Engineered composite building materials and methods of making same

• US 8,415,009 B2
• Filed: 12/13/2006
• Issued: 04/09/2013
• Est. Priority Date: 12/13/2006
• Status: Active Grant

• Current Assignee: James Hardie Technology Limited (James Hardie Industries Plc)
• Original Assignee: James Hardie Technology Limited (James Hardie Industries Plc)
• Inventors: Peng, Weiling, Chen, Hong, Luo, Caidian, Merkley, Donald J.
• Primary Examiner(s): Michener, Joshua J
• Assistant Examiner(s): Plummer, Elizabeth A
• Application Number:
  US11/638,624
• Publication Number:
  US 20080141908A1
• Time in Patent Office: 2,309 Days
• Field of Search: 527/821, 527/831, 523/091.2, 523/091.7, 428/312.4, 428/334
• US Class Current: 428/331
• CPC Class Codes: C04B 14/386 Carbon carbon nanotubes C04B14/026
• CPC Class Codes: C04B 14/42 Glass
• CPC Class Codes: C04B 14/48 Metal
• CPC Class Codes: C04B 16/06 fibrous
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 20/1029 Macromolecular compounds
• CPC Class Codes: C04B 2111/0062 Gypsum-paper board like materials
• CPC Class Codes: C04B 2111/27 Water resistance, i.e. waterproof or water-repellent materials
• CPC Class Codes: C04B 24/282 Polyurethanes; Polyisocyanates
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/48 Macromolecular compounds
• CPC Class Codes: C04B 41/483 Polyacrylates
• CPC Class Codes: C04B 41/4884 Polyurethanes; Polyisocyanates
• CPC Class Codes: C04B 41/4922 applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
• CPC Class Codes: C04B 41/4961 Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
• CPC Class Codes: C04B 41/52 Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
• CPC Class Codes: C04B 41/63 Macromolecular compounds
• CPC Class Codes: C04B 41/64 Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
• CPC Class Codes: C04B 41/71 : at least one coating being an organic material
• CPC Class Codes: C09D 1/08 : with organic additives
• CPC Class Codes: E04C 2/26 : composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups of cement and mineral fibres E04C2/04
• CPC Class Codes: Y02W 30/91 : Use of waste materials as fillers for mortars or concrete
• CPC Class Codes: Y10T 428/2495 : Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/249964 : Fibers of defined composition
• CPC Class Codes: Y10T 428/249965 : Cellulosic
• CPC Class Codes: Y10T 428/249968 : Of hydraulic-setting material
• CPC Class Codes: Y10T 428/259 : Silicic material

Abstract

An engineered composite building material, such as fiber cement, having one or more engineered sub-surface regions designed to provide the building material with improved moisture ingress resistance, paint adhesion, and other mechanical properties is provided. The sub-surface region has a cement-polymer matrix formed by introducing an impregnating agent into the pores of the substrate. The composite building material may be formed by applying impregnating agents to the subsurface regions of the substrate to form chemical and/or mechanical bonds with the matrix of the building material, the reinforcement fibers, and/or the surface coatings applied to the material. The thickness of the sub-surface regions may be controlled by varying the viscosity and porosity of the building material substrate. The cement-polymer building material has enhanced durability, weather resistance, strength, and stiffness.

Claims

1. An engineered composite building material comprising:

a cementitious substrate having a pre-determined porosity; and

a sub-surface region formed in the substrate, said sub-surface region comprising a cement-polymer matrix configured to reduce moisture absorption of the building material, wherein the cement-polymer matrix comprises a polymeric impregnating agent chemically bonded to hydroxyl functional groups in the substrate, wherein the thickness of the sub-surface region is controlled by the viscosity of the impregnating agent and the porosity of the cementitious substrate, the impregnating agent having a viscosity of less than about 500 cps at 25°

C., wherein the impregnating agent is deposited in the pores and interstices in the cementitious substrate of the sub-surface region, thereby causing the porosity of the sub-surface region to be less than the pre-determined porosity of the cementitious substrate.

2. The engineered composite material of claim 1, wherein the impregnating agent has a viscosity pre-selected to form the sub-surface region.

3. The engineered composite building material of claim 1, wherein the thickness of the sub-surface region is about 10 microns or greater.

4. The engineered composite building material of claim 1, wherein the thickness of the sub-surface region is about 100 microns or greater.

5. The engineered composite building material of claim 1, wherein the thickness of the sub-surface region is substantially the same as the thickness of the cementitious substrate.

6. The engineered composite building material of claim 1, wherein the polymeric impregnating agent is selected from the group consisting of isocyanates, epoxies, acrylics, and mixtures thereof.

7. The engineered composite building material of claim 6, wherein the impregnating agent comprises functional groups and wherein the functional groups are blocked.

8. The engineered composite building material of claim 6, wherein the impregnating agent is methylene diphenyl diisocyanate.

9. The engineered composite building material of claim 1, wherein the impregnating agent further comprises a polymerization initiator selected from the group consisting of organic peroxides, azo compounds, and mixtures thereof.

10. The engineered composite building material of claim 9, wherein the impregnating agent further comprises a catalyst selected from the group consisting of tertiary amines, metal salts, and combination thereof.

11. The engineered composite building material of claim 1, wherein the impregnating agent forms non-hydrolysable chemical bonds with free hydroxyl functional groups in the cementitious substrate.

12. The engineered composite building material of claim 1, wherein the cementitious substrate comprises a fiber cement matrix, said fiber cement matrix comprises fibers selected from the group consisting of cellulose fibers, PVA fibers, PP fibers, PE fibers, polyester fibers, carbon fibers, steel fibers, glass fibers and other mineral fibers, wherein the polymeric impregnating agent forms chemical and mechanical bonds with the fibers.

13. The engineered composite building material of claim 1, further comprising an exterior coating formed on an exterior surface of the building material, said exterior coating selected from the group consisting of paints, topcoats, primers, sealers, and combinations thereof.

14. The engineered composite building material of claim 13, wherein the impregnating in the sub-surface region forms a chemical bond with the exterior coating.

15. The engineered composite building material of claim 1, wherein the building material is selected from the group consisting of gypsum board, fiber cement board, fiber cement board reinforced by a mesh or continuous fibers, gypsum board reinforced by short fibers, mesh or continuous fibers, inorganic bonded wood and fiber composite material, geopolymer bonded wood and fiber board, concrete roofing tile, and one or more fiber-plastic composite material.