Electrophoretic displays with controlled amounts of pigment

• US 8,390,918 B2
• Filed: 05/15/2008
• Issued: 03/05/2013
• Est. Priority Date: 04/02/2001
• Status: Active Grant

• Current Assignee: E Ink Holdings Incorporated
• Original Assignee: E Ink Holdings Incorporated
• Inventors: Wilcox, Russell J., Cao, Lan, Danner, Guy M., Paolini, Richard J. Jr., Webber, Richard M.
• Primary Examiner(s): TRA, TUYEN Q
• Application Number:
  US12/121,211
• Publication Number:
  US 20080266245A1
• Time in Patent Office: 1,755 Days
• Field of Search: 359/296, 345/107, 252/582, 252/583, 430/32, 430/34, 430/38, 204/600, 204/450
• US Class Current: 359/296
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1681 having two or more microcells partitioned by walls, e.g. of microcup type

Abstract

An electrophoretic medium has walls defining a microcavity containing an internal phase. This internal phase comprises electrophoretic particles suspended in a suspending fluid and capable of moving therethrough upon application of an electric field to the electrophoretic medium. The average height of the microcavity differs by not more than about 5 μm from the saturated particle thickness of the electrophoretic particle divided by the volume fraction of the electrophoretic particles in the internal phase.

Claims

1. An electrophoretic medium comprising a plurality of at least one type of electrophoretic particle suspended in a suspending fluid and capable of moving therethrough upon application of an electric field to the electrophoretic medium, such that, when application of a specific electric field to the medium for time T suffices to switch the medium between its extreme optical states, variations in the time of application of this specific electric field within the range of 0.9 to 1.1 T will not change the optical properties of either extreme state of the electrophoretic medium by more than 2 units of L*, where L* has the definition:

L*=116(R/R₀)^1/3−

16, where R is the reflectance and R₀ is a standard reflectance value.

2. An electrophoretic medium according to claim 1 such that variations in the time of application of this specific electric field within the range of 0.8 to 1.2 T will not change the optical properties of either extreme state of the electrophoretic medium by more than 2 units of L*.

3. A electrophoretic medium according to claim 1 comprising a single type of electrophoretic particle in a colored suspending fluid.

4. A electrophoretic medium according to claim 1 comprising a first type of electrophoretic particle having a first optical characteristic and a first electrophoretic mobility and a second type of electrophoretic particle having a second optical characteristic different from the first optical characteristic and a second electrophoretic mobility different from the first electrophoretic mobility.

5. A electrophoretic medium according to claim 4 wherein the suspending fluid is uncolored.

6. A electrophoretic medium according to claim 1 wherein the electrophoretic particles and the suspending fluid are retained within a plurality of cavities formed within a carrier medium.

7. A electrophoretic medium according to claim 1 wherein the electrophoretic particles and the suspending fluid are held within a plurality of capsules.

8. An electrophoretic medium according to claim 1 wherein the electrophoretic particles comprise titania.

9. An electrophoretic medium according to claim 8 wherein the electrophoretic particles further comprise dark colored particles formed from carbon black or copper chromite, the dark colored particles formed from carbon black or copper chromite and having an electrophoretic mobility different from the electrophoretic mobility of the titania particles.

10. An electrophoretic medium according to claim 1 wherein the volume fraction of electrophoretic particles in the internal phase is from about 3 to about 40 percent.

11. An electrophoretic medium according to claim 10 wherein the volume fraction of electrophoretic particles in the internal phase is from about 6 to about 18 percent.

12. An electrophoretic medium according to claim 1 wherein the viscosity of the internal phase is less than about 5 mPa sec.

13. An electrophoretic medium according to claim 12 wherein the viscosity of the internal phase is greater than about 1 mPa sec.

14. An electrophoretic medium according to claim 1 wherein the suspending fluid has dissolved or dispersed therein a polymer having a number average molecular weight in excess of about 20,000, the polymer being essentially non-absorbing on the electrophoretic particles.

15. An electrophoretic medium according to claim 14 wherein the suspending fluid is a hydrocarbon, and the polymer is a polyisobutylene having a viscosity average molecular weight in the range of about 400,000 to 1,200,000 g/mole, the polyisobutylene comprising from about 0.25 to about 2.5 percent by weight of the suspending fluid.

16. An electrophoretic medium according to claim 1 wherein the suspending fluid has dissolved or dispersed therein a polymer having an intrinsic viscosity of η

in the suspending fluid and being substantially free from ionic or ionizable groups in the suspending fluid, the polymer being present in the suspending fluid in a concentration of from about 0.5 [η

]<sup>−

1</sup> to about 2.0 [η

]<sup>−

1</sup>.

17. An electrophoretic display comprising an electrophoretic medium according to claim 1 and at least one electrode disposed adjacent the electrophoretic medium and arranged to apply an electric field thereto.

18. An electrophoretic display according to claim 17 having a first optical state in which the display displays an optical characteristic of the one type of electrophoretic particle and a second optical state in which the electrophoretic medium is light-transmissive.

19. An electrophoretic display according to claim 18 wherein, in the light-transmissive optical state, the electrophoretic particles are confined in a minor proportion of the cross-sectional area of each microcavity.

20. An electrophoretic display according to claim 18 comprising a backplane comprising a plurality of pixel electrodes, and a color filter or reflector, the color filter or reflector being disposed between the backplane and the electrophoretic medium.