Solid-layered bleach compositions and methods of use

• US 8,361,945 B2
• Filed: 11/10/2010
• Issued: 01/29/2013
• Est. Priority Date: 12/09/2008
• Status: Active Grant

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Smith, William L., Rumberger, Evan
• Primary Examiner(s): ANTHONY, JOSEPH DAVID
• Application Number:
  US12/943,185
• Publication Number:
  US 20110059882A1
• Time in Patent Office: 811 Days
• Field of Search: 252/187.27, 252/187.28, 252/187.29, 252/187.3, 252/186.37, 510/116, 510/117, 510/298, 510/302, 510/349, 510/380, 510/446, 422/28, 422/29
• US Class Current: 510/116
• CPC Class Codes: A61K 2800/88 Two- or multipart kits
• CPC Class Codes: A61K 8/19 containing inorganic ingredients
• CPC Class Codes: A61K 8/20 Halogens; Compounds thereof
• CPC Class Codes: A61K 8/36 Carboxylic acids; Salts or anhydrides thereof
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/466 containing sulfonic acid derivatives; Salts
• CPC Class Codes: A61K 8/8147 Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8152 Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8176 Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8188 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bonds, and at least one being terminated by a bond to sulfur or by a hertocyclic ring containing sulfur; Compositions of derivatives of such polymers
• CPC Class Codes: A61Q 11/02 Preparations for deodorising, bleaching or disinfecting dentures
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 17/0078 Multilayered tablets
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/2075 Carboxylic acids-salts thereof
• CPC Class Codes: C11D 3/2079 Monocarboxylic acids-salts thereof
• CPC Class Codes: C11D 3/2082 Polycarboxylic acids-salts thereof
• CPC Class Codes: C11D 3/33 Amino carboxylic acids
• CPC Class Codes: C11D 3/3454 containing sulfone groups, e.g. vinyl sulfones
• CPC Class Codes: C11D 3/349 : additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
• CPC Class Codes: C11D 3/361 : Phosphonates, phosphinates or phosphonites
• CPC Class Codes: C11D 3/3761 : in solid compositions
• CPC Class Codes: C11D 3/3776 : Heterocyclic compounds, e.g. lactam
• CPC Class Codes: C11D 3/378 : (Co)polymerised monomers containing sulfur, e.g. sulfonate
• CPC Class Codes: C11D 3/3953 : Inorganic bleaching agents C11D3/3951 takes precedence

Abstract

The present invention provides a method for cleaning dentures by contacting the dentures with a solid, multi-layered composition having at least two parts in water. The first part of the composition comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.

Claims

1. A method for cleaning dentures, said method comprising:

contacting said dentures with a solid, multi-layered composition in water, wherein said composition comprises at least a first part and a second part;

wherein said first part comprising,

a) 0.001%-50% by weight of a hypochlorite selected from the group consisting of calcium hypochlorite, magnesium hypochlorite and mixtures thereof;

b) a builder selected from the group consisting of carbonate, bicarbonate, sesquicarbonate and mixtures thereof;

c) a water-soluble polymer selected from the group consisting of a polycarboxylate, sulfonated carboxylate, polysulfonate, polyvinylpyrrolidone, polyquaternary ammonium salts, copolymers and mixtures thereof;

d) at least 30% by weight of an acid selected from the group consisting of sulfonic acid, polysulfonic acid, carboxylic acid, dicarboxylic acid, polycarboxylic acid, acid sulfate, acid phosphate, phosphonic acid, and mixtures thereof;

e) optionally, a filler selected from group consisting of chloride, sulfate, phosphate, silicate, borate, nitrate, chlorate, aluminate, silica-aluminate, hydroxide, and oxide compounds of alkali metals, alkaline earths, aluminum, zinc and tin including hydrates, mono, di and tribasic compounds, mixed salts, borates, clays, zeolites and mixtures thereof;

f) optionally, a water-swellable polymer wherein said water-swellable polymer is selected from the group consisting of cross-linked polycarboxylate, cross-linked polysulfonate, cross-linked carboxymethyl cellulose, cellulose, sodium carboxymethylcelluose, and mixtures thereof;

g) optionally, desiccants, solid processing aids, colorants, agglomeration aids, binders, glidants, corrosion inhibitors, and mixtures thereof; and

