Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, and gas separation assemblies

• US 8,425,662 B2
• Filed: 04/01/2011
• Issued: 04/23/2013
• Est. Priority Date: 04/02/2010
• Status: Active Grant

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: McGrail, B. Peter, Thallapally, Praveen K., Xu, Wu
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US13/078,548
• Publication Number:
  US 20110243820A1
• Time in Patent Office: 753 Days
• Field of Search: 951/39, 951/48, 961/21, 961/43, 502/526, 423/230
• US Class Current: 95/139
• CPC Class Codes: B01D 2253/204 Metal organic frameworks (MOF's)
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/40083 Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/32 by electrical effects other than those provided for in group B01D61/00
• CPC Class Codes: B01D 53/326 in electrochemical cells
• CPC Class Codes: C25B 15/00 Operating or servicing cells
• CPC Class Codes: F23J 15/02 of purifiers, e.g. for removing noxious material traps for solid residues F23J3/04
• CPC Class Codes: F23J 2215/50 Carbon dioxide
• CPC Class Codes: F23J 2219/60 Sorption with dry devices, e.g. beds
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Gas separation assemblies are provided.

Claims

1. A method for releasing associated guest materials from a metal organic framework the method comprising altering the oxidation state of at least a portion of the metal of the metal organic framework to dissociate at least a portion of the guest materials from the framework.

2. The method of claim 1 wherein the portion of the metal of the metal organic framework is a transition metal.

3. The method of claim 1 wherein the portion of the metal of the metal organic framework is one or more of Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Mn, Tc, Re, Bh, Fe, Ru, Os, Hs, Co, Rh, Os, Hs, Co, Rh, Ir, Mt, Ni, pd, Pt, Ds, Cu, Ag, Au, and Rg.

4. The method of claim 1 wherein the portion of the metal of the metal organic framework has a mixed oxidation state.

5. The method of claim 1 wherein the portion of the metal of the metal organic framework is represented as (M²⁺/M³⁺).

6. The method of claim 1 wherein the portion of the metal of the metal organic framework is coupled to a substantially conductive organic ligand.

7. The method of claim 1 wherein the guest material comprises carbon dioxide.

8. A method for associating guest materials with a metal organic framework, the method comprising altering the oxidation state of at least a portion of the metal of the metal organic framework to associate at least a portion of the guest materials with the framework.

9. The method of claim 8 further comprising exposing a mixture to the metal organic framework, the mixture comprising the guest materials and other materials, at least a portion of the other materials not being associated with the metal organic framework upon the exposing.

10. The method of claim 9 wherein the mixture comprises a flue gas.

11. The method of claim 9 wherein the mixture comprises combustion products.

12. The method of claim 9 wherein the mixture comprises carbon dioxide and water.

13. The method of claim 9 wherein the mixture comprises carbon dioxide and water and the guest material is carbon dioxide.

14. A method for selectively associating or dissociating guest materials with a metal organic framework, the method comprising altering the oxidation state of at least a portion of the metal of the metal organic framework to associate or dissociate at least a portion of the guest materials with the framework.

15. The method of claim 14 further comprising exposing a mixture to the metal organic framework, the mixture comprising the guest materials and other materials, at least a portion of the other materials not being associated with the metal organic framework upon the exposing.

16. The method of claim 15 wherein during the exposing, guest material is associated with the metal organic framework.

17. The method of claim 16 further comprising:

ceasing the exposing;

altering the oxidation state of the portion of the metal; and

dissociating at least a portion of the guest materials from the metal organic framework.

18. The method of claim 17 further comprising:

after the dissociating, altering the oxidation state of the portion of the metal to return the oxidation state to an associating oxidation state;

after the altering, exposing the mixture to the metal organic framework; and

associating at least a portion of the guest material of the mixture with the metal organic framework.

19. The method of claim 14 wherein the altering comprises applying a predetermined voltage to the metal organic framework.

20. The method of claim 14 wherein the oxidation state of the portion of the metal is electrochemically altered.

21. A system for associating or dissociating guest materials within a series of metal organic frameworks, the system comprising at least two individual metal organic frameworks, one of the individual metal organic frameworks configured to dissociate and the other configured to associate guest materials, wherein the one framework comprises at least some metals of one oxidation state and the other framework comprises the same metals of another oxidation state.

22. The system of claim 21 further comprising:

a power source; and

a controller operatively coupled to both the power source and the metal organic frameworks.

23. The system of claim 21 wherein the metal of the metal organic frameworks are mixed valence transition metals.

24. The system of claim 22 wherein the one metal organic framework comprises (M²⁺/M³⁺), and the other metal organic framework comprises (M₃₊/M³⁺).

25. The system of claim 21 further comprising a conduit extending to a valve in fluid communication with both the metal organic frameworks.

26. The system of claim 25 further comprising:

a power source;

a motor configured to operate the valve; and

a controller operatively coupled to the power source, the metal organic frameworks, and the motor.

27. A gas separation assembly comprising:

a plurality of individual cells housing metal organic framework, the plurality comprising at least one series of cells and another series of cells, each series comprising at least two electrically isolated individual cells;

a channel between the one series of cells and the other series of cells;

a power source; and

a controller coupled to both the assembly and the power source.

28. The assembly of claim 27 wherein the channel comprises an electrolyte.

29. The assembly of claim 27 wherein the one series is aligned laterally of the other series, and the individual cells of the one series are aligned lateral to the individual cells of the other series to form a pair of cells.

30. The assembly of claim 29 wherein one of the pair of cells is configured to dissociate guest materials, and the other of the pair of cells is configured to associate guest materials.

31. The assembly of claim 29 further comprising conduits extending along the perimeter of each of the series of cells, the conduits configured to expose the metal organic framework of each of the cells of each of the series.

32. The assembly of claim 31 wherein the one series of cells is in fluid communication with one conduit, and the other series of cells is in fluid communication with another conduit.