Mixed hydrophilic/hydrophobic fiber media for liquid-liquid coalescence

• US 8,409,448 B2
• Filed: 01/07/2010
• Issued: 04/02/2013
• Est. Priority Date: 01/13/2009
• Status: Active Grant

• Current Assignee: University of Akron
• Original Assignee: University of Akron
• Inventors: Chase, George, Kulkarni, Prashant
• Primary Examiner(s): POPOVICS, ROBERT J
• Application Number:
  US12/655,823
• Publication Number:
  US 20100200512A1
• Time in Patent Office: 1,181 Days
• Field of Search: None
• US Class Current: 210/799
• CPC Class Codes: B01D 17/0202 by ab- or adsorption
• CPC Class Codes: B01D 17/045 with coalescers
• CPC Class Codes: B01D 17/10 with stationary filtering elements
• CPC Class Codes: B01D 39/04 Organic material, e.g. cellulose, cotton
• CPC Class Codes: B01D 39/06 Inorganic material, e.g. asbestos fibres, glass beads or fibres

Abstract

An immiscible lipophilic or hydrophilic liquid phase separated respectively from a continuous hydrophilic phase or a lipophilic phase liquid. Fibers having hydrophilic and hydrophobic properties are mixed, layered, etc., and formed into a filter. The separation mechanism involves capture of small droplets of the immiscible phase, coalescence of the small droplets into larger droplets as the immiscible liquid flows through the fiber filter, and release of the large immiscible droplets from the filter. With respect to separation of a hydrophilic immiscible fluid such as water in a lipophilic continuous fluid such as oil, the hydrophobic fibers will cause small water droplets to migrate towards the hydrophilic fibers whereby large droplets are formed on hydrophilic surface. The large droplets stay on hydrophilic fiber surface for extended periods of time and continue to coalescence until they are so large that they can no longer be maintained by the hydrophilic fibers and are released and drained off of the filter. In designing such filter, wettability of the filter media is an important parameter. The filter media can be designed by mixing hydrophilic and hydrophobic fibers in various proportions to achieve an optimum wettability range for separation of the immiscible liquid from the continuous phase liquid. The wettability of filter media can be characterized by a modified Washburn Equation.

Claims

1. A process for removing an immiscible lipophilic or a hydrophilic liquid respectively from a continuous hydrophilic or a lipophilic liquid phase, comprising the steps of:

1) forming a filter comprising a specific weight ratio of hydrophobic fibers to hydrophilic fibers;

2) determining an initial slope of a weight gain take-up versus time plot of the immiscible liquid by said filter;

3) determining an initial slope of weight gain take-up versus time plot of said continuous liquid by said filter;

4) calculating an L/H ratio from said initial slope of the plot of said immiscible liquid and of said initial slope of the plot of said continuous liquid and obtaining a wettability value for each;

5) forming a plurality of filters comprising different weight ratios of said hydrophobic fibers to said hydrophilic fibers from a range of from about 90% by weight of said hydrophobic fibers to about 10% by weight, or any portion thereof, of hydrophobic fibers with the remaining weight percent being said hydrophilic fibers;

repeating steps

     2),

     3), and

     4) with respect to each weight ratio of said lipophobic fibers to said hydrophilic fibers in step

     5);

plotting a wettability range from said L/H wettability values obtained from said plurality of said different weight ratios of said hydrophobic fibers to said hydrophilic fibers; and

utilizing a filter having a wetness value within a weight range of from about 20% to about 80% of hydrophobic fibers to hydrophilic fibers to coalesce said immiscible liquid phase within said continuous liquid phase.

2. The process of claim 1, wherein the fiber diameter of said hydrophobic fibers and said hydrophilic fibers, independently, is from about 0.1 to about 500 microns, and wherein said L/H wettability values of said different weight ratios of said hydrophobic fibers to said hydrophilic fibers, independently, is from about 1 to about 3,000.

3. The process of claim 2, wherein said fiber diameter of said hydrophobic fibers and said hydrophilic fibers, independently, is from about 0.5 to about 50 microns, and wherein said L/H wettability values of said different weight ratios of said hydrophobic fibers to said hydrophilic fibers, independently, is from about 2 to about 2,000, and wherein said filter has a wetness value within a weight range of from about 30% to about 70% of hydrophobic fibers to hydrophilic fibers.

4. The process of claim 3, wherein said L/H wettability values of said different weight ratios of said hydrophobic fibers to said hydrophilic fibers, independently, is from about 2 to about 150, and wherein said filter has a wetness value within a weight range of from 35% to about 65% of hydrophobic fibers to hydrophilic fibers.

5. The process of claim 1, wherein said hydrophobic fibers comprise one or more polymers including polyethylene, polypropylene, nomex, polyester, a halogen-containing polymer, rubber, polyurethane, polycarbonate, or a silicone polymer;

one or more minerals such as zinc oxide; and

fibers that contain silane coatings thereon; and

wherein said hydrophilic fibers comprise one or more glasses including sodium glass, boron glass, phosphate glass, or B-glass;

one or more minerals including alumina, titania, or silica;

one or more metals including aluminum or aluminum alloys; and

one or more polymers including cellulose acetate, poly(methylmethacrylate), polyethylene oxide, or nylon.

6. The process of claim 4, wherein said hydrophobic fibers include one or more polyethylene, polypropylene, or polyester, and halogen-containing fibers, and wherein said hydrophilic fibers comprise glass fibers.