Touch screen devices employing nanostructure networks

• US 8,390,589 B2
• Filed: 06/11/2010
• Issued: 03/05/2013
• Est. Priority Date: 08/11/2006
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Hu, Liangbing, Gruner, George
• Primary Examiner(s): Wang, Quan-Zhen
• Assistant Examiner(s): NGUYEN, JENNIFER T
• Application Number:
  US12/813,799
• Publication Number:
  US 20110080355A1
• Time in Patent Office: 998 Days
• Field of Search: 345173-179, 3151691-1694, 178 1801- 1809
• US Class Current: 345/173
• CPC Class Codes: G06F 3/0445 using two or more layers of sensing electrodes, e.g. using two layers of electrodes separated by a dielectric layer
• CPC Class Codes: G06F 3/045 using resistive elements, e.g. a single continuous surface or two parallel surfaces put in contact

Abstract

Touch screen displays comprising at least one nanostructure-film, and fabrication methods thereof, are discussed. Nanostructure-films may comprise, for example, a network(s) of nanotubes, nanowires, nanoparticles and/or graphene flakes. Such films are preferably at least semi-transparent and relatively flexible, making them well-suited for use in a variety of touch screen applications.

Claims

1. A multilayer device, comprising:

a spacer layer on a first transparent substrate;

a first transparent conductive layer between the spacer layer and the first transparent substrate, the first transparent conductive layer including a network of nanostructures directly contacting the spacer layer and the first transparent substrate; and

at least two circuits, wherein

the first transparent conductive layer stores an electric charge, and

the circuits detect changes in capacitance across the first transparent conductive layer when the first transparent conductive layer is directly contacted by an external capacitance field.

2. The device of claim 1, further comprising:

a second conductive layer on a second substrate,

wherein the first transparent conductive layer and the second conductive layer face each other and are separated by the spacer layer,

wherein at least one of the first substrate and the second substrate is flexible, and

wherein the spacer layer prevents contact between the first transparent conductive layer and the second conductive layer in the absence of external deformation.

3. The device of claim 2, wherein nanostructures of the first network of nanostructures are substantially single-walled carbon nanotubes.

4. The device of claim 3, wherein the first transparent conductive layer further comprises a conducting polymer.

5. The device of claim 4, wherein at least one of the first transparent conductive layer and the second conductive layer is patterned.

6. The device of claim 5, wherein the second conductive layer comprises a second network of nano structures.

7. The device of claim 1, wherein the first transparent conductive layer has a sheet resistance of less than 500 ohm/sq and a transmittance of at least 90% for 550 nm wavelength light.

8. The device of claim 1, wherein the first transparent conductive layer has a sheet resistance of less than 350 ohm/sq and a transmittance of at least 90% for 550 nm wavelength light.

9. The device of claim 1, wherein the first transparent conductive layer has a sheet resistance of less than 200 ohm/sq and a transmittance of at least 90% for 550 nm wavelength light.

10. The device of claim 1, wherein the network of nanostructures is a single layer.

11. A method of fabricating a multi-layer device, comprising:

depositing a first conductive layer on a first substrate,

depositing a second conductive layer on a second substrate; and

affixing the first substrate to the second substrate such that the first conductive layer faces the second conductive layer,

wherein the first conductive layer is deposited by a multi-step spraying and washing process, comprising,

spraying nanostructures in solution onto the first substrate;

washing the first substrate after spraying, and

repeating the spraying and washing until a nanostructure-film of desired thickness is achieved,

wherein the first substrate is heated during the spraying process,

wherein a spacer layer prevents contact between the first and second conductive layers in the absence of external deformation,

wherein at least one of the first and second substrates is flexible,

wherein the first conductive layer comprises a first network of nanostructures, and

wherein the first network of nanostructures directly contacts the spacer layer and the first substrate.

12. The method of claim 11, wherein nanostructures of the first network of nanostructures are substantially single-walled carbon nanotubes.

13. The method of claim 12, further comprising depositing a conducting polymer that substantially fills open porosity in the first conductive layer.

14. The method of claim 13, wherein the second conductive layer comprises a second network of nanostructures, and

wherein at least one of the first network of nanostructures and the second network of nanostructures is patterned.

15. The method of claim 11, wherein the first conductive layer is deposited by transfer stamping.

16. The device of claim 11, wherein the first network of nanostructures is a single layer.

17. A touch screen comprising:

a first network of substantially single-walled carbon nanotubes (SWNTs) deposited directly on a first substrate,

wherein both the first network of SWNTs and the first substrate are transparent and the first network of substantially single-walled carbon nanotubes (SWNTs) are configured to directly contact a spacer layer;

a second network of substantially SWNTs deposited on a second substrate, wherein the first and second networks of substantially SWNTs face each other and are separated by the spacer layer,

wherein the spacer layer prevents contact between the first and second networks of substantially SWNTs in the absence of external deformation,

wherein at least one of the first and second substrates is flexible,

wherein the first network of substantially single-walled carbon nanotubes (SWNTs) directly contacts the spacer layer,

wherein at least one of the first and second networks of substantially SWNTs has a sheet resistance of less than 500 ohm/sq and a transmittance of at least 90% for 550 nm wavelength light, and

wherein capacitance across the first network of substantially single-walled carbon nanotubes is changed when the first network of substantially single-walled carbon nanotubes is directly contacted by an external capacitance field.

18. The touch screen of claim 17, wherein at least one of the first and second networks of substantially SWNTs has a conductivity of at least 1000 S/cm.

19. The touch screen of claim 17, wherein the first network of substantially single-walled carbon nanotubes (SWNTs) is a single layer.