Coated article with low-E coating including zirconium oxide and/or zirconium silicon oxynitride and methods of making same

• US 8,389,121 B2
• Filed: 08/22/2012
• Issued: 03/05/2013
• Est. Priority Date: 06/25/2008
• Status: Expired due to Fees

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Centre Luxembourgeois de Recherches pour le Verre et la Ceramique SA, Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Disteldorf, Bernd, Lingle, Philip J., Lao, Jingyu, Boyce, Brent
• Primary Examiner(s): Geyer, Scott B
• Application Number:
  US13/591,271
• Publication Number:
  US 20120315469A1
• Time in Patent Office: 195 Days
• Field of Search: None
• US Class Current: 428/428
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3636 one layer at least containing silicon, hydrogenated silicon or a silicide
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 2217/74 UV-absorbing coatings
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

This application relates to a coated article including at least one infrared (IR) reflecting layer of a material such as silver or the like in a low-E coating. In certain embodiments, at least one layer of the coating is of or includes zirconium oxide (e.g., ZrO₂) or zirconium silicon oxynitride (e.g., ZrSiO_xN_y). When a layer comprising zirconium oxide or zirconium silicon oxynitride is provided as the uppermost or overcoat layer of the coated article (e.g., over a silicon nitride based layer), this results in improved chemical and heat stability in certain example embodiments. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windows, or in other suitable applications such as monolithic window applications, laminated windows, and/or the like.

Claims

1. A coated article including a coating supported by a glass substrate, the coating comprising from the glass substrate outwardly:

a first dielectric layer comprising silicon nitride;

a first contact layer;

an infrared (IR) reflecting layer comprising silver located on the substrate over at least and contacting the first contact layer;

a second contact layer located over and contacting the IR reflecting layer, the second contact layer having a thickness of less than or equal to 11 angstroms;

a second dielectric layer comprising silicon nitride located over and contacting the second contact layer; and

an overcoat dielectric layer comprising one or more of zirconium oxynitride and zirconium silicon oxynitride located over and contacting the second dielectric layer comprising silicon nitride, and wherein the overcoat dielectric layer is doped with Y.

2. The coated article of claim 1, wherein the first dielectric layer comprising silicon nitride is in direct contact with the glass substrate.

3. The coated article of claim 1, wherein the overcoat layer comprises zirconium silicon oxynitride.

4. The coated article of claim 1, wherein the coated article has a sheet resistance (R_s) of no greater than about 15 ohms/square and a visible transmission of at least about 70%.

5. The coated article of claim 1, wherein the overcoat layer comprises zirconium oxynitride.

6. The coated article of claim 1, wherein the first contact layer comprises Ni and Cr, and has a thickness of 7-8 angstroms.

7. The coated article of claim 1, wherein the overcoat layer is doped with from about 2-12% Y₂O₃.