Configurations and methods for acid gas absorption and solvent regeneration

• US 8,398,748 B2
• Filed: 04/18/2006
• Issued: 03/19/2013
• Est. Priority Date: 04/29/2005
• Status: Expired due to Fees

• Current Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Original Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Inventors: Mak, John
• Primary Examiner(s): Smith, Duane
• Assistant Examiner(s): WU, IVES J
• Application Number:
  US11/911,789
• Publication Number:
  US 20080184887A1
• Time in Patent Office: 2,527 Days
• Field of Search: 951/74, 951/64, 951/69, 951/81, 951/83, 952/04, 952/07, 95235-236, 962/18, 962/42, 423/220, 423228-229, 423/223
• US Class Current: 95/162
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Contemplated configurations and methods include a solvent regenerator (58) that has an upper (93) and a lower stripping section (94). Cooled rich solve is used as reflux while heated rich solvent (11) is used as a source of stripping agent in the upper section (91). A reboiler (62) in the lower section provides further stripping agent, hi especially preferred configurations, a portion of lean solved from the regenerator (58) is further stripped in a separate or integrated regenerator (62) to form an ultra-lean solvent. Both lean and ultra-lean solvents are preferably used in a two-stage absorber (52) to thereby from the rich solvent and an offgas that is very low in acid gas.

Claims

1. A plant comprising:

A solvent regenerator having a upper section and a lower section;

wherein the upper section has a first rich solvent inlet that is configured to provide a rich solvent reflux, and a second rich solvent inlet that is configured to provide a heated rich solvent regenerator feed;

wherein the lower section is configured to produce a lean solvent from both the rich solvent reflux and the heated rich solvent regenerator feed;

a heater operationally coupled to the regenerator and configured to heat a portion of a rich solvent to thereby provide the heated rich solvent regenerator feed;

a second regenerator that is configured to receive a portion of the lean solvent from the lower section of the solvent regenerator and to produce a steam-containing overhead product and an ultra-lean solvent from the lean solvent;

wherein the second regenerator is coupled to the solvent regenerator such as to deliver the steam-containing overhead product to solvent regenerator to thereby provide at least a portion of the stripping steam required in the solvent regenerator; and

an absorber having an upper section and a lower section, wherein absorber is configured to receive the ultra-lean solvent from the second regenerator and the lean solvent from the solvent regenerator in the respective upper and lower sections.

2. The plant of claim 1 further comprising a flash vessel coupled to the absorber and configured to flash the rich solvent from the absorber.

3. The plant of claim 1 further comprising a heat exchanger that is configured to heat untreated gas prior to entry into the absorber to thereby cool the rich solvent reflux.

4. The plant of claim 1 wherein the lean solvent comprises an amine-based solvent.

5. A method of regenerating a solvent, comprising:

feeding a first portion of a rich solvent as reflux to a first section of a regenerator, and feeding a heated second portion of the rich solvent to the first section of the regenerator;

wherein the second portion has a temperature sufficient to provide at least a portion of stripping medium to the first section;

forming in a second section of the regenerator a lean solvent from the first and second portions to thereby regenerate the solvent;

feeding a first portion of a bottom product of the regenerator to a second regenerator to thereby form an ultra-lean solvent and a second steam-containing regenerator overhead product;

feeding a second portion of the bottom product of the regenerator to a lower section of an absorber as a lean solvent, and feeding the ultra-lean solvent to an upper section of the absorber; and

providing the second steam-containing regenerator overhead product to the solvent regenerator to thereby supply at least a portion of the stripping steam required in the solvent regenerator.

6. The method of claim 5 wherein a heat exchanger heats the second portion of the rich solvent using heat from a bottom product of the regenerator.

7. The method of claim 5 further comprising a step of cooling the first portion of the rich solvent prior to the step of feeding the first portion to the first section of the regenerator.

8. The method of claim 5 wherein the absorber produces the rich solvent.

9. The method of claim 8 further comprising a step of flashing the rich solvent before the rich solvent is divided in a first and second portion.

10. The method of claim 8 further comprising a step of heating untreated gas in a heat exchanger prior to entry into the absorber to thereby cool the first portion of the rich solvent.

11. The method of claim 8 wherein the absorber produces an absorber overhead product, and wherein the absorber overhead product is combined with a portion of the ultra-lean solvent to produce a semi-lean solvent.

12. The method of claim 11 further comprising a step of feeding the semi-lean solvent as a reflux stream to the upper section of the regenerator.