed" technique
• CPC Class Codes: C10B 57/06 containing additives
• CPC Class Codes: C10B 57/12 Applying additives during coking
• CPC Class Codes: C10G 2400/10 Lubricating oil
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10G 2400/22 Higher olefins

Abstract

Gas oil components, coking process recycle, and heavier hydrocarbons are cracked or coked in the coking vessel by injecting an additive into the vapors of traditional coking processes in the coking vessel. The additive contains catalyst(s), seeding agent(s), excess reactant(s), quenching agent(s), carrier(s), or any combination thereof to modify reaction kinetics to preferentially crack or coke these components. Modifications of the catalysts in the additive improve performance for certain desired outcomes. One exemplary embodiment of the present invention uses the olefin production capabilities from newly developed catalysts to increase the production of light olefins (e.g. ethylene, propylenes, butylenes, pentenes) for alkylation process unit feed, the production of oxygenates, and petrochemical feedstocks, such as plastics manufacture. Another exemplary embodiment of the present invention is the use of the olefin production from newly developed catalysts to improve the coker naphtha quality. A third exemplary embodiment of the present invention uses the cracking characteristics of newly developed catalysts to optimize the production of light gas oils, naphtha, and gases from the coking process.

Claims

1. A process comprising introducing an additive including cracking catalyst into a coking vessel during a coking cycle of a delayed coking process such that reactions are enhanced to further increase a production of olefins in said coking process.

2. A process of claim 1 wherein said additive is added to the vapors above a coking vapor-liquid interface in said coking vessel.

3. A process of claim 1 wherein said additive is added to said coking process by a means of pressurized injection.

4. A process of claim 1 wherein said additive comprises said cracking catalyst(s), alone or in combination with seeding agent(s), excess reactant(s), quenching agent(s), carrier fluid(s), or any combination thereof.

5. A process of claim 1 wherein said cracking catalyst substantially increases a proportion of an olefin in gases separated from said coking process.

6. A process of claim 1, wherein said olefins are selected from a group comprising ethylene, propylene, butylenes, pentenes, and any combination thereof.

7. A process of claim 1 wherein said cracking substantially increases a proportion of olefins in a naphtha boiling point range.

8. A process of claim 7 wherein said olefins have boiling points in the range between 180 and 400 degrees Fahrenheit.

9. A process of claim 1 wherein said cracking catalyst is developed to optimize the production of heavy coker gas oil, light coker gas oil, naphtha, and gases.