Removal of inhibitory compounds during pre-treatment of lignocellulosic biomass

• US 8,394,235 B2
• Filed: 01/15/2010
• Issued: 03/12/2013
• Est. Priority Date: 01/16/2009
• Status: Active Grant

• Current Assignee: GreenField Specialty Alcohols Inc.
• Original Assignee: GreenField Ethanol Inc.
• Inventors: Lehoux, Richard Romeo, Bradt, Christopher Bruce
• Primary Examiner(s): CALANDRA, ANTHONY J
• Application Number:
  US12/688,342
• Publication Number:
  US 20100181034A1
• Time in Patent Office: 1,152 Days
• Field of Search: 162/19, 162/41, 162/63, 162/68
• US Class Current: 162/68
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: D21C 11/0007 Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042
• CPC Class Codes: D21C 5/00 Other processes for obtaining cellulose, e.g. cooking cotton linters obtaining fibres for spinning D01C; Processes characterised by the choice of cellulose-containing starting materials
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A process for the pretreatment of lignocellulosic biomass, in particular during the production of ethanol from biomass. The process including a cooking step where the biomass is exposed to steam at elevated temperatures and pressures for a preselected period of time in a treatment vessel. During the process, volatile and liquid compounds are purged from the treatment vessel.

Claims

1. A process for pretreatment of a lignocellulosic biomass, comprising the steps of:

exposing the lignocellulosic biomass to steam in an exposing step in a treatment vessel at a temperature of 190 to 220 degrees C. and an elevated pressure for an exposure time of 5 to 15 minutes; and

purging volatile inhibitory compounds from the treatment vessel after having reached a pressure of 50 to 200 psig and for a duration of 20 to 600 seconds, and purging liquid inhibitory compounds after a delay of 60 seconds following pressurization, and for a duration of 380 seconds; and

wherein the treatment vessel has a volatiles purge device including a valve that is selectively openable to permit flow at a controlled rate for a controlled duration of time, the volatiles purge device is located on the treatment vessel at a vertical position on the vessel above a level of the lignocellulosic biomass and the liquid compounds within the vessel, and the volatile compounds are removed through the volatiles purge device.

2. The process of claim 1, wherein the volatile compounds and/or liquid compounds are removed from the treatment vessel during the exposing step.

3. The process of claim 1, wherein the volatile compounds and the liquid compounds are purged from the vessel after the exposing step.

4. The process of claim 1, wherein the exposing step is carried out in a reaction vessel with a charge of lignocellulosic material and the volatile compounds are removed from a space above the charge of lignocellulosic material.

5. The process of claim 1, wherein the treatment vessel has a liquid purge device including a valve that is selectively openable to permit flow at a controlled rate for a controlled duration of time, the liquid purge device is located on the treatment vessel at a vertical position which permits removal of the liquid compounds in the treatment vessel, and the liquid compounds are removed through the liquid purge device.

6. The process of claim 1, wherein the exposing step is carried out at a temperature of 205 degrees C., a pressure of 235 psig and for a time interval of 8 minutes.

7. The process of claim 6, wherein the removal of the volatile compounds is carried out after the reaction vessel has reached 100 psig, and for a duration of 120 seconds.

8. The process of claim 1, wherein the lignocellulosic biomass is corncob.

9. The process of claim 8, wherein the corncob is ground to a particle size of 0.5 to 1.0 cm³ prior to the exposing step.

10. The process of claim 1, wherein the volatile inhibitory compounds and the liquid inhibitory compounds are selected from the group consisting of lignin, acetic acid, hemicellulose and hemicellulose degradation products.

11. A process for pretreatment of a lignocellulosic biomass for the generation of cellulose to be used in the production of ethanol through hydrolysis and fermentation in a cellulosic ethanol production process, the process for pretreatment comprising the steps of:

exposing the lignocellulosic biomass to steam in an exposing step in a treatment vessel at a temperature of 190 to 220 degrees C., at an elevated pressure and for an exposure time of 5 to 15 minutes; and

purging liquid and volatile inhibitory compounds, which are inhibitory to the hydrolysis and fermentation and are generated during the pretreatment of the lignocellulosic biomass, from the treatment vessel, the purging of the liquid inhibitory compounds being carried out after a delay of 60 seconds following pressurization of the treatment chamber and for a duration of 380 seconds, and the purging of the volatile inhibitory compounds being carried out after having reached a pressure of 50 to 200 psiq and for a duration of 20 to 600 seconds;

the treatment vessel having a liquid purge device including a valve that is selectively openable to permit flow at a controlled rate for a controlled duration of time, and a volatiles purge device including a valve that is selectively openable to permit flow at a controlled rate for a controlled duration of time;

the liquid purge device being located on the treatment vessel at a vertical position which permits removal of the liquid compounds in the treatment vessel, and the liquid compounds are removed through the liquid purge device; and

the volatiles purge device being located on the treatment vessel at a vertical position on the vessel above a level of the lignocellulosic biomass and the liquid compounds within the vessel, and the volatile compounds are removed through the volatiles purge device.

12. The process of claim 11, wherein the volatile compounds and/or liquid compounds are removed from the treatment vessel during the exposing step.

13. The process of claim 11, wherein the volatile compounds and the liquid compounds are purged from the vessel after the exposing step.

14. The process of claim 11, wherein the exposing step is carried out at a temperature of 205 degrees C., a pressure of 235 psig and for a time interval of 8 minutes.

15. The process of claim 14, wherein the removal of the volatile compounds is carried out after the reaction vessel has reached 100 psig, and for a duration of 120 seconds.

16. The process of claim 11, wherein the lignocellulosic biomass is corncob.

17. The process of claim 16, wherein the corncob is ground to a particle size of 0.5 to 1.0 cm³ prior to the exposing step.

18. The process of claim 11, wherein the inhibitory volatile compounds and/or the liquid compounds are selected from the group consisting of lignin, acetic acid, hemicellulose and hemicellulose degradation products.

19. A process for pretreatment of a lignocellulosic biomass, comprising the steps of:

exposing the lignocellulosic biomass to steam in an exposing step in a treatment vessel at an elevated temperature of 190 to 220 degrees C. and an elevated pressure for an exposure time of 5 to 15 minutes;

purging volatile inhibitory compounds from the treatment vessel after having reached a pressure of 50 to 200 psig in the treatment vessel and for a duration of 20 to 600 seconds; and

purging liquid inhibitory compounds after a delay of 60 seconds following pressurization, and for a duration of 380 seconds;

wherein the volatile compounds are removed from the treatment vessel during the exposing step; and

wherein the treatment vessel has a volatiles purge device including a valve that is selectively openable to permit flow at a controlled rate for a controlled duration of time and a liquid purge device including a valve that is selectively openable to permit flow at a controlled rate for a controlled duration of time, the volatiles purge device being located on the treatment vessel at a vertical position on the vessel above a level of the lignocellulosic biomass and the liquid compounds within the vessel, and the volatile compounds are removed through the volatiles purge device and the liquid purge device being located on the treatment vessel at a vertical position which permits removal of the liquid compounds in the treatment vessel, and the liquid compounds are removed through the liquid purge device.

20. The process of claim 19, wherein the volatile compounds are further purged from the vessel after the exposing step.

21. The process of claim 19, wherein the exposing step is carried out at a temperature of 205 degrees C., a pressure of 235 psig and for a time interval of 8 minutes.

22. The process of claim 21, wherein the removal of the volatile compounds is carried out after the reaction vessel has reached 100 psig, and for a duration of 120 seconds.

23. The process of claim 19, wherein the lignocellulosic biomass is corncob.

24. The process of claim 23, wherein the corncob is ground to a particle size of 0.5 to 1.0 cm³ prior to the exposing step.

25. The process of claim 19, wherein the inhibitory volatile compounds and/or the liquid compounds are selected from the group consisting of lignin, acetic acid, hemicellulose and hemicellulose degradation products.