Graphite electrode

• US 8,366,892 B2
• Filed: 03/09/2011
• Issued: 02/05/2013
• Est. Priority Date: 03/19/2010
• Status: Active Grant

• Current Assignee: Wacker Chemie AG (Dr. Alexander Wacker Familiengesellschaft Mit Beschrã¤Nkter Haftung)
• Original Assignee: Wacker Chemie AG (Dr. Alexander Wacker Familiengesellschaft Mit Beschrã¤Nkter Haftung)
• Inventors: Sofin, Mikhail, Kraus, Heinz
• Primary Examiner(s): BELL, BRUCE F
• Application Number:
  US13/044,107
• Publication Number:
  US 20110229658A1
• Time in Patent Office: 699 Days
• Field of Search: 204/294, 423/348, 423/349, 117/88, 117/87, 117/84, 117/98, 117/935, 427/255.27, 427/452, 427/563, 427/578
• US Class Current: 204/294
• CPC Class Codes: C01B 33/035 by decomposition or reduction of gaseous or vaporised silicon compounds in the presence of heated filaments of silicon, carbon or a refractory metal, e.g. tantalum or tungsten, or in the presence of heated silicon rods on which the formed silicon is deposited, a silicon rod being obtained, e.g. Siemens process
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The present invention relates to an electrode composed of carbon having at least two different zones, wherein an outer zone (A) forms the base of the electrode and carries one or more inner zones, wherein the innermost zone (B) projects from the zone (A) at the top and has a lower specific thermal conductivity than zone (A).

Claims

1. An electrode comprised of carbon, wherein the electrode comprises at least two different zones having different specific thermal conductivities:

(A) an outer zone forming a base of the electrode; and

(B) at least one inner zone carried by the outer zone (A), projecting from a top of the outer zone (A) and having a specific thermal conductivity lower than a specific thermal conductivity of the outer zone (A).

2. The electrode as claimed in claim 1, wherein the at least two different zones are arranged in such a way that an innermost zone has the lowest specific thermal conductivity and is wholly or partly surrounded by a zone having a higher thermal conductivity.

3. The electrode as claimed in claim 1, wherein the at least one inner zone (B) is embodied as a loose or changeable insert.

4. The electrode as claimed in claim 3, wherein the at least one inner zone (B) is connected by means of a conical plug connection in the outer zone.

5. The electrode as claimed in claim 1, wherein the at least two different zones have a common thermal and electrical contact.

6. The electrode as claimed in claim 2, wherein the innermost zone having the lowest thermal conductivity has a device for receiving a filament rod.

7. The electrode as claimed in claim 1, wherein the electrode is coupled to a heat sink at the base.

8. The electrode as claimed in claim 1, wherein the electrode comprises high- or ultrahigh-purity electrographite having different thermal conductivities.

9. The electrode as claimed in claim 1, wherein the carbon has at least one of the following parameters:

a) a specific thermal conductivity from 20 to 200 W/(m*K),

b) an electrical resistivity 30 to 5 μ

Ohm*m,

c) an arithmetic mean roughness value of a surface roughness Ra 1 to 20 μ

m given a total height of the roughness profile Rt between 10 and 200 μ

m and an averaged roughness depth Rz between 8 and 160 μ

m,

d) a compressive strength 40 to 250 MPa,

e) a flexural strength 10 to 100 MPa,

f) a modulus of elasticity 1 to 20 GPa,

g) a coefficient of linear thermal expansion in a temperature range 20 to 1000°

C., 2*10<sup>−

6</sup> to 10*10<sup>−

6</sup> 1/K, and

h) an open porosity 5 to 25%.

10. A method for producing polycrystalline silicon by depositing high-purity elemental silicon from a gas phase on a surface of silicon rods, wherein the silicon rods are held in a reactor by electrodes as claimed in claim 1.