Multi-gas microsensor assembly

• US 8,366,894 B2
• Filed: 02/22/2010
• Issued: 02/05/2013
• Est. Priority Date: 02/20/2009
• Status: Expired due to Fees

• Current Assignee: Giner, Inc.
• Original Assignee: Giner, Inc.
• Inventors: Manoukian, Mourad, LaConti, Anthony B., Krebs, W. Michael, Tempelman, Linda A., Forchione, John W. Jr., Muehlanger, Erich Jr.
• Primary Examiner(s): Ball, J. Christopher
• Assistant Examiner(s): DIETERLE, JENNIFER M
• Application Number:
  US12/660,197
• Publication Number:
  US 20100276287A1
• Time in Patent Office: 1,079 Days
• Field of Search: 204/412, 204421-429, 204/431, 204/432
• US Class Current: 204/426
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

A multi-gas microsensor assembly for simultaneously detecting carbon dioxide and oxygen in real time. According to one embodiment, the assembly comprises a non-conductive, solid substrate. A plurality of sensing electrodes, a single reference electrode, and a single counter electrode are positioned on one side of the non-conductive, solid substrate. In addition, all of the electrodes are in intimate contact with the same side of a solid-polymer electrolyte anion-exchange membrane, the solid polymer electrolyte membrane having at least one gas diffusion opening aligned with each sensing electrode. The sensor is operated in a three-electrode potentiostatic mode, in which a constant potential is maintained between the sensing and reference electrodes, and the current is measured between the sensing and counter electrodes. Control of the electrodes is achieved with a small bi-potentiostat. The design of the bi-potentiostat allows at least two different sensing electrodes to share the same counter and reference electrodes.

Claims

1. A multi-gas microsensor assembly comprising:

(a) a sensor module, said sensor module comprising

(i) a sensor, said sensor comprising

(A) a non-conductive solid substrate,

(B) a plurality of sensing electrodes positioned on said non-conductive solid substrate,

(C) a reference electrode positioned on said non-conductive solid substrate,

(D) a counter electrode positioned on said non-conductive solid substrate,

(E) wherein at least two of said sensing electrodes share said reference electrode and said counter electrode,

(F) a solid polymer electrolyte ion-exchange membrane having a first side in intimate contact with each of said sensing electrodes, said reference electrode, and said counter electrode, said solid polymer electrolyte ion-exchange membrane having at least one gas diffusion opening aligned with each of said sensing electrodes,

(G) wherein at least a portion of said reference electrode is positioned between the at least two sensing electrodes sharing said reference electrode and wherein at least a portion of said counter electrode is positioned between the at least two sensing electrodes sharing said counter electrode, and

(ii) a sensor housing, the sensor housing having a cavity, the sensor being disposed within the cavity of the sensor housing; and

(b) an electronics module, said electronics module comprising

(i) an electronics housing, the electronics housing having a cavity,

(ii) electronics disposed within the cavity of the electronics housing, said electronics including a multi-potentiostat, the multi-potentiostat being coupled to the sensor so as to simultaneously and independently control at least two of the sensing electrodes;

(c) wherein one of the electronics module and the sensor module is positioned over the other.

2. The multi-gas microsensor assembly as claimed in claim 1 wherein said electronics further includes an electrical pulse generator electrically coupled to each of said metal oxide sensing electrode, said reference electrode, and said counter electrode, wherein the electrical pulse generator generates periodically at least one electrical pulse that simultaneously regenerates the metal oxide sensing electrode, the solid polymer electrolyte ion-exchange membrane, and the counter electrode.

3. The multi-gas sensor as claimed in claim 1, wherein said plurality of sensing electrodes includes a metal oxide sensing electrode and a gold sensing electrode.

4. The multi-gas microsensor assembly as claimed in claim 1 wherein the multi-potentiostat is coupled to the sensor using spring-loaded, electrically-conductive pins.

5. The multi-gas microsensor assembly as claimed in claim 4 further comprising a gasket, said electronics module being positioned over and in intimate contact with said gasket, said gasket being positioned over and in intimate contact with said sensor module.

6. The multi-gas microsensor assembly as claimed in claim 1 wherein said sensor housing comprises a base and a cover, said base having a recess, said sensor being disposed within said recess.