h) wherein said first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite, sodium chlorite, chlorine dioxide, N-halogenated compounds, hydantoins, isocyanurates, carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups, enzymes; and

wherein said second part comprising,

a) a functional ingredient selected from the group consisting of surfactant, a hydrotrope, a wetting agent, a dispersant, a penetrant, a chelating agent, an odor absorbent, a fragrance, a flavoring agent, a sweetener, a colorant, a corrosion inhibitor, a viscosity modifier, a foam booster, a defoamer, a stain and soil repellant, a fluorescent whitening agent, an enzyme, a cloud point modifier, an anti-microbial agent, a sporulation agent, a catalyst, an activating agent, a therapeutic agent, and mixtures thereof;

b) a builder or filler selected from the group consisting of carbonate, bicarbonate, sesquicarbonate, chloride, sulfate, phosphate, silicate, borate, nitrate, aluminate, silica-aluminate, hydroxide, or oxide compound of alkali metals, alkaline earths, aluminum, zinc and tin including hydrates, mono, di and tribasic compounds, mixed salts, borates, clays, zeolites, and mixtures thereof;

c) optionally acids, water soluble polymers, disintegrants, desiccants, solid processing aids, agglomeration aids, binders, glidants, preservatives, corrosion inhibitors, and mixtures thereof; and

d) wherein said second part does not contain any oxidant wherein said oxidant comprises hypochlorite, chlorite, chlorate, perchlorate, N-halo compound, chlorine dioxide, peracid, peroxide, peroxygen bleach and mixtures thereof.

2. The method of claim 1, wherein after the contacting step, the pH of the dissolved composition is between about 5 and about 8.

3. The method of claim 1, wherein none of the ingredients of the composition are coated, encapsulated or embedded in a polymer, resin, or a wax.

4. The method of claim 1, wherein the second part of the composition comprises a builder selected from carbonate, bicarbonate, sesquicarbonate and mixtures thereof and the second part of the composition comprises an acid selected from the group consisting of sulfonic acid, a carboxylic acid, a dicarboxylic acid, acid sulfate, an acid phosphate, a phosphonic acid, and mixtures thereof.

5. The method of claim 1, wherein the functional ingredient of the second part of the composition contains both the surfactant and the hydrotrope.

6. The method of claim 5, wherein the surfactant is an anionic surfactant and the hydrotrope is a salt selected from the group consisting of toluene sulfonate, cumene sulfonate, xylene sulfonate, naphthalene sulfonate, methyl naphthalene sulfonate, C4-C10 alkane sulfonates, and C6-C10 carboxylates, and mixtures thereof.

7. The method of claim 1, wherein the acid in the first part is the dicarboxylic acid.

8. The method of claim 1, wherein the water-soluble polymer in the first part is the polycarboxylate, and the polycarboxylate is selected from the group consisting of maleic acid, acrylic acid, methacrylic acid and mixtures thereof.

9. The method of claim 1, wherein the composition requires a third part wherein said third part is situated between the first part and second part and said third part comprises a component selected from the group consisting of binder, filler, colorant, desiccant, solid processing aids, sodium chloride, sodium silicate, sodium sulfate, magnesium sulfate, magnesium carbonate, calcium carbonate, calcium hydroxide, calcium oxide, magnesium oxide, magnesium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, sodium sesquicarbonate, potassium sesquicarbonate, sodium borate, boric acid, aluminum hydroxide, silica and mixtures thereof.

10. A method for cleaning dentures, said method comprises:

contacting said dentures with a solid, multi-layered composition in water, wherein said composition comprises at least a first part and a second part;

wherein said first part consisting essentially of,

a) 0.001%-50% by weight of a hypochlorite selected calcium hypochlorite, magnesium hypochlorite and mixtures thereof;

b) a builder selected from the group consisting of carbonate, bicarbonate, sesquicarbonate and mixtures thereof;

c) a water-soluble polymer selected from the group consisting of a polycarboxylate, sulfonated carboxylate, polysulfonate, polyvinylpyrrolidone, polyquaternary ammonium salts, copolymers and mixtures thereof;

d) at least 30% by weight of an acid selected from the group consisting of sulfonic acid, polysulfonic acid, carboxylic acid, dicarboxylic acid, polycarboxylic acid, acid sulfate, acid phosphate, phosphonic acid, and mixtures thereof;

e) optionally, a filler selected from group consisting of chloride, sulfate, phosphate, silicate, borate, nitrate, chlorate, aluminate, silica-aluminate, hydroxide, and oxide compounds of alkali metals, alkaline earths, aluminum, zinc and tin including hydrates, mono, di and tribasic compounds, mixed salts, borates, clays, zeolites and mixtures thereof;

f) optionally, a water-swellable polymer selected from the group consisting of cross-linked polycarboxylate, cross-linked polysulfonate, cross-linked carboxymethyl cellulose, cellulose, sodium carboxymethylcellulose, and mixtures thereof;

g) optionally, desiccants, solid processing aids, colorants, agglomeration aids, binders, glidants, corrosion inhibitors, and mixtures thereof; and

h) wherein said first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite, sodium chlorite, chlorine dioxide, N-halogenated compounds, hydantoins, isocyanurates, carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups, enzymes; and

wherein said second part consisting essentially of,

a) a functional ingredient selected from the group consisting of a surfactant, a hydrotrope, a wetting agent, a dispersant, a penetrant, a chelating agent, an odor absorbent, a fragrance, a flavoring agent, a sweetener, a colorant, a corrosion inhibitor, a viscosity modifier, a foam booster, a defoamer, a stain and soil repellant, a fluorescent whitening agent, an enzyme, a cloud point modifier, an anti-microbial agent, a sporulation agent, a catalyst or an activating agent, a therapeutic agent, and mixtures thereof;

b) a builder or filler selected from the group consisting of a carbonate, bicarbonate, sesquicarbonate, chloride, sulfate, phosphates, silicate, borate, nitrate, aluminate, silica-aluminate, hydroxide, or oxide compound of alkali metals, alkaline earths, aluminum, zinc and tin including hydrates, mono, di and tribasic compounds, mixed salts, borates, clays, zeolites, and mixtures thereof;

c) optionally, a water-soluble polymer selected from the group consisting of polycarboxylate, sulfonated carboxylate, polysulfonate, polyvinylpyrrolidone, polyquaternary ammonium salts, copolymers and mixtures thereof;

d) optionally, an acid selected from the group consisting of sulfonic acid, polysulfonic acid, carboxylic acid, dicarboxylic acid, polycarboxylic acid, acid sulfate, acid phosphate, phosphonic acid, and mixtures thereof;

e) optionally, a water-swellable polymer selected from the group consisting from cross-linked polycarboxylate, cross-linked polysulfonate, cross-linked carboxymethyl cellulose, cellulose, sodium carboxymethylcellulose, and mixtures thereof;

optionally, desiccants, solid processing aids, agglomeration aids, bidders, glidants, preservatives, corrosion inhibitors and mixtures thereof; and

g) wherein said second part does not contain any oxidant, wherein said oxidant comprises hypochlorite, chlorite, chlorate, perchlorate, N-halo compound, chlorine dioxide, peracid, peroxide, peroxygen bleach and mixtures thereof.

11. The method of claim 10, wherein after the contacting step, the pH of the dissolved composition is between about 5 and about 8.

12. The method of claim 10, wherein none of the ingredients of the composition are coated, encapsulated or embedded in a polymer, resin, or a wax.

13. The method of claim 10, wherein the second part of the composition contains a builder selected from group consisting of carbonate, bicarbonate, sesquicarbonate and mixtures thereof and an acid selected from the group consisting of sulfonic acid, a carboxylic acid, a dicarboxylic acid, acid sulfate, an acid phosphate, a phosphonic acid, and mixtures thereof.

14. The method of claim 10, wherein the functional ingredient of the second part of the composition contains the surfactant and the hydrotrope.

15. The method of claim 10, wherein the water-soluble polymer in the first part is a polycarboxylate and the acid is a dicarboxylic acid.

16. The method of claim 10, wherein the composition requires a third part wherein said third part is situated between the first part and second part and said third part consists essentially of a component selected from the group consisting of binder, filler, colorant, desiccant, sodium chloride, sodium silicate, sodium sulfate, magnesium sulfate, magnesium carbonate, calcium carbonate, calcium hydroxide, calcium oxide, magnesium oxide, magnesium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, sodium sesquicarbonate, potassium sesquicarbonate, sodium borate, boric acid, aluminum hydroxide, silica and mixtures thereof.

17. A method for cleaning dentures, said method comprises:

contacting said dentures with a solid, multi-layered composition in water, wherein said composition comprises a first part and a second part;

wherein said first part consisting of,

0.001%-50% by weight of a hypochlorite selected calcium hypochlorite, magnesium hypochlorite and mixtures thereof;

b) a builder selected from the group consisting of carbonate, bicarbonate, sesquicarbonate and mixtures thereof;

c) a water-soluble polymer selected from the group consisting of sulfonic acid, sulfonated carboxylate, polysulfonate, polyvinylpyrrolidone, polyquaternary ammonium salts, copolymers and mixtures thereof;

d) at least 30% by weight of an acid selected from the group consisting of sulfonic acid, polysulfonic acid, carboxylic acid, dicarboxylic acid, polycarboxylic acid, acid sulfate, acid phosphate, phosphonic acid, and mixtures thereof;

e) optionally, a filler selected from chloride, sulfite, phosphate, silicate, borate, nitrate, chlorate, aluminate, silica-aluminate, hydroxide, and oxide compounds of alkali metals, alkaline earths, aluminum, zinc and tin including hydrates, mono, di and tribasic compounds, mixed salts, borates, clays, zeolites and mixtures thereof;

f) optionally, a water-swellable polymer selected from the group consisting of cross-linked polycarboxylate, cross-linked polysulfonate, cross-linked carboxymethyl cellulose, cellulose, sodium carboxymethylcellulose, and mixture thereof;

g) optionally, desiccants, solid processing aids, colorants, agglomeration aids, binders, glidants, corrosion inhibitors, and mixtures thereof; and

h) wherein said first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite, sodium chlorite, chlorine dioxide, N-halogenated compounds, hydantoins, isocyanurates, carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups, enzymes; and

wherein said second part consisting of,

a) a functional ingredient selected from the group consisting of a surfactant, a hydrotrope, a wetting agent, a dispersant, a penetrant, a chelating agent, an odor absorbent, a fragrance, a flavoring agent, a sweetener, a colorant, a corrosion inhibitor, a viscosity modifier, a foam booster, a defoamer, a stain and soil repellant, a fluorescent whitening agent, an enzyme, a cloud point modifier, an anti-microbial agent, a sporulation agent, a catalyst or an activating agent, a therapeutic agent, and mixtures thereof;

b) a builder or filler selected from the group consisting of carbonate, bicarbonate, sesquicarbonate, chloride, sulfate, phosphate, silicate, borate, nitrate, aluminate, silica-aluminate, hydroxide, or oxide compound of alkali metals, alkaline earths, aluminum, zinc and tin including hydrates, mono, di and tribasic compounds, mixed salts, borates, clays, zeolites, and mixtures thereof;

c) optionally, a water-soluble polymer selected from the group consisting of a polycarboxylate, sulfonated carboxylate, polysulfonate, polyvinylpyrrolidone, polyquaternary ammonium salts, copolymers and mixtures thereof;

d) optionally, an acid selected from the group consisting of sulfonic acid, polysulfonic acid, carboxylic acid, dicarboxylic acid, polycarboxylic acid, acid sulfate, acid phosphate, phosphonic acid, and mixtures thereof;

e) optionally, a water-swellable polymer selected from the group of cross-linked polycarboxylate, cross-linked polysulfonate, cross-linked carboxymethyl celluose, cellulose, sodium carboxymethylcellulose, and mixtures thereof; and

f) optionally, desiccants, solid processing aids, agglomeration aids, binders, glidants, preservatives, corrosion inhibitors and mixtures thereof; and

g) wherein said second part does not contain any oxidant, wherein said oxidant comprises hypochlorite, chlorite, chlorate, perchlorate, N-halo compound, chlorine dioxide, peracid, peroxide, peroxygen beach and mixtures thereof.

18. The method of claim 17, wherein after the contacting step, the pH of the dissolved composition is between about 5 and about 8.

19. The method of claim 17, wherein none of the ingredients of the composition are coated, encapsulated or embedded in a polymer, resin, or a wax.

20. The method of claim 17, wherein the functional ingredient of the second part of the composition contains the surfactant and the hydrotrope.