Polymer object optical fabrication process

• US 8,404,173 B2
• Filed: 07/06/2010
• Issued: 03/26/2013
• Est. Priority Date: 11/17/2006
• Status: Active Grant

• Current Assignee: Poof Technologies, LLC
• Original Assignee: Poof Technologies, LLC
• Inventors: Cregger, Robert Brian
• Primary Examiner(s): Gupta, Yogendra
• Assistant Examiner(s): Grun, Robert J
• Application Number:
  US12/830,452
• Publication Number:
  US 20110006459A1
• Time in Patent Office: 994 Days
• Field of Search: 264/401
• US Class Current: 264/401
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing

Abstract

High-volume mass-production and customization of complex three-dimensional polymer and polymer-derived-ceramic microstructures are manufactured in a single step directly from three dimensional computer models. A projection based non-degenerate two-photon induced photopolymerization method overcomes the drawbacks of conventional one and two-photon fabrication methods. The structure includes dual, synchronized, high-peak power, pulsed femtosecond and picosecond lasers combined with spatial light modulation. Applications include high-resolution rapid prototyping and rapid manufacturing with an emphasis on fabrication of various Micro-Electro-Mechanical Systems (MEMS) devices, especially in the area of MEMS packaging.

Claims

1. A method for fabricating three-dimensional micro-structures directly from computer models, the method comprising:

placing a photoreactive material into a container wherein at least a part of the container is optically transparent so that said photoreactive material is accessible by light;

modifying said photoreactive material by non-degenerate two-photon absorption, wherein said modifying includes;

directing, inside said photoreactive material, one or more first light pulses comprising a pulsed patterned source light having a first wavelength range so as to form an image of pulsed patterned source light;

directing, inside said photoreactive material, one or more second light pulses having a second wavelength range so that the one or more second light pulses intersect the image of pulsed patterned source light and preselected portions of the photoreactive material are modified within a fabrication region, wherein said first wavelength range is different from said second wavelength range;

whereby at least certain photons of the one or more first light pulses intersect with at least certain photons of the one or more second light pulses to effect non-degenerate two-photon absorption within said photoreactive material.

2. The method of claim 1, wherein said modifying further includes patterned modification to produce at least one of:

solidification of said photoreactive material in accordance with a first pattern associated with said patterned modification,

desolidification of said photoreactive material in accordance with a second pattern associated with said patterned modification, and

modification of the index of refraction of said photoreactive material in accordance with a third pattern associated with said patterned modification.

3. The method of claim 1,

wherein said directing one or more first light pulses comprises directing femtosecond laser pulses onto an array of pixel elements so that said array of pixel elements induces at least in part said pulsed patterned source light said method further comprising:

synchronizing said pulsed patterned source light and said second light pulses;

aiming said pulsed patterned source light so that said pulsed patterned source light travels through an optically transparent part of said container into the photoreactive material and focuses inside said photoreactive material, at one or more selected portions of said fabrication region;

wherein said directing one or more second light pulses comprises directing picosecond pulsed laser light and focusing said picosecond laser pulses into a fiat, thin sheet of laser light that intersects the pulsed patterned source light from the array of pixel elements, said intersection being positioned so that said one or more preselected portions of the photoreactive material are modified within said fabrication region;

directing said container having said photoreactive material therein through said fabrication region;

whereby synchronized overlapping pulses operating at two different wavelengths of preselected energies meet combined energy requirements necessary to achieve nondegenerate two-photon absorption in the fabrication region within said photoreactive material.

4. The method of claim 1, wherein a first laser produces said one or more first light pulses and a second laser produces said one or more second light pulses.

5. The method of claim 1, wherein the image of pulsed patterned source light is at least one of a holographic image or a two dimensional image.

6. The method of claim 1, wherein said pulsed patterned source light is induced at least in part by at least one of a spatial light modulator, an array of pixel elements, a holographic grating, and a micromirror array spatial light modulator.

7. A method for inducing selective non-degenerate two-photon absorption events to occur, the method comprising:

directing, at a medium, at least one pulse of photons comprising photons of a first wavelength range to populate an event region inside said medium;

directing, at said medium, at least one patterned pulse of photons comprising photons of a second wavelength range to populate said event region, wherein;

said medium comprises a material that is susceptible to a non-degenerate-two-photon absorption of a photon of the first wavelength range and a photon of the second wavelength range, and

said at least one pulse of photons of said first wavelength range and said at least one patterned pulse of photons of said second wavelength range are directed such that non-degenerate two-photon absorption events occur at selected locations in the medium within the event region due to the coexistence of selectively positioned photons of said first wavelength range and selectively positioned photons of said second wavelength range of photons.

8. The method of claim 7, wherein energies of the photons of the first wavelength range and the photons of the second wavelength range meet combined energy requirements to achieve non-degenerate two-photon absorption without causing at least one of:

unwanted thermal effects and thermal damage.

9. The method of claim 7, wherein the temporal pulse lengths of pulses of the first wavelength range and the second wavelength range meet the requirements to achieve selective non-degenerate two-photon absorption events without causing at least one of;

unwanted thermal effects and thermal damage.

10. The method of claim 7, wherein the at least one pulse of photons of the first wavelength range is selected to be of a temporal duration to populate a selected thickness of the event region.

11. The method of claim 7, wherein exposing the material to the photons of the first wavelength range alone or exposing the material to the photons of the second range alone does not induce two-photon absorption.

12. The method of claim 7, wherein said at least one patterned pulse of photons is induced at least in part by at least one of a spatial light modulator, an array of pixel elements, a holographic grating, and a micromirror array spatial light modulator.

13. The method of claim 7, wherein said at least one patterned pulse comprises at least one of a holographic image and a two dimensional image.

14. The method of claim 7, wherein a first laser produces said at least one pulse of photons comprising photons of a first wavelength range and a second laser produces said at least one patterned pulse of photons comprising photons of a second wavelength range.

15. The method of claim 7, wherein said non-degenerate two-photon absorption events produce at least one of:

solidification of said material, desolidification of said material, and modification of the index of refraction of said material.

16. The method of claim 7, wherein the method is repeated to produce at least one of a three dimensional object, a micro polymer structure, a part, a micro-polymer-derived-ceramic structure, an optical circuit, a microstructure for Micro Electro Mechanical Systems (MEMS), a MEMS package, and a MicroOptoElectroMechanical (MOEMS) package.

17. The method of claim 7, wherein said event region comprises at least one of a two dimensional plane, a flat sheet, and a three dimensional volume.

18. The method of claim 7, wherein the at least one pulse of photons is of a picosecond-scale temporal duration and the at least one patterned pulse of photons is of a femtosecond-scale temporal duration.

19. The method of claim 7, wherein the event region is static.

20. The method of claim 7, wherein said material comprises at least one two-photon absorption peak between a summed energy of two photons of the first wavelength range and a summed energy of two photons of the second wavelength range.