7. The multi-gas microsensor assembly as claimed in claim 6 wherein said recess comprises a lower portion and an upper portion, said sensor being disposed within said lower portion, and wherein said sensor module further comprises a tray, said tray being removably mounted within said upper portion of said recess.

8. The multi-gas microsensor assembly as claimed in claim 7 wherein said base further includes a water input, wherein said cover includes at least one gas input and, in fluid communication therewith, a first gas output and a second gas output, and wherein said tray includes a first gas channel in fluid communication with said first gas output of said cover and with said first sensing electrode, a second gas channel in fluid communication with said second gas output of said cover and with said second sensing electrode, a water reservoir, a water input in fluid communication both with said water reservoir and with said water input of said base, and a water output in fluid communication both with said water reservoir and with said lower portion of said recess.

9. A multi-gas microsensor assembly comprising:

(a) a multi-gas sensor, said multi-gas sensor comprising

(i) a non-conductive solid substrate, said non-conductive solid substrate having a first side,

(ii) a plurality of sensing electrodes, each of said sensing electrodes being positioned on said first side of said non-conductive solid substrate,

(iii) a reference electrode, said reference electrode being positioned on said first side of said non-conductive solid substrate,

(iv) a counter electrode, said counter electrode being positioned on said first side of said non-conductive solid substrate,

(v) wherein at least two of said sensing electrodes share said reference electrode and said counter electrode, and

(vi) a solid polymer electrolyte ion-exchange membrane, said solid polymer electrolyte ion-exchange membrane having a first side in intimate contact with each of said sensing electrodes, said reference electrode, and said counter electrode, said solid polymer electrolyte ion-exchange membrane having at least one gas diffusion opening aligned with each of said sensing electrodes;

(vii) wherein at least a portion of said reference electrode is positioned between the at least two sensing electrodes sharing said reference electrode and wherein at least a portion of said counter electrode is positioned between the at least two sensing electrodes sharing said counter electrode; and

(b) a multi-potentiostat, the multi-potentiostat simultaneously and independently controlling at least two of the sensing electrodes of the multi-gas sensor.

10. The multi-gas microsensor assembly as claimed in claim 9, wherein said solid polymer electrolyte ion-exchange membrane is a solid polymer electrolyte cation exchange membrane.

11. The multi-gas microsensor assembly as claimed in claim 9, wherein said multi-gas sensor is operated by said multi-potentiostat to detect at least two different gases simultaneously and in real time.

12. The multi-gas microsensor assembly as claimed in claim 11, wherein said plurality of sensing electrodes includes a metal oxide sensing electrode and a gold sensing electrode.

13. The multi-gas microsensor assembly as claimed in claim 12, wherein said plurality of sensing electrodes, said counter electrode and said reference electrode are made by screen-printing onto said non-conductive solid substrate.

14. The multi-gas microsensor assembly as claimed in claim 13, wherein the counter electrode comprises a material selected from the group consisting of silver and platinum, and wherein the reference electrode comprises a material selected from the group consisting of silver/silver chloride and Pt/air.

15. The multi-gas microsensor assembly as claimed in claim 14, wherein said solid polymer electrolyte ion-exchange membrane is a solid polymer electrolyte anion exchange membrane.

16. The multi-gas microsensor assembly as claimed in claim 15, wherein said solid polymer electrolyte anion exchange membrane is selected from the group consisting of a solid polymer electrolyte anion exchange membrane of a chloride ion form, a solid polymer electrolyte anion exchange membrane of a carbonate ion form, a solid polymer electrolyte anion exchange membrane of a bicarbonate ion form, a solid polymer electrolyte anion exchange membrane of a sulfate ion form, wherein the solid polymer electrolyte anion exchange membrane comprises a quaternary ammonium ion polymer or ionomer.

17. A multi-gas sensor, the multi-gas sensor comprising:

(a) a non-conductive solid substrate, said non-conductive solid substrate having a first side;

(b) a plurality of sensing electrodes, each of said sensing electrodes being positioned on said first side of said non-conductive solid substrate;

(c) a reference electrode, said reference electrode being positioned on said first side of said non-conductive solid substrate;

(d) a counter electrode, said counter electrode being positioned on said first side of said non-conductive solid substrate;

(e) wherein at least two of said sensing electrodes share said reference electrode and said counter electrode; and

(f) a solid polymer electrolyte ion-exchange membrane, said solid polymer electrolyte ion-exchange membrane having a first side in intimate contact with each of said sensing electrodes, said reference electrode, and said counter electrode, said solid polymer electrolyte ion-exchange membrane having at least one gas diffusion opening aligned with each of said sensing electrodes;

(g) wherein at least a portion of said reference electrode is positioned between the at least two sensing electrodes sharing said reference electrode and wherein at least a portion of said counter electrode is positioned between the at least two sensing electrodes sharing said counter electrode.

18. The multi-gas sensor as claimed in claim 17, wherein the plurality of sensing electrodes, the counter electrode, and the reference electrode are formed by screen printing.

19. The multi-gas sensor as claimed in claim 17, wherein the plurality of sensing electrodes, the counter electrode, and the reference electrode are arranged in a generally circular pattern, with a lead extending generally radially outwardly from each electrode.

20. The multi-gas sensor as claimed in claim 17, wherein said solid polymer electrolyte ion-exchange membrane is a solid polymer electrolyte cation exchange membrane.

21. The multi-gas sensor as claimed in claim 17, wherein said plurality of sensing electrodes consists of exactly two sensing electrodes.

22. The multi-gas sensor as claimed in claim 17, wherein the counter electrode has a surface area that exceeds the combined surface areas of the plurality of sensing electrodes.

23. The multi-gas sensor as claimed in claim 17, wherein the plurality of sensing electrodes consist of exactly two sensing electrodes and wherein the plurality of sensing electrodes, the counter electrode, and the reference electrode are arranged in a generally circular pattern, with each of the counter electrode and the reference electrode positioned alternately to the plurality of sensing electrodes.

24. The multi-gas sensor as claimed in claim 17, wherein the plurality of sensing electrodes consist of exactly two sensing electrodes, wherein the plurality of sensing electrodes, the counter electrode, and the reference electrode are arranged in a generally circular pattern, with each of the counter electrode and the reference electrode positioned alternately to the plurality of sensing electrodes, with a first lead extending generally radially outwardly from one of the sensing electrodes to a first contact pad on a first corner of the solid non-conductive substrate, a second lead extending generally radially outwardly from the counter electrode to a second contact pad on a second corner of the solid non-conductive substrate, a third lead extending generally radially outwardly from the other of the sensing electrodes to a third contact pad on a third corner of the solid non-conductive substrate, and a fourth lead extending generally radially outwardly from the reference electrode to a fourth contact pad at a fourth corner of the non-conductive solid substrate.

25. The multi-gas sensor as claimed in claim 24 further comprising an insulator, the insulator having a generally annular shape and covering the second and fourth leads but not covering the first and third leads, the first, second, third and fourth contact pads, and the plurality of sensing electrodes, the reference electrode and the counter electrode.

26. The multi-gas sensor as claimed in claim 17, wherein said plurality of sensing electrodes includes a metal oxide sensing electrode and a gold sensing electrode.

27. The multi-gas sensor as claimed in claim 26, wherein said metal oxide is selected from the group consisting of at least one of ruthenium oxide and iridium oxide.

28. The multi-gas sensor as claimed in claim 26, wherein said solid substrate comprises at least one of an inorganic material and an organic polymer, the inorganic material being selected from the group consisting of alumina, silica and titania, the organic polymer being selected from the group consisting of polyesters, polyimides, polysulfones, polyethers, polystyrenes, polyethylenes, polypropylenes, polycarbonates, and liquid crystal polymers.

29. The multi-gas sensor as claimed in claim 26, wherein the counter electrode comprises a material selected from the group consisting of silver and platinum and wherein the reference electrode comprises a material selected from the group consisting of silver/silver chloride and Pt/air.

30. The multi-gas sensor as claimed in claim 26, wherein said solid polymer electrolyte ion-exchange membrane is a solid polymer electrolyte anion exchange membrane.

31. The multi-gas sensor as claimed in claim 30, wherein said solid polymer electrolyte anion exchange membrane is selected from the group consisting of a solid polymer electrolyte anion exchange membrane of a chloride ion form, a solid polymer electrolyte anion exchange membrane of a carbonate ion form, a solid polymer electrolyte anion exchange membrane of a bicarbonate ion form, a solid polymer electrolyte anion exchange membrane of a sulfate ion form, wherein the solid polymer electrolyte anion exchange membrane comprises a quaternary ammonium ion polymer or ionomer